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The Atmospheric Aerosol

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Abstract

The term aerosol refers to a suspension of fine particles in air. The principal sources of the aerosol in the troposphere are: (a) surface agitation by wind force, which generates soil dust, sea salt particles, and biogenic material; (b) high temperature processes including volcanic eruptions, forest fires and anthropogenic combustion processes; (c) chemical reactions leading to compounds with low vapor pressures such as the oxidation of SO2 to sulfuric acid, NO2 to nitric acid, or glyoxal to oxalic acid, and the neutralization of the acids by ammonia or alkaline minerals to form water-soluble salts. Particles in the size range above ∼0.1 μm act as cloud condensation nuclei (CCN). While most clouds evaporate again so that the aerosol particles are recycled, precipitation transfers the material to the earth surface. The particles are incorporated in rain water during the formation of precipitating clouds (nucleation scavenging) and by attachment to rain drops (below-cloud scavenging). Dry deposition also contributes to the removal of particles from the atmospheric boundary layer (primarily in the size range >5 μm). Directly emitted particles usually retain their original chemical character in the vicinity of sources, but during transport in the troposphere all particles undergo chemical modification both by the coagulation of small particles and by the accumulation of material resulting from chemical reactions occurring in the gas phase and in clouds. In the stratosphere the principal source of aerosol particles is the chemical conversion of sulfur compounds to sulfuric acid.

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Warneck, P., Williams, J. (2012). The Atmospheric Aerosol. In: The Atmospheric Chemist’s Companion. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-2275-0_5

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