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Zeolite Effects in Organic Catalysis

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Abstract

New catalytic technology developed during the 1980s in Japan [1, 2], USA [3], China [4] and Europe [5] has been reviewed recently. Table 6.1 contains the reported catalytic technology extracted from this work which makes use of zeolite molecular sieves. It is clear that most of the technological developments have been made in the area of the refining of oil fractions (Table 6.1.I). Strong acidity in a shape-selective environment in which the zeolite pore and cage walls exert stereoselective constraints on the transition states and/or on the movement of products and reagents, together with intense hydrogen transfer reactions, are at the basis of this specific behavior (vide infra).

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Espeel, P., Parton, R., Toufar, H., Martens, J., Hölderich, W., Jacobs, P. (1999). Zeolite Effects in Organic Catalysis. In: Weitkamp, J., Puppe, L. (eds) Catalysis and Zeolites. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03764-5_6

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