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Photofunctionalization of Molecular Switch Based on Pyrimidine Ring Rotation in Copper Complexes pp 25–61Cite as

Details of Molecular Bistability Based on Pyrimidine Ring Rotation in Copper(I) Complexes

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Abstract

The rational molecular design requires a detailed investigation for the equilibrium between two rotational isomers derived from orientation of pyrimidine ring. I studied on chemistry of rotational equilibrium in newly synthesized copper(I) complexes bearing two bidentate ligands, pyridylpyrimidine and bulky diphosphine, using 1H NMR and single crystal X-ray structural analysis. I found that ion-pairing sensitivities of rotational bistability in the view point of both thermodynamics and kinetics, evidence for intramolecular process of interconversion, and suitability of common organic solution state for the desired function.

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Authors and Affiliations

  1. Seikei University, Musashino, Japan

    Michihiro Nishikawa

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  1. Michihiro Nishikawa
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Correspondence to Michihiro Nishikawa .

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Nishikawa, M. (2014). Details of Molecular Bistability Based on Pyrimidine Ring Rotation in Copper(I) Complexes. In: Photofunctionalization of Molecular Switch Based on Pyrimidine Ring Rotation in Copper Complexes. Springer Theses. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54625-2_2

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