Abstract
About 1800 geochemical measurements including more than 1000 isotope analyses have been published as a result of geochemical monitoring programs established at several CO2 storage and enhanced oil and gas recovery projects worldwide. These projects are briefly discussed here in order to compare sampling techniques to obtain fluid and gas samples for chemical and isotopic analyses. In all the projects, changes of stable isotope ratios of CO2 and dissolved inorganic carbon in samples obtained pre- and post-injection were used to quantify solubility and ionic trapping of CO2 via stable isotope mass balances. Further applications include, monitoring of underground CO2 migration and early detection of potential CO2 leaks into overlying formations. Other benefits of these stable isotope tracers include a better understanding of water-rock-gas interactions with CO2 under supercritical conditions and often highly saline reservoir fluids that are present in the storage formations. While the results of these projects need further laboratory and experimental confirmation, further increase in field applications of stable isotope tracer techniques are anticipated with the introduction of new portable laser stable isotope mass spectrometers.
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References
Freifeld, B.M., Daley, T.M., Hovorka, S.D., Henninges, J., Underschultz, J., Sharma, S.: Recent advances in well-based monitoring of CO2 sequestration. Energy Procedia 1(1), 2277–2284 (2009)
Emberley, S., Hutcheon, I., Shevalier, M., Durocher, K., Mayer, B., Gunter, W.D., Perkins, E.H.: Monitoring of fluid-rock interaction and CO2 storage through produced fluid sampling at the Weyburn CO2-injection enhanced oil recovery site, Saskatchewan, Canada. Appl. Geochem. 20(6), 1131–1157 (2005), doi:10.1016/J.Apgeochem.2005.02.007
Kharaka, Y.K., Cole, D.R., Thordsen, J.J., Kakouros, E., Nance, H.S.: Gas-water-rock interactions in sedimentary basins: CO2 sequestration in the Frio Formation, Texas, USA. J. Geochem. Explor. 89(1-3), 183–186 (2006), doi:10.1016/J.Gexplo.2005.11.077
Boreham, C., Underschultz, J., Stalker, L., Kirste, D., Freifeld, B., Jenkins, C., Ennis-King, J.: Monitoring of CO2 storage in a depleted natural gas reservoir: Gas geochemistry from the CO2CRC Otway Project, Australia. Int. J. Greenh. Gas Con. 5(4), 1039–1054 (2011), doi:10.1016/J.Ijggc.2011.03.011
Emberley, S., Hutcheon, I., Shevalier, M., Durocher, K., Gunter, W.D., Perkins, E.H.: Geochemical monitoring of fluid-rock interaction and CO2 storage at the Weyburn CO2-injection enhanced oil recovery site, Saskatchewan, Canada. Energy 29(9-10), 1393–1401 (2004), doi:10.1016/J.Energy.2004.03.073
Kharaka, Y.K., Thordsen, J.J., Hovorka, S.D., Nance, H.S., Cole, D.R., Phelps, T.J., Knauss, K.G.: Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test, Texas, USA. Appl. Geochem. 24(6), 1106–1112 (2009), doi:10.1016/J.Apgeochem.2009.02.010
Shi, J.Q., Sinayuc, C., Durucan, S., Korre, A.: Assessment of carbon dioxide plume behaviour within the storage reservoir and the lower caprock around the KB-502 injection well at In Salah. Int. J. Greenh. Gas Con. 7, 115–126 (2012), doi:10.1016/J.Ijggc.2012.01.002
Zimmer, M., Erzinger, J., Kujawa, C.: The gas membrane sensor (GMS): A new method for gas measurements in deep boreholes applied at the CO2SINK site. Int. J. Greenh. Gas Con. 5(4), 995–1001 (2011)
Ghosh, P., Brand, W.A.: Stable isotope ratio mass spectrometry in global climate change research. International Journal of Mass Spectrometry 228(1), 1–33 (2003)
Raistrick, M., Mayer, B., Shevalier, M., Perez, R.J., Hutcheon, I., Perkins, E., Gunter, B.: Using chemical and isotopic data to quantify ionic trapping of injected carbon dioxide in oil field brines. Environ. Sci. Technol. 40(21), 6744–6749 (2006), doi:10.1021/Es060551a
Lu, J.M., Kharaka, Y.K., Thordsen, J.J., Horita, J., Karamalidis, A., Griffith, C., Hakala, J.A., Ambats, G., Cole, D.R., Phelps, T.J., Manning, M.A., Cook, P.J., Hovorka, S.D.: CO2-rock-brine interactions in Lower Tuscaloosa Formation at Cranfield CO2 sequestration site, Mississippi, USA. Chem. Geol. 291, 269–277 (2012), doi:10.1016/J.Chemgeo.2011.10.020
Johnson, G., Mayer, B., Shevalier, M., Nightingale, M., Hutcheon, I.: Tracing the movement of CO2 injected into a mature oilfield using carbon isotope abundance ratios: The example of the Pembina Cardium CO2 Monitoring project. Int. J. Greenh. Gas Con. 5(4), 933–941 (2011), doi:10.1016/J.Ijggc.2011.02.003
Johnson, G., Mayer, B., Nightingale, M., Shevalier, M., Hutcheon, I.: Using oxygen isotope ratios to quantitatively assess trapping mechanisms during CO2 injection into geological reservoirs: The Pembina case study. Chem. Geol. 283(3-4), 185–193 (2011), doi:10.1016/J.Chemgeo.2011.01.016
Kharaka, Y.K., Cole, D.R., Hovorka, S.D., Gunter, W.D., Knauss, K.G., Freifeld, B.M.: Gas-water-rock interactions in Frio Formation following CO2 injection: Implications for the storage of greenhouse gases in sedimentary basins. Geology 34(7), 577–580 (2006), doi:10.1130/G22357.1
Mayer, B., Shevalier, M., Nightingale, M., Kwon, J.S., Johnson, G., Raistrick, M., Hutcheon, I., Perkins, E.: Tracing the movement and the fate of injected CO2 at the IEA GHG Weyburn-Midale CO2 monitoring and storage project (Saskatchewan, Canada) using carbon isotope ratios. Int. J. Greenh. Gas Con. (submitted)
Shevalier, M., Durocher, K., Perez, R.J., Hutcheon, I., Mayer, B., Perkins, E., Gunter, B.: Geochemical monitoring of gas-water-rock interaction at the iea Weyburn CO2 Monitoring and Storage Project, Saskatchewan, Canada. In: Rubin, E.S., Keith, D.W., Gilboy, C.F., et al. (eds.) Greenhouse Gas Control Technologies 7, pp. 2135–2139. Elsevier Science Ltd., Oxford (2005)
Hovorka, S.D., Benson, S.M., Doughty, C., Freifeld, B.M., Sakurai, S., Daley, T.M., Kharaka, Y.K., Holtz, M.H., Trautz, R.C., Nance, H.S., Myer, L.R., Knauss, K.G.: Measuring permanence of CO2 storage in saline formations: The Frio experiment. Environmental Geosciences 13(2), 105–121 (2006)
Freifeld, B.M., Trautz, R.C., Kharaka, Y.K., Phelps, T.J., Myer, L.R., Hovorka, S.D., Collins, D.J.: The U-tube: A novel system for acquiring borehole fluid samples from a deep geologic CO2 sequestration experiment. J. Geophys. Res.-Sol. Ea. 110(B10) (2005), doi:Artn B10203
Shevalier, M., Nightingale, M., Johnson, G., Mayer, B., Perkins, E., Hutcheon, I.: Monitoring the reservoir geochemistry of the Pembina Cardium CO2 monitoring project, Drayton Valley, Alberta. Energy Procedia 1(1), 2095–2102
Vogel, J.C., Grootes, P.M., Mook, W.G.: Isotopic fractionation between gaseous and dissolved carbon dioxide. Zeitschrift für Physik 230(3), 225–238 (1970)
Stalker, L., Boreham, C., Underschultz, J., Freifeld, B., Perkins, E., Schacht, U., Sharma, S.: Geochemical monitoring at the CO2CRC Otway Project: tracer injection and reservoir fluid acquisition. Energy Procedia 1, 2119–2125 (2009)
Martens, S., Kempka, T., Liebscher, A., Lüth, S., Möller, F., Myrttinen, A., Norden, B., Schmidt-Hattenberger, C., Zimmer, M., Kühn, M.: Europe’s longest-operating on-shore CO2 storage site at Ketzin, Germany: a progress report after three years of injection. Environmental Earth Sciences 67(2), 323–334 (2012)
Förster, A., Norden, B., Zinck-Jörgensen, K., Frykman, P., Kulenkampff, J., Spangenberg, E., Erzinger, J., Zimmer, M., Kopp, J., Borm, G., Juhlin, C., Cosma, C.G., Hurter, S.: Baseline characterization of the CO2SINK geological storage site at Ketzin, Germany. Environmental Geosciences 13(3), 145–161 (2006)
Myrttinen, A., Becker, V., van Geldern, R., Wurdemann, H., Morozova, D., Zimmer, M., Taubald, H., Blum, P., Barth, J.A.C.: Carbon and oxygen isotope indications for CO(2) behaviour after injection: First results from the Ketzin site (Germany). Int. J. Greenh. Gas Con. 4(6), 1000–1006 (2010), doi:10.1016/J.Ijggc.2010.02.005
Wiese, B., Zimmer, M., Nowak, M., Pilz, P.: Above-zone well-based hydraulic and geochemical monitoring of the CO2 reservoir in Ketzin, Germany. Environmental Earth Sciences (Special Issue Geoenergy) (2012) (submitted)
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Nowak, M., Myrttinen, A., van Geldern, R., Becker, V., Mayer, B., Barth, J.A.C. (2013). A Brief Overview of Isotope Measurements Carried Out at Various CCS Pilot Sites Worldwide. In: Hou, M., Xie, H., Were, P. (eds) Clean Energy Systems in the Subsurface: Production, Storage and Conversion. Springer Series in Geomechanics and Geoengineering. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-37849-2_7
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DOI: https://doi.org/10.1007/978-3-642-37849-2_7
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