Abstract
Several DTA and TGA instruments used to study the kinetics of fast high-temperature reactions in condensed phases of energetic materials over a wide range of temperatures and pressures are described. The design of new experimental cells used in original approaches to the “thermal and mechanical dilution” of the sample with inert heat-conducting material is discussed in detail. Due to the special cell design, the sample is spatially isothermal and even very fast exothermal reactions do not result in self-inflammation.The use of the special cell in combination with commercial DTA, TGA and DSC instruments allows one to increase the upper limit of measurable reaction rates by several orders of magnitude.
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Kolesov YuR (1970) PhD thesis. Institute of Chemical Physics of the USSR Academy of Sciences, Chernogolovka, Russia
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© 2008 Springer-Verlag Berlin Heidelberg
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Shteinberg, A.S. (2008). Equipment for Studying Kinetics During~Linear~Heating. In: Fast Reactions in Energetic Materials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-78861-4_7
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DOI: https://doi.org/10.1007/978-3-540-78861-4_7
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-78860-7
Online ISBN: 978-3-540-78861-4
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