Abstract
This volume represents the proceedings of The Second International Workshop on Materials Processing at High Gravity, hosted by Clarkson University in June of 1993. Evidence continues to demonstrate the unique and advantageous features of centrifugation during materials processing.
In this book, the symbol “g” is sometimes used to represent Earth’s gravity and other times, especially in equations and dimensionless numbers, g designates the total acceleration vector. When g represents Earth’s gravity, then the magnitude of the total acceleration is expressed by Ng, where N is any positive number.
Through a combination of experiments and theory, we are gaining an understanding of centrifugation on phenomena of importance to materials processing. We find that it is necessary to consider not only acceleration, but also the Coriolis effect and the variation of acceleration with position. As one consequence, the vigor of buoyancy-driven convection is sometimes increased by centrifugation and sometimes decreased. Similarly, the tendency of the convection to become unstable or oscillatory may either be increased or decreased by centrifugation. On the other hand, the observed effects of centrifugation on product quality have largely gone unexplained. In this introduction, we summarize our current understanding of centrifugation effects as gained from the Workshop and the papers in this volume. We conclude with recommendations for future research efforts.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
H. Rodot, L.L. Regel, G.V. Sarafanov, H. Hamidi, I.V. Videskii, and A.M. Turtchaninov, Cristaux de tellurure de plomb elabores en centrifugeuse, J. Crystal Growth 79:77 (1986).
H. Rodot, L.L. Regel, and A.M. Turtchaninov, Crystal growth of IV-VI semiconductors in a centrifuge, J. Crystal Growth 104:280 (1990).
L.L. Regel, M. Rodot, and W.R. Wilcox, editors, “Material Processing in High Gravity, Proceedings of the First International Workshop on Material Processing in High Gravity,” North-Holland, Amsterdam (1992). Also volume 119 of the Journal of Crystal Growth.
G. Müller, E. Schmidt, and P. Kyr, Investigation of convection in melts and crystal growth under large inertial accelerations, J. Crystal Growth 49:387 (1980).
G. Müller, Crystal growth at greater than 1 g, in: “ESA Special Publication No. 114,” European Space Agency, Paris (1980) pp 213–216.
G. Müller and G. Neumann, Suppression of doping striations in zone melting of InSb by enhanced convection on a centrifuge, J. Crystal Growth 59:548 (1982).
G. Müller, Convection in melts and crystal growth, in: “Convective Transport and Instability Phenomena,” J. Zierep and H. Oertel, Jr., eds., Braun Verlag, Karlsruhe (1982).
G. Müller, “Uber die Enstehung von Inhomogenitaten in Halbleiterkristallen bei der Herstellung aus Schmelzen,” Selisch Fachbuch-Verlag, Langensendelbach (1986) pp 151–165.
G. Müller, A comparative study of crystal growth phenomena under reduced and enhanced gravity, J. Crystal Growth 99:1242 (1990).
W. Weber, G. Neumann, and G. Müller, Stabilizing influence of the Coriolis force during melt growth on a centrifuge, J. Crystal Growth 100:145 (1990).
G. Müller, G. Neumann, and W. Weber, The growth of homogeneous semiconductor crystals in a centrifuge by the stabilizing influence of the Coriolis force, J. Crystal Growth 119:8 (1992).
A. Chevy, P. Williams, M. Rodot, and G. Labrosse, Removal of convective instabilities in liquid metals by centrifugation, present volume.
B. Zhou, F. Cao, L. Lin, W. Ma, Y. Zheng, F. Tao, and M. Xue, Growth of GaAs at high gravity, present volume.
W.J. Ma, F. Tao, Y. Zheng, M.L. Xue, B.J. Zhou, and L.Y. Lin, Response of temperature oscillations in a tin melt to centrifugal effects, present volume.
F. Tao, Y. Zheng, W.J. Ma, and M.L. Xue, Unsteady thermal convection of melts in a 2-D horizontal boat in a centrifugal field with consideration of the Coriolis effect, present volume.
C.E. Chang, V.F.S. Yip, and W.R. Wilcox, Vertical gradient freeze growth of gallium arsenide and naphthalene: theory and practice, J. Crystal Growth 22:247 (1974).
C.E. Chang and W.R. Wilcox, Control of interface shape in the vertical Bridgman-Stockbarger technique, J. Crystal Growth 21:135 (1974).
S. Sen and W.R. Wilcox, Influence of crucible on interface shape, position and sensitivity in the vertical Bridgman-Stockbarger technique, J. Crystal Growth 28:36 (1975).
T.W. Fu and W.R. Wilcox, Influence of insulation on stability of interface shape and position in the vertical Bridgman-Stockbarger technique, J. Crystal Growth 48:416 (1980).
G.T. Neugebauer and W.R. Wilcox, Convection in the vertical Bridgman-Stockbarger technique, J. Crystal Growth 89:143 (1988).
S. Motakef, Interference of buoyancy-induced convection with segregation during directional solidification: scaling laws, J. Crystal Growth 102:197 (1990).
L.L. Regel et al., Effect of increased gravity on the structure of directionally solidified aluminum-copper eutectic, Fiz. Khim. Obrab. Mater 45 (1989).
L.L. Regel, A.M. Turchaninov, R.V. Parfeniev, I. Farbshtein, N.K. Shulga, S.V. Nikitin, and S.V. Yakimov, “Electrofizicheskie Svoictva Monokristallov Tellura i Splava Te1-xSex, Poluchennikh v Usloviyakh pri Vishennoi Gravitatsii (5 go i 10 go),” USSR Space Research Institute, Moscow (July 1989).
L.L. Regel, I.V. Videnskii, V.V. Zubenko, I.M. Cafonova, and I.V. Telegina, Vliyanie povishennoi gravitatsii na strukturu napravlenno — za kristallizovannik evtektik alyominii — medi, Fizika i Chimiya Obrabotki Materialov 23:45 (1989).
P. Bartsi, L.L. Regel, and I. Solyom, in: “Proceedings of the 4th Intercosmos Seminar on Cosmic Materials and Technologies,” Bucharest (1989) pp 117–137.
B.V. Burdin, L.L. Regel, A.M. Turchaninov, and O.V. Shumaev, The peculiarities of material crystallization experiments on the CF-18 centrifuge in high gravity, J. Crystal Growth 119:61 (1992).
L.L. Regel and O.V. Shumaev, GaSb directional solidification in high gravity conditions, J. Crystal Growth 119:70 (1992).
P. Barczy, J. Solyom, and L.L. Regel, Solidification AlNi(Cu) eutectics at high gravity, J. Crystal Growth 119:160 (1992).
L.L. Regel et al., Te and Te-Se alloy crystal growth under higher gravity, J. Phys. France 2:373 (1992).
Z. Chvoj and C. Barta, Remark on the influence of gravitation on the solidification of the binary systems, Czech. J. Phys. B 36:868 (1986).
C. Barta, F. Fendrych, E. Krcova, and A. Triska, Directional solidification of complex-forming eutectic melt of the lead dichloride — silver chloride dielectric system under conditions of zero, normal and increased gravity, Adv. Space Res. 8:167 (1988). Also, in: “Proceedings of the 4th Intercosmos Seminar on Cosmic Materials and Technologies,” V. Lupei and D. Toma, eds., Rumanian Academy of Science, Bucharest (1989).
W. Arnold, W.R. Wilcox, F. Carlson, A. Chait, and L.L. Regel, Transport modes during crystal growth in centrifuge, J. Crystal Growth 119:24 (1992).
W.A. Arnold, W.R. Wilcox, F. Carlson, L.L. Regel, and A. Chait, Row mode transitions during crystal growth in a centrifuge, J. Crystal Growth (submitted).
W. Arnold, W. Wilcox, F. Carlson, A. Chait, and L. Regel, Crystal growth of semiconductor compounds in a centrifuge, in: “Proceedings of the Society of Engineering Science,” Gainesville (November 1991).
W. Arnold, “Numerical Modeling of Directional Solidification in a Centrifuge,” PhD Thesis, Clarkson University (1993).
W.A. Arnold and L.L. Regel, Thermal stability and the suppression of convection in a rotating fluid on earth, present volume.
M.A. Fikri, G. Labrosse, and M. Betrouni, The melt phase hydrodynamics for the “stabilized” Bridgman procedure applied under centrifugation; preliminary analysis and numerical results, J. Crystal Growth 119, 41–60 (1992).
V.A. Urpin, Convective flows during crystal growth in a centrifuge, present volume.
P.A. Vorobiov, N.A. Baturin, and O.V. Shumaev, Laminar convection in the melt during crystal growth in a centrifuge, J. Crystal Growth 119:111 (1992).
R. Derebail, W.R. Wilcox, and L.L. Regel, Directional solidification of InSb in a centrifuge, J. Crystal Growth 119:98 (1992).
R. Derebail, W.R. Wilcox, and L.L. Regel, The influence of gravity on the directional solidification of indium antimonide, J. Spacecraft & Rockets 30:202 (1993).
R. Derebail, “Study of Directional Solidification of InSb under Low, Normal and High Gravity,” M.S. Thesis, Clarkson University (1990).
R. Derebail, “Directional Solidification of InSb in the Centrifuge,” PhD Thesis, Clarkson University (1994).
L.I. Farbshtein, R.V. Parfeniev, S.V. Yakimov, L.L. Regel, R. Derebail, and W.R. Wilcox, Analysis of impurity distribution by galvanomagnetic method in InSb obtained under high gravity conditions, present volume.
L.I. Farbshtein, R.V. Parfeniev, N.K. Shulga, and L.L. Regel, Variation of effective impurity segregation coefficient in tellurium grown under high gravity, present volume.
R.N. Grugel, A.B. Hmelo, C.C. Battaile, and T.G. Wang, Microstructural development in Pb-Sn alloys subjected to high gravity during controlled directional solidification, present volume.
L.L. Regel, A.M. Turchaninov, O.V. Shumaev, I.N. Bandeira, C.Y. An, and P.H.O. Rappl, Growth of lead-tin telluride crystals in high gravity, J. Crystal Growth 119:94 (1992).
Y.A. Chen, I.N. Bandeira, A.H. Franzan, S. Eleutério Filho, and M.R. Slomka, The influence of gravity on Pb1-xSnxTe crystals grown by the vertical Bridgman method, present volume.
A. Chevy, Cristallogenese du germanium en centrifugeuse, Compte Rendue Acad. Sci. Paris 307:1147 (1988).
A. Chevy, Private Communication, Universite Pierre et Marie Curie, Paris, France (1990).
T. Lee, J.C. Moosbrugger, F.M. Carlson, and DJ. Larson, Jr., The role of thermal stress in vertical Bridgman growth of CdZnTe crystals, present volume.
M.P. Volkov, B.T. Melekh, R.V. Parfeniev, N.F. Kartenko, and L.L. Regel, Properties of superconducting Bi-Sr-Ca-Cu-O system remelted under high gravity conditions, J. Crystal Growth 119:122 (1992).
H. Wiedemeier, L.L. Regel, and W. Palosz, Vapor transport and crystal growth of GeSe under normal and high acceleration, J. Crystal Growth 119:79 (1992).
J.C. Launay, S. Bouchet, A. Randriamampianina, P. Bontoux, and P. Gibart, Epitaxial growth on a GaAs hemisphere substrate at 1 g and under hypergravity, present volume.
J. Chen, J.M. Most, P. Joulain, and D. Durox, Fire behavior in macrogravity, present volume.
J. Domey, D.K. Aidun, G. Ahmadi, L.L. Regel, and W.R. Wilcox, Numerical simulation of the effect of gravity on weld pool shape, present volume.
T. Hibiya, S. Nakamura, K.W. Yi, and K. Kakimoto, Coriolis effect on heat transfer experiment using hot-wire technique on centrifuge, present volume.
K.O. Pedersen, Uber das Sedimentationsgleichgewicht von anorganischen Salzen in der Ultrazentrifuge, Z. Phys. Chem. A170:41 (1934).
D.J. Cox, Computer simulation of sedimentation in the ultracentrifuge. III. Concentration-dependent sedimentation, Arch. Biochem. Biophys. 119:230 (1967).
W.R. Wilcox and P. Shlichta, Movement of crystal inclusions in a centrifugal field, J. Appl. Phys. 42:1823 (1971).
W.R. Wilcox, Movement of liquid inclusions by centrifugation, J. Crystal Growth 13/14:787 (1972).
T.R. Anthony and H.E. Cline, The kinetics of droplet migration in solids in an accelerational field, Phil Mag. 22:893 (1970).
P.J. Shlichta, Crystal growth and materials processing above 1000 g, J. Crystal Growth 119:1 (1992).
P.J. Shlichta and R.E. Knox, Growth of crystals by centrifugation, J. Crystal Growth 3/4:808 (1968).
M.Y.D. Lanzerotti, J. Autera, J. Pinto, and J. Sharma, Crystal growth of energetic materials during high acceleration using an ultracentrifuge, present volume.
R.S. Sokolowski, “Gravitational influence on binary alloy melt equilibria and eutectic solidification,” Ph.D. Thesis, Rensselaer Polytechnic Institute, Troy, NY (1981).
M.E. Glicksman and R.S. Sokolowski, Gravitational influence on binary alloy melt equilibria, Adv. Space Res. 3:129 (1983).
R.S. Sokolowski and M.E. Glicksman, Gravitational influence on eutectic solidification, J. Crystal Growth 119:126 (1992).
D.T. Hayhurst, PJ. Melling, W.J. Kim, and W. Bibbey, in: “Zeolite Synthesis,” M.L. Occelli and H.E. Robson, eds., American Chemical Society (1989) ch 17.
W J. Kim, “The Effect of Elevated Gravity on the Crystallization of the MFI Zeolites, ZSM-5 and Silicalite,” Ph.D. Thesis, Cleveland State University, Cleveland, Ohio (1989); through Chem. Abstr. 112:219459 (1990).
D.T. Hayhurst, W.J. Kim, and PJ. Melling, “Crystal Growth in Enhanced Gravitational field,” US Patent Application 233,287 (1988); PCT Int. Appl. WO 90 02,221 (1990); through Chem. Abstr. 113:32438 (1990).
V.A. Briskman, K.G. Kostarev, and T.P. Lyubimova, Gel polymerization at high gravity, present volume.
J. Garnier and L.M. Cottineau, Questions raised about material processing in a centrifuge: lessons derived from the LCPC’s experience, J. Crystal Growth 119:66 (1992).
R. Derebail, W.A. Arnold, G.J. Rosen, W.R. Wilcox, and L.L. Regel, HIRB — the centrifuge facility at Clarkson, present volume.
M.J. Paulin, R. Phillips, J.I. Clark, R. Meaney, D. Millan, and K. Tuff, Establishment of the new C-CORE centrifuge center, present volume.
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1994 Springer Science+Business Media New York
About this chapter
Cite this chapter
Regel, L.L., Wilcox, W.R. (1994). Introduction to Materials Processing in Large Centrifuges. In: Regel, L.L., Wilcox, W.R. (eds) Materials Processing in High Gravity. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-2520-2_1
Download citation
DOI: https://doi.org/10.1007/978-1-4615-2520-2_1
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-6073-5
Online ISBN: 978-1-4615-2520-2
eBook Packages: Springer Book Archive