Abstract
Inverse gas chromatography (IGC) is a very useful technique for the characterization of surface thermodynamics of a wide range of finely divided materials such as polymers, fibres, mineral fillers and clays. IGC permits determining the dispersive component of the surface energy(γ dS ) and acid-base constants describing the ability of the materials to interact via London and Lewis forces. These forces are important in wetting, adhesion and mixing properties of materials. However, experimental factors such as the sample injection and the flow rate on the one hand, and data treatment on the other hand strongly affect the accuracy in assessing quantitative properties of the materials under test.
Résumé
La chromatographic en phase gazeuse (CPG) inverse est une technique très utile pour la caractérisation des propriétés de surface de matériaux finement divisés tels que polymères, fibres, charges minérales et argiles. La CPG inverse permet de déterminer le composante dispersive de l’énergie de surface et les constantes acide-base qui décrivent les réactions des matériaux à travers les forces de London et de Lewis. Ces forces sont importantes en mouillage, adhérence et mélange des matériaux. Néanmoins, les paramètres expérimentaux tels que la quantité de soluté injectée et le débit d’une part et le traitement de données d’autre part font que les propriétés de surface des matériaux ne sont déterminées que d’une manière semi-quantitative.
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Chehimi, M.M. (1998). Surface Thermodynamics of Solid Materials by Inverse Gas Chromatography. In: Caliste, JP., Truyol, A., Westbrook, J.H. (eds) Thermodynamic Modeling and Materials Data Engineering. Data and Knowledge in a Changing World. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72207-3_14
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DOI: https://doi.org/10.1007/978-3-642-72207-3_14
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