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Chemomechanical Instabilities in Responsive Materials pp 95–116Cite as

Chemomechanics: Oscillatory Dynamics in Chemoresponsive Gels

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Abstract

Wereview the different strategies to produce mechanical oscillations by coupling a gel which swells/deswells as a function of the chemical composition of its solvent (‘chemo-responsive gel’) with an autocatalytic reaction kept far from equilibrium. Afterwards we focus on the case of oscillations obtained by coupling the gel with a reaction that exhibits spatial bistability. The principles are illustrated with a simple swelling and reaction-diffusion model and experimental data obtained with the chlorite-tetrathionate reaction an a polyelec-trolyte gel.

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Author information

Authors and Affiliations

  1. Université de Bordeaux and CNRS, Centre de recherche Paul Pascal, 115,av., Schweitzer, F-33600, Pessac

    J. Boissonade & P. De Kepper

Authors
  1. J. Boissonade
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  2. P. De Kepper
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Correspondence to J. Boissonade .

Editor information

Editors and Affiliations

  1. Service de Chimie Physique et Biologie Théorique Université Libre de Bruxelles, Belgium

    P. Borckmans

  2. Centre de Recherche Paul Pascal Université de Bordeaux, France

    P. De Kepper

  3. Chair of Physics of Polymers and Crystals Moscow State University, Russia

    A. R. Khokhlov

  4. Matière et Systèmes Complexes Université Paris 7 — Denis Diderot, France

    S. Métens

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Boissonade, J., De Kepper, P. (2009). Chemomechanics: Oscillatory Dynamics in Chemoresponsive Gels. In: Borckmans, P., De Kepper, P., Khokhlov, A.R., Métens, S. (eds) Chemomechanical Instabilities in Responsive Materials. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2993-5_4

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