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Microemulsions as Liquid Media for Chemical Reactions

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Abstract

Microemulsions are thermodynamically stable, macroscopically homogeneous dispersions of submicroscopical domains of water and nonpolar solvents with a large internal interface. As such they are suited for performing chemical reactions between water-soluble and oil-soluble reactants. In this article the general patterns of the phase behavior of such mixtures is summarized. Their knowledge permits tailoring microemulsions as media for particular chemical reactions.

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References

  1. Kahlweit M, Strey R (1985) Angew Chemie Int Ed Engl 24:654

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  2. For attempts to describe microemulsions on the basis of phenomenological models see: Andelman D, Cates ME, Roux D, Safran SA (1987) J Chem Phys 87:7229

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  3. For an overview over the various experimental techniques see: Kahlweit M, et al (1987) J Colloid Interf Sci 118:436

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  4. For the general patterns of mixtures with nonionics see: Kahlweit M, Strey R, Firman P, Haase D, Jen J, Schomacker R (1988) Langmuir 4:499

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  5. For the general patterns of mixtures with ionics see: Kahlweit M, Strey R, Schomacker R, Haase D (1989) Langmuir (in press)

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© 1989 Springer-Verlag Berlin Heidelberg

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Kahlweit, M., Strey, R., Schomäcker, R. (1989). Microemulsions as Liquid Media for Chemical Reactions. In: Knoche, W., Schomäcker, R. (eds) Reactions in Compartmentalized Liquids. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-74787-8_1

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  • DOI: https://doi.org/10.1007/978-3-642-74787-8_1

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-51188-5

  • Online ISBN: 978-3-642-74787-8

  • eBook Packages: Springer Book Archive

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