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Chemomechanical Dynamics of Responsive Gels

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Book cover Chemomechanical Instabilities in Responsive Materials

Abstract

In this contribution we present a formalism to describe the spatio-temporalevolution of a responsive gel submitted to some autocatalytic chemical reaction. This theory is based on an hydrodynamical multi-diffusional approach of a gel, which is plunged in a chemically active mixture. Emergent volume self-oscillation dynamics of the gel result from the nonlinear coupling of the elastic deformation, the chemical kinetics and the transport phenomenon, that take place in the system. We apply our formalism to the case of the Belouzov-Zhabotinsky oscillatory chemical reaction, for which Yoshida et al. (see in this volume) have obtained many experimental results. In particular we discuss some possible coupling between the gel and the chemical reaction.

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Author information

Authors and Affiliations

  1. Matière et Systèmes Complexes UMR 7057 CNRS, Université Paris 7-Paris Diderot., 10, rue Alice Domon et Léonie Duquet, Paris cedex 13, 75205, France

    Stéphane Métens & Sébastien Villain

  2. Unité de Chimie-Physique nonlinéaire, Université Libre de Bruxelles., CP 231, Bd du Triomphe, Bruxelles, B1050, Belgique

    Pierre Borckmans

Authors
  1. Stéphane Métens
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  2. Sébastien Villain
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  3. Pierre Borckmans
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Corresponding author

Correspondence to Stéphane Métens .

Editor information

Editors and Affiliations

  1. Service de Chimie Physique et Biologie Théorique Université Libre de Bruxelles, Belgium

    P. Borckmans

  2. Centre de Recherche Paul Pascal Université de Bordeaux, France

    P. De Kepper

  3. Chair of Physics of Polymers and Crystals Moscow State University, Russia

    A. R. Khokhlov

  4. Matière et Systèmes Complexes Université Paris 7 — Denis Diderot, France

    S. Métens

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Métens, S., Villain, S., Borckmans, P. (2009). Chemomechanical Dynamics of Responsive Gels. In: Borckmans, P., De Kepper, P., Khokhlov, A.R., Métens, S. (eds) Chemomechanical Instabilities in Responsive Materials. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2993-5_6

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