Abstract
The difference in charges on the even and odd carbon atoms in the chain and the ring, and in the positive charge on the hydrogen atoms, and the existence of the essentially unshared 2s2(c)-electron pair on the carbon atom result in the formation of specific interactions in the saturated and unsaturated linear and cyclic hydrocarbons. The characteristic feature of the hydrocarbons consists in the formation by ethane and butane, and ethylene and butylenes, respectively, of dissimilar types of specific interactions existing together in liquid propane, pentane, propylene, and pentene and further in the members of their homologous series. The energies were estimated of the unlike two types of specific interactions in alkanes, alkenes, and alkynes remaining practically constant throughout all the compounds in the homologous series. The increase in the vaporization enthalpy is determined by the practically equivalent contribution of the growing number of CH2 or CH groups. The energies of the specific interactions in the cyclic hydrocarbons and the energies of the interactions formed by the isostructural methyl groups were estimated.
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Baev, A.K. (2012). Specific Intermolecular Interactions of Hydrocarbons. In: Specific Intermolecular Interactions of Organic Compounds. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-21622-0_8
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DOI: https://doi.org/10.1007/978-3-642-21622-0_8
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