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Nanoenergy pp 153–177Cite as

Nanocomposites from V2O5 and Lithium Ion Batteries

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Abstract

In this chapter, V2O5 xerogel and nanocomposites of V2O5 and polymers as well as the charge storage properties are described and discussed, aiming their use as cathode for lithium ion batteries. First, the different synthesis methods are presented, emphasizing the sol–gel methods via vanadates and vanadium alkoxides. Structural aspects are briefly mentioned to a better comprehension of lithium ion insertion/deinsertion, which influence on the electrochemical properties, and consequently, on the charge capacity of electrodes formed of V2O5. Nanostructured materials such as nanorolls, nanobelts, nanowires, and ordered nanorods arrays have been prepared and studied to increase the specific capacity, energy density, and power density. Moreover, the intimate contact between the nanocomposite components can also guarantee the enhancement of these properties so that these materials can be used in lithium ion batteries. Intermolecular interactions are also investigated to explain the performance of these positive electrodes. Various polymers have been used in these nanomaterials to increase the electronic conductivity as well as the ionic diffusion, and/or electrochemical stability.

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Acknowledgments

Financial support from FAPESP, CNPq, and Capes is gratefully acknowledged.

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Authors and Affiliations

  1. Departamento de Química, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Ribeirão Preto–SP, 14040-901, Brazil

    Fritz Huguenin & Ana Rita Martins

  2. Instituto de Química, Universidade de São Paulo, CP 26077, São Paulo–SP, 05513-970, Brazil

    Roberto Manuel Torresi

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  1. Fritz Huguenin
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  2. Ana Rita Martins
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Correspondence to Fritz Huguenin .

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  1. , Centro de Ciências Naturais e Humanas., Universidade Federal do ABC, Rua Santa Adélia 166, Santo André, 09210-170, Brazil

    Flavio Leandro de Souza

  2. , CCET - Depart. de Química, Universidade Federal de Sao Carlos, Rodovia Washington Luis, km 235, São Carlos (SP), 13565-905, Brazil

    Edson Roberto Leite

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Huguenin, F., Martins, A.R., Torresi, R.M. (2013). Nanocomposites from V2O5 and Lithium Ion Batteries. In: de Souza, F., Leite, E. (eds) Nanoenergy. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-31736-1_6

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