Abstract
Covalent catalyses by cyclodextrin (C) proceed as shown in Scheme 1, where S and S · C represent the substrate and the (noncovalent) inclusion complex, respectively; C — P1 is the covalent intermediate, which is an acyl-cyclodextrin in the hydrolyses of esters and amides and is cyclodextrin phosphate in the hydrolyses of organophosphates; P1 and P2 are the final products; and k1, k-1, k2, k3, and kun are rate constants for the various processes indicated.
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© 1978 Springer-Verlag Berlin Heidelberg
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Bender, M.L., Komiyama, M. (1978). Covalent Catalyses. In: Cyclodextrin Chemistry. Reactivity and Structure Concepts in Organic Chemistry, vol 6. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-66842-5_5
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DOI: https://doi.org/10.1007/978-3-642-66842-5_5
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-66844-9
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