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Abstract

In this chapter, we summarize notable problems that are unresolved and also try to predict future prospects of amorphous chalcogenides.

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S and Se

  • Cook, B.E., Spear, W.E.: The optical properties of orthorhombic sulphur crystals in the vacuum ultraviolet. J. Phys. Chem. Solids 30, 1125–1134 (1969)

    Article  CAS  Google Scholar 

  • Zingaro, R.A., Cooper, W.C.: Selenium, Van Nostrand Reinhold, New York, NY (1974)

    Google Scholar 

  • Nielsen, P.: Photoemission studies of sulfur. Phys. Rev. B 10, 1673–1682 (1974)

    Article  CAS  Google Scholar 

  • Salaneck, W.R., Lipari, N.O., Paton, A., Zallen, R., Liang, K.S.: Electronic structure of S8. Phys. Rev. B 12, 1493–1500 (1975)

    Article  CAS  Google Scholar 

  • Robins, L.H., Kastner, M.A.: Recombination and excited-state absorption at photoluminescence centres in crystalline and amorphous arsenic triselenide. Philos. Mag. B 50, 29–51 (1984)

    Article  CAS  Google Scholar 

  • Abass, A.K., Ahmad, N.H.: Absorption edge of pure and selenium-doped α-sulfur single crystals. Phys. Status Solidi (a) 91, 627–630 (1985)

    Google Scholar 

  • Oda, S., Kastner, M.A.: Transient photoluminescence and photo-induced optical absorption in polymeric and crystalline sulphur. Philos. Mag. B 50, 373–377 (1984)

    Article  CAS  Google Scholar 

  • Nagata, K., Miyamoto, Y., Nishimura, H., Suzuki, H., Yamasaki, S.: Photoconductivity and photoacoustic spectra of trigonal, rhombohedral, orthorhombic, and α-, β-, and γ-monoclinic selenium. Jpn. J. Appl. Phys. 24, L858–L860 (1985)

    Article  CAS  Google Scholar 

  • Lundt, H., Weiser, G.: Defect luminescence and its excitation spectra in As-doped Se single crystals. Philos. Mag. B 51, 367–380 (1985)

    Article  CAS  Google Scholar 

  • Chen, C.Y., Kastner, M.A., Robins, L.H.: Transient photoluminescence and excited-state optical absorption in trigonal selenium. Phys. Rev. B 32, 914–917 (1985)

    Article  CAS  Google Scholar 

  • Chen, C.Y., Kastner, M.A.: Transient photoinduced optical absorption spectroscopy in trigonal selenium. Phys. Rev. B 33, 1073–1075 (1986)

    Article  CAS  Google Scholar 

  • Povoa, J.M., Leal Ferreira, G.F.: Anomalies in the electronic time-of-flight current trace in sulfur. Phys. Rev. B 47, 1610–1612 (1993)

    Article  CAS  Google Scholar 

As2S(Se)3

  • Evans, B.L., Young, P.A.: Optical properties of arsenic trisulphide. Proc. R. Soc. A297, 230–243 (1967)

    Google Scholar 

  • Kolomiets, B.T., Mamontova, T.N., Babaev, A.A.: Radiative recombination in vitreous and single crystal As2S3 and As2Se3. J. Non-Cryst. Solids 4, 289–294 (1970)

    Article  CAS  Google Scholar 

  • Drews, R.E., Emerald, R.L., Slade, M.L., Zallen, R.: Interband spectra of As2S3 and As2Se3 crystals and glasses. Solid State Commun. 10, 293–296 (1972)

    Article  CAS  Google Scholar 

  • Zallen, R., Slade, M.: Rigid-layer modes in chalcogenide crystals. Phys. Rev. B 9, 1627–1637 (1974)

    Article  CAS  Google Scholar 

  • Zallen, R., Blossey, D.F.: The optical properties, electronic structure, and photoconductivity of arsenic chalcogenide layer crystals. Physics and Chemistry of Materials with Layered Structures, edited by E. Mooser (D. Reidel Publishing Company, Dordrecht, 1976) pp. 231–272.

    Google Scholar 

  • Smith, B.A., Cowlam, N., Shamah, A.M.: The crystal growth and atomic structure of As2(Se,S)3 compounds. Philos. Mag. B 39, 111–132 (1979)

    Article  CAS  Google Scholar 

As2S3

  • Morimoto, N.: The crystal structure of orpiment (As2S3) refined. Mineralogical J. 1, 160–169 (1954)

    CAS  Google Scholar 

  • Mullen, D.J.E., Nowacki, W.: Refinement of the crystal structure of realgar, AsS and orpiment, As2S3. Z. Kristallogr. 136, 48–65 (1972)

    Article  CAS  Google Scholar 

  • Lisitra, M.P., Berezhinsky, L.I., Valakh, M.Ya., Yaremko, A.M.: Exciton peculiarities in the As2S3 layer crystal. Phys. Lett. 42A, 51–52 (1972)

    Google Scholar 

  • Perrin, J., Cazaux, J., Soukiassians, P.: Optical constants and electronic structure of crystalline and amorphous As2S3 in the 3 to 35 eV range. Phys. Status Solidi (b) 62, 343–350 (1974)

    Article  CAS  Google Scholar 

  • Blossey, D.F., Zallen, R.: Surface and bulk photoresponse of crystalline As2S3. Phys. Rev. B 9, 4306–4313 (1974)

    Article  CAS  Google Scholar 

  • Schein, L.B.: Temperature independent drift mobility along the molecular direction of As2S3. Phys. Rev. B 15, 1024–1034 (1977)

    Article  CAS  Google Scholar 

  • Murayama K., Bösch, M.A.: Radiative recombination in crystalline As2S3. Phys. Rev. B 23, 6810–6812 (1981)

    Article  CAS  Google Scholar 

  • Rebenstorff, D., Weiser, G.: Electric-field-modulated spectra of orpiment (As2S3) near the energy gap. Philos. Mag. B 46, 207220 (1982)

    Article  Google Scholar 

  • Weistein, B.A.: Anomalous pressure studies of luminescence in c-As2S3 and a-As2SeS2: Consequences for defect structure in chalcogenides. Philos. Mag. B 50, 709–729 (1984)

    Article  Google Scholar 

  • Shimoi, Y., Fukutome, H.: Degeneracy in the crystal structure of As2S3. J. Phys. Soc. Jpn. 59, 1264–1276 (1990)

    Article  CAS  Google Scholar 

  • McNeil, L.E., Grimsditch, M.: Elastic constants of As2S3. Phys. Rev. B 44, 4174–4177(1991)

    Article  CAS  Google Scholar 

  • Zallen, R.: Effect of pressure on optical properties of crystalline As2S3. High Pressure Res. 24, 117–118 (2004)

    Article  CAS  Google Scholar 

  • Espeau, P., Tamarit, J.Li., Barrio, M., Lopez, D.O., Perrin, M.A., Allouchi, H., Ceolin, R.: Solid state studies on synthetic and natural crystalline arsenic(III) sulfide, As2S3 (orpiment): New data for an old compound. Chem. Mater. 18, 3821–3826 (2006)

    Article  CAS  Google Scholar 

  • Bonazzi, P., Bindi, L.: A crystallographic review of arsenic sulfides: Effects of chemical variations and changes induce by exposure to light. Z. Kristallogr. 223, 132–147 (2008)

    Article  CAS  Google Scholar 

  • Gibbs, G. V., Wallace, A. F., Zallen, R., Downs, R. T., Ross, N. L., Cox, D. F., Rosso, K. M.: Bond paths and van der Waals interactions in orpiment, As2S3. J. Phys. Chem. A 114, 6550–6557  (2010)  

    Article  CAS  Google Scholar 

As4S4

  • Street, G.B., Gill, W.D.: Photoconductivity and drift mobilities in single crystal realgar (As4S4). Phys. Status Solidi 18, 601–607 (1966)

    Article  CAS  Google Scholar 

  • Mullen, D.J.E., Nowacki, W.: Refinement of the crystal structures of realgar, AsS and orpiment As2S3. Z. Kristallogr. 136, 48–65 (1972)

    Article  CAS  Google Scholar 

  • Street, R.A., Austin, I.G., Searle, T.M.: Photoluminescence in chalcogenide crystals showing small polaron conduction; Orthorhombic sulphur and As4S4. J. Phys. C: Solid State Phys. 8, 1293–1300 (1975)

    Google Scholar 

As2Se3

  • Kitao, M., Asakura, N., Yamada, S.: Preparation of As2Se3 single crystals. Jpn. J. Appl. Phys. 8, 499–500 (1969)

    Article  CAS  Google Scholar 

  • Shaw, R.F., Liang, W.Y., Yoffe, A.D.: Optical properties, photoconductivity, and energy levels in crystalline and amorphous arsenic triselenide. J. Non-Cryst. Solids 4, 29–42 (1970)

    Article  CAS  Google Scholar 

  • Sussmann, R.S., Searle, T.M., Austin, I.G.: Absorption and electro-absorption in single-crystal As2Se3 near the fundamental edge. J. Phys. C: Solid State Phys. 8, L564–L568 (1975)

    Article  CAS  Google Scholar 

  • Marshall, J.M.: Electron transport in arsenic triselenide single crystals. J. Phys. C: Solid State Phys. 10, 1283–1290 (1977)

    Google Scholar 

  • Althaus, H.L., Weiser, G., Nagel, S.: Optical spectra and band structure of As2Se3. Phys. Status Solidi (b) 87, 117–128 (1978)

    Article  CAS  Google Scholar 

  • Sussmann, B.S., Searle, T.M., Austin, I.G.: The excitonic gaps and Urbach tail in crystalline As2Se3: Absorption and electroabsorption studies. Philos. Mag. B 44, 665–683 (1981)

    Article  CAS  Google Scholar 

  • Kanishcheva, A.S., Mikhailov, Yu.N., Zhukov, E.G., Grevtseva, T.G.: Redetermination of the crystal structure of As2Se3 and a comparison of the coordination of As(III) in chalcogenides and their analogs. Inorg. Mater. 19, 1744–1748 (1984)

    Google Scholar 

  • Marshall, J.M., Barclay, R.P., Main, C., Dunn, C.: The transient photodecay process and its interpretation in the case of disordered single crystals of arsenic triselenide. Philos. Mag. B 52, 997–1004 (1985)

    Article  CAS  Google Scholar 

  • Brunst, G., Weiser, G.: Defect-controlled conductivity in As2Se3 single crystals. Philos. Mag. B 51, 67–77 (1985)

    Article  CAS  Google Scholar 

  • Antonelli, A., Tarnow, E., Joannopoulos, J.D.: New insight into the electronic structure of As2Se3. Phys. Rev. B 33, 2968–2971 (1986)

    Article  CAS  Google Scholar 

  • Tarnow, E., Antonelli, A., Joannopoulos, J.D.: Crystalline As2Se3: Electronic and geometric structure. Phys. Rev. B 34, 4059–4073 (1986)

    Article  CAS  Google Scholar 

  • Tarnow, E., Antonelli, A., Joannopoulos, J.D.: Crystalline As2Se3: Optical properties. Phys. Rev. B 34, 8718–8727 (1986)

    Article  CAS  Google Scholar 

  • Kitao, M., Nishimoto, T., Yamada, S.: Emission and excitation spectra of photoluminescence of As2Se3 single crystals. Phys. Status Solidi(a) 103, K149–K152 (1987)

    Article  CAS  Google Scholar 

  • Ristein, J., Weiser, G.: Thermalization of excited carriers through band states studied by photoluminescence in As2Se3 and Se single crystals. Philos. Mag. B 56, 51–62 (1987)

    Article  CAS  Google Scholar 

  • Ristein, J., Weiser, G.: Recombination of germinate pairs in As2Se3 single crystals. Philos. Mag. B 54, 533–542 (1987)

    Article  Google Scholar 

  • Robins, L.H., Kastner, M.A.: Anomalous magnetic properties of triplet excited states in crystalline and amorphous arsenic triselenide. Phys. Rev. B 35, 2867–2885 (1987)

    Article  CAS  Google Scholar 

  • Ristein, J., Weiser, G.: Microscopic structure of the radiative centre in As2Se3 crystals. Solid State Commun. 66, 361–365 (1988)

    Article  CAS  Google Scholar 

  • Ristein, J., Taylor, P.C., Ohlsen, W.D., Weiser, G.: Radiative recombination center in As2Se3 as studied by optically detected magnetic resonance. Phys. Rev. B 42, 11845–11856 (1990)

    Article  CAS  Google Scholar 

GeS(Se)2

  • Inoue, K., Matsuda, O., Murase, K.: Raman spectra of tetrahedral vibrations in crystalline germanium dichalcogenides, GeS2 and GeSe2, in high and low temperature forms. Solid State Commun. 79, 905–910 (1991)

    Article  CAS  Google Scholar 

  • Ho, C.H., Lin, S.L., Wu, C.C.: Thermoreflectance study of the electronic structure of Ge(Se1−xSx)2. Phys. Rev. B 72, 125313 (2005)

    Article  Google Scholar 

GeS2

  • Zachariasen, W.H.: The crystal structure of germanium disulphide. J. Chem. Phys. 4, 618–619 (1936)

    Article  CAS  Google Scholar 

  • Prewitt, C.T., Young, H.S.: Germanium and silicon disulfides: Structure and synthesis. Science 149, 535–537 (1965)

    Article  CAS  Google Scholar 

  • Rubenstein, M., Roland, G.: A monoclinic modification of germanium disulfide, GeS2. Acta Crystallogr. B27, 505–506 (1971)

    Google Scholar 

  • Dittmar, Von G., Schäfer, H.: Die Kristallstructur von H.T.-GeS2. Acta Cryst. B31, 2060–2064 (1975)

    CAS  Google Scholar 

  • Saji, M., Kubo, H.: Electrical properties of GeS2 single crystals. Rept. Nagoya Inst. Technol. 32, 213–221 (1980) (in Japanese)

    CAS  Google Scholar 

  • Weinstein, B.A., Zallen, R., Slade, M.L.: Pressure-optical studies of GeS2 glasses and crystals: Implications for network topology. Phys. Rev. B 25, 781–792 (1982)

    Article  CAS  Google Scholar 

GeSe2

  • Aspens, D.E., Phillips, J.C., Tai, K.L.: Optical spectra and electronic structure of crystalline and glassy Ge(S,Se)2. Phys. Rev. B 23, 816–822 (1981)

    Article  Google Scholar 

  • Popović, Z.V.: Optical absorption band edge of single crystal β-GeSe2. Phys. Lett. A 110, 426–428 (1985)

    Article  Google Scholar 

  • Popović, Z.V., Gajić, R.: New vibrational modes in the far-infrared spectra of germanium diselenide. Phys. Rev. B 33, 5878–5879 (1986)

    Article  Google Scholar 

  • Nikolic, P.M., Todorovic, D.M., Vujatovic, S.S., Djuric, S., Mihailovic, P., Blagojevic, V., Radulovic, K.T., Bojicic, A.I., Vasiljevic-Radovic, D., Elazar, J., Urosevic, D.: Anisotropy in thermal and electronic properties of single crystal GeSe2 obtained by the photoacoustic method. Jpn. J. Appl. Phys. 37, 4925–4930 (1998)

    Google Scholar 

  • Popović, Z.V., Jakšić, Z., Raptis, Y.S., Anastassakis, E.: High-pressure Raman-scattering study of germanium diselenide. Phys. Rev. B 57, 3418–3422 (1998)

    Article  Google Scholar 

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Correspondence to Keiji Tanaka .

Appendix: Publications on Related Crystals

Appendix: Publications on Related Crystals

Comparisons of the glass and crystal provide valuable insight, as described in this text, since elemental and stoichiometric glasses have the corresponding crystals with the same composition and the crystalline physics is much more advanced than that of the non-crystalline. We here list related publications in a historical order on simple chalcogenide crystals of interest. In addition to these publications below, we may consult Landolt–Bornstein (Group III Condensed Matter, Numerical Data and Functional Relationships in Science and Technology, Volume 41C: Non-Tetrahedrally Bonded Elements and Binary Compounds I), which contains comprehensive data on some chalcogenide crystals.

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Tanaka, K., Shimakawa, K. (2011). Future Prospects. In: Amorphous Chalcogenide Semiconductors and Related Materials. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-9510-0_8

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