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Applications of Short-Lived Radionuclides (7Be, 210Pb, 210Po, 137Cs and 234Th) to Trace the Sources, Transport Pathways and Deposition of Particles/Sediments in Rivers, Estuaries and Coasts

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Handbook of Environmental Isotope Geochemistry

Part of the book series: Advances in Isotope Geochemistry ((ADISOTOPE))

Abstract

Natural and anthropogenic radioisotopes can be used to determine not only the mixing and diffusion processes of water masses but also the sources and sedimentary dynamics of particles in aquatic systems such as rivers, estuaries and oceans. Particle-reactive radionuclides that are derived from atmospheric deposition and/or the decay from their parent nuclides in aqueous system, can be used to determine the removal rates of suspended particulate matter, sediment focusing/erosion, sediment resuspension rates and sediment accumulation and mixing rates. They can be also used as analogs for tracing the transport and fates of other particle-reactive contaminants, such as PCBs and PAH. In this chapter, we focus on various applications of short-lived radionuclides (i.e., 7Be, 210Pb, 210Po, 137Cs and 234Th) as tracers for particle and sediment dynamics to quantify several river, estuary and coastal oceanic processes with their concerned timescales ranging from a few days to about 100 years.

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Acknowledgments

This work was funded by the Natural Science Foundation of China (41021064; 40976054) and the Ministry of Science and Technology of PR China (2011CB409801). We thank the two reviewers (Chih-An Huh and Brent A. McKee) for their critical reviews of the earlier version of this manuscript.

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Correspondence to J. Z. Du .

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Appendix: Descriptions of symbols and abbreviation used in this chapter

Appendix: Descriptions of symbols and abbreviation used in this chapter

Symbols

Meaning

Unit

\( {A_{Th}}/{A_{Be}}/{A_{Pb}} \)

Activity of excess 234Th/7Be/excess 210Pb in the water column

Bq cm−3

\( A_{Th}^p/A_{_{Be}}^p/A_{Pb}^p \)

Activity of excess 234Th/7Be/excess 210Pb in the particulate phase

Bq g−1 or Bq cm−3

\( A_{Th}^d/A_{_{Be}}^d/A_{Pb}^d \)

Activity of 234Th/7Be/210Pb in the dissolved phase

Bq cm−3

\( A_{_{Th}}^{sed}/A_{_{Be}}^{sed}/A_{Pb}^{sed} \)

Activity of excess 234Th/7Be/excess 210Pb in surficial bottom sediments subject to resuspension

Bq g−1

\( A_{_{Th}}^{adv}/A_{_{Be}}^{adv}/A_{Pb}^{sdv} \)

Activity of excess 234Th/7Be/excess 210Pb on advected particles

Bq g−1

\( A_{_{Th}}^{resus}/A_{_{Be}}^{resus}/A_{Pb}^{resus} \)

Activity of excess 234Th/7Be/excess 210Pb on resuspension particles from sea bed

Bq g−1

\( A_{_{Th}}^{trap}/A_{_{Be}}^{trap}/A_{Pb}^{trap} \)

Activity of excess 234Th/7Be/excess 210Pb on settling particles collected by sediment trap

Bq g−1

\( {\lambda_{Th}}/{\lambda_{Be}}/{\lambda_{Pb}} \)

Decay constant of 234Th/7Be/210Pb

day−1

\( {k_{Th}}/{k_{Be}}/{k_{Pb}} \)

Rate constant for the scavenging of dissolved 234Th/7Be/210Pb onto particles

day−1

\( {\kappa_{Th}}/{\kappa_{Be}}/{\kappa_{Pb}} \)

Removal rate constant of excess 234Th/7Be/excess 210Pb in the water column

day−1

\( \varphi_{Th}/\varphi_{Be}/\varphi_{Pb} \)

Removal flux of excess 234Th and 7Be and excess 210Pb from water column

Bq cm−3 day−1

\( \varphi_{Th}^p/\varphi_{Be}^p/\varphi_{Pb}^p \)

Removal flux of particulate excess 234Th and 7Be and excess 210Pb from water column to the sea bed

Bq cm−3 day−1

\( \kappa_{Th}^p/\kappa_{Be}^p/\kappa_{Pb}^p \)

Removal rate constant of particulate excess 234Th/7Be/excess 210Pb in the water column

day−1

\( {I_{\rm{Be}}}/{I_{Pb}} \)

7Be/210Pb atmospheric deposition flux

Bq cm−2 day−1

\( {A_U}/{A_{Ra}} \)

Activity of 238U/226Ra in the water column

Bq cm−3

h

Water depth

cm

\( \varphi_{Th}^{resus}/\varphi_{Be}^{resus}/\varphi_{Pb}^{resus} \)

Resuspension flux of particulate excess 234Th and 7Be and excess 210Pb from the sea bed

Bq cm−3 day−1

\( \varphi_{Th}^{adv}/\varphi_{Be}^{adv}/\varphi_{Pb}^{advs} \)

Advective flux of particulate excess 234Th and 7Be and excess 210Pb

Bq cm−3 day−1

\( \varphi_{Th}^{prod}/\varphi_{Be}^{prod}/\varphi_{Pb}^{prod} \)

Supply flux of excess 234Th and 7Be and excess 210Pb from 238U decay or the atmosphere (7Be, 210Pb) followed by rapid scavenging fluxes

Bq cm−3 day−1

\( \varphi_{Th}^{total}/\varphi_{Be}^{total}/\varphi_{Pb}^{total} \)

Total supply flux of particulate excess 234Th/7Be/excess 210Pb into turbidity maximum zone

Bq cm−3 day−1

\( \phi_{Th}^{resus}/\phi_{Be}^{resus}/\phi_{Pb}^{resus} \)

Sediment resuspension flux by excess 234Th and 7Be and excess 210Pb from the sea bed

g cm−2 day−1

\( \phi_{part}^{resus}/\phi_{part}^{adv}/\phi_{part}^{total} \)

Particle flux from resuspension/advective input/total input

g cm−3 day−1

\( \phi^{sed}/\phi^{er} \)

Sedimentary deposition/erosion flux

g cm−2 day−1

\( {\tau_{Pb}} = 1/{\kappa_{Pb}} \)

Residence times for total 210Pb in the water column

Day

\( \nu \)

Horizontal flux constant

cm day−1

\( \varphi_{Be}^{river}/\varphi_{Pb}^{river} \)

Riverine input particulate 7Be and excess 210Pb

Bq cm−3 day−1

\( \varphi_{Be}^{out}/\varphi_{Pb}^{out} \)

Riverine output flux of particulate 7Be and excess 210Pb

Bq cm−3 day−1

C PCB/PAH

Concentration of PCB/PAH in mixing layer of water column

g m−3

\( \phi_{PCB/PAH} \)

Vertical flux of PCB/PAH from mixing layer of water column

g cm−3 day−1

AMP

Amaniamolybdenum (III) phosphate

 

SPM

Suspended particle matter

 

PCB

Polychlorinated biphenyl

 

PAH

Polycyclic aromatic hydrocarbons

 

LSS

Liquid scintillation spectrometry

 

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© 2012 Springer-Verlag Berlin Heidelberg

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Du, J.Z., Zhang, J., Baskaran, M. (2012). Applications of Short-Lived Radionuclides (7Be, 210Pb, 210Po, 137Cs and 234Th) to Trace the Sources, Transport Pathways and Deposition of Particles/Sediments in Rivers, Estuaries and Coasts. In: Baskaran, M. (eds) Handbook of Environmental Isotope Geochemistry. Advances in Isotope Geochemistry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-10637-8_16

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