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1 Temperature Effects on Platinum Single-Crystal/Aqueous Solution Interphases. Combining Gibbs Thermodynamics with Laser-Pulsed Experiments

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Book cover Interfacial Phenomena in Electrocatalysis

Part of the book series: Modern Aspects of Electrochemistry ((MAOE,volume 51))

Abstract

The rigorous analysis of the effect of temperature variations on interfacial properties is a key tool to provide new and valuable information on the structure and reactivity of the metal|solution interphase. The entropy of the components that form the interphase is a unique probe of their structural properties. Therefore, this experimental data is particularly useful for the validation of molecular models of electrified interphases. In addition, the use of fast temperature perturbations is especially suitable for the selective characterization of different interfacial components, based on their different response time towards the temperature change. In this way, the entropic properties of double-layer phenomena and charge-transfer adsorption processes can be evaluated separately. It will be shown in this chapter that the combination of Gibbs thermodynamics with results from laser-induced temperature jump experiments, allows the evaluation of key interfacial properties, such as the entropy of charge-transfer adsorbed species, the entropy of formation of the interfacial water network, and the potential of water reorientation.

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References

  1. J. A. Harrison, J. E. B. Randles, and D. J. Schiffrin, J. Electroanal. Chem., 48 (1973) 359.

    Article  CAS  Google Scholar 

  2. N. Huu Cuong, C. V. D’Alkaine, A. Jenard, and H. D. Hurwitz, J. Electroanal. Chem., 51 (1974) 377.

    Article  Google Scholar 

  3. V. A. Benderskii, G. I. Velichko, and I. Kreitus, J. Electroanal. Chem., 181 (1984) 1.

    Article  CAS  Google Scholar 

  4. G. J. Hills and S. Hsieh, J. Electroanal. Chem., 58 (1975) 289.

    Article  CAS  Google Scholar 

  5. D. Posadas and G. Gordillo, J. Electroanal. Chem., 163 (1984) 363.

    Article  CAS  Google Scholar 

  6. B. E. Conway, Adv. Colloid Interface Science, 8 (1977) 91.

    Article  CAS  Google Scholar 

  7. J. O. Bockris and M. A. Habib, Electrochim. Acta, 22 (1977) 41.

    Article  CAS  Google Scholar 

  8. W. R. Fawcett, S. Levine, R. M. de Nobriga, and A. C. Mc Donald, J. Electroanal. Chem., 111 (1980) 163.

    Article  CAS  Google Scholar 

  9. E. Dutkiewicz and S. Lamperski, J. Electroanal. Chem., 162 (1984) 13.

    CAS  Google Scholar 

  10. A. Hamelin, L. Stoicoviciu, and F. Silva, J. Electroanal. Chem., 229 (1987) 107.

    Article  CAS  Google Scholar 

  11. L. M. Doubova, A. Hamelin, L. Stoicoviciu, and S. Trasatti, J. Electroanal. Chem., 325 (1992) 197.

    Article  CAS  Google Scholar 

  12. F. Silva, M. J. Sottomayor, and A. Martins, J. Chem. Soc., Faraday Trans., 92 (1996) 3693.

    Article  CAS  Google Scholar 

  13. B. E. Conway, H. Angerstein-Kozlowska, and W. B. Sharp, J. Chem. Soc., Faraday Trans., 74 (1978) 1373.

    Article  CAS  Google Scholar 

  14. G. Jerkiewicz and A. Zolfaghari, J. Phys. Chem., 100 (1996) 8454.

    Article  CAS  Google Scholar 

  15. A. Zolfaghari and G. Jerkiewicz, J. Electroanal. Chem., 422 (1997) 1.

    Article  CAS  Google Scholar 

  16. R. Gomez, J. M. Orts, B. Alvarez-Ruiz, and J. M. Feliu, J. Phys. Chem. B, 108 (2004) 228.

    Article  CAS  Google Scholar 

  17. V. Climent, R. Gomez, J. M. Orts, and J. M. Feliu, J. Phys. Chem. B, 110 (2006) 11344.

    Article  CAS  Google Scholar 

  18. N. Garcia-Araez, V. Climent, and J. Feliu, J. Phys. Chem. C., 113 (2009) 19913.

    Article  CAS  Google Scholar 

  19. N. Garcia-Araez, V. Climent, and J. M. Feliu, J. Solid State Electrochem., 12 (2008) 387.

    Article  CAS  Google Scholar 

  20. N. Garcia-Araez, V. Climent, and J. Feliu, J. Phys. Chem. C., 113 (2009) 9290.

    Article  CAS  Google Scholar 

  21. N. Garcia-Araez, V. Climent, and J. Feliu, J. Am. Chem. Soc., 130 (2008) 3824.

    Article  CAS  Google Scholar 

  22. V. Climent, B. A. Coles, and R. G. Compton, J. Phys. Chem. B, 106 (2002) 5258.

    Article  CAS  Google Scholar 

  23. V. Climent, B. A. Coles, and R. G. Compton, J. Phys. Chem. B, 106 (2002) 5988.

    Article  CAS  Google Scholar 

  24. V. Climent, N. Garcia-Araez, R. G. Compton, and J. M. Feliu, J. Phys. Chem. B, 110 (2006) 21092.

    Article  CAS  Google Scholar 

  25. V. Climent, B. A. Coles, R. G. Compton, and J. M. Feliu, J. Electroanal. Chem., 561 (2004) 157.

    Article  CAS  Google Scholar 

  26. N. Garcia-Araez, V. Climent, and J. Feliu, Electrochim. Acta, 54 (2009) 966.

    Article  CAS  Google Scholar 

  27. R. Parsons, Trans. Faraday Soc., 51 (1955) 1518.

    Article  CAS  Google Scholar 

  28. M. Breiter, Electrochim. Acta, 7 (1962) 38.

    Google Scholar 

  29. A. J. de Bethune, T. S. Licht, and N. Swendeman, J. Electrochem. Soc., 106 (1959) 616.

    Article  Google Scholar 

  30. J. N. Agar, in Advan. Electrochem. Electrochem. Eng., Vol. 2, Wiley-Interscience, New York, 1963, p. 31.

    Google Scholar 

  31. J. Jastrzebska, M. Jurkiewiczherbich, and S. Trasatti, J. Electroanal. Chem., 216 (1987) 21.

    Article  CAS  Google Scholar 

  32. N. Markovic, T. J. Schmidt, B. N. Grgur, H. A. Gasteiger, R. J. Behm, and P. N. Ross, J. Phys. Chem. B, 103 (1999) 8568.

    Article  CAS  Google Scholar 

  33. A. Zolfaghari and G. Jerkiewicz, J. Electroanal. Chem., 467 (1999) 177.

    Article  CAS  Google Scholar 

  34. E. A. Guggenheim, Trans. Faraday Soc., 46 (1940) 397.

    Article  Google Scholar 

  35. R. Parsons, Can. J. Chem., 37 (1959) 308.

    Article  CAS  Google Scholar 

  36. R. Guidelli, G. Aloisi, E. Leiva, and W. Schmickler, J. Phys. Chem. B, 92 (1988) 6671.

    Article  CAS  Google Scholar 

  37. V. Climent, R. Gómez, J. M. Orts, A. Aldaz, and J. M. Feliu, in The Electrochemistry Society Proceedings (Hydrogen at Surface and Interfaces), The Electrochemical Society, Inc., Pennington, NJ, 2000, p. 12.

    Google Scholar 

  38. M. J. Weaver, Langmuir, 14 (1998) 3932.

    Article  CAS  Google Scholar 

  39. N. Garcia-Araez, V. Climent, E. Herrero, J. Feliu, and J. Lipkowski, Electrochim. Acta, 51 (2006) 3787.

    Article  CAS  Google Scholar 

  40. H. D. Hurwitz and C. V. D’Alkaine, J. Electroanal. Chem., 42 (1973) 77.

    Article  CAS  Google Scholar 

  41. D. C. Grahame, Chem. Rev., 41 (1947) 441.

    Article  CAS  Google Scholar 

  42. M. Kaack and D. Fick, Surf. Sci., 342 (1995) 111.

    Article  CAS  Google Scholar 

  43. A. W. Adamson and A. P. Gast, Physical Chemistry of Surfaces, 6ª ed., Wiley-Interscience, New York, 1997.

    Google Scholar 

  44. A. P. Graham, A. Menzel, and J. P. Toennies, J. Chem. Phys., 111 (1999) 1676.

    Article  CAS  Google Scholar 

  45. G. W. Watson, R. P. K. Wells, D. J. Willock, and Hutchings G.J., J. Phys. Chem. B, 105 (2001) 4889.

    Article  CAS  Google Scholar 

  46. R. A. Olsen, G. J. Kroes, and E. J. Baerends, J. Chem. Phys., 111 (1999) 11155.

    Article  CAS  Google Scholar 

  47. P. Legare, Surf. Sci., 559 (2004) 169.

    Article  CAS  Google Scholar 

  48. K. Bedurftig, S. Volkening, Y. Wang, J. Wintterlin, K. Jacobi, and G. Ertl, J. Chem. Phys., 111 (1999) 11147.

    Article  CAS  Google Scholar 

  49. P. Vassilev, M. T. M. Koper, and R. A. van Santen, Chem. Phys. Lett., 359 (2002) 337.

    Article  CAS  Google Scholar 

  50. V. A. Benderskii and G. I. Velichko, J. Electroanal. Chem., 140 (1982) 1.

    Article  CAS  Google Scholar 

  51. W. H. Press, Numerical recipes in FORTRAN the art of scientific computing, 2nd ed., Cambridge University Press, Cambridge, 1992.

    Google Scholar 

  52. S. Trasatti, in Comprehensive Treatise of Electrochemistry, Vol. 2, Plenum, New York, 1980, p. 45.

    Google Scholar 

  53. S. Trasatti and E. Lust, in Mod. Aspects Electrochem., Vol. 1, Kluwer Academic/Plenum Publishers, New York, 1999, p. 1.

    Google Scholar 

  54. S. Trasatti, J. Electroanal. Chem., 82 (1977) 391.

    Article  CAS  Google Scholar 

  55. P. Vassilev, R. A. van Santen, and M. T. M. Koper, J. Chem. Phys., 122 (2005) 054701.

    Article  Google Scholar 

  56. S. Meng, Wang E.G., and S. Gao, Phys. Rev. B, 69 (2004) 195404.

    Article  Google Scholar 

  57. A. Michaelides, A. Alavi, and D. A. King, Phys. Rev. B, 69 (2004) 113404.

    Article  Google Scholar 

  58. H. H. Rotermund, S. Jakubith, S. Kubala, A. von-Oertzen, and G. Ertl, J. Electron Spectrosc. Relat. Phenom., 52 (1990) 811.

    Article  CAS  Google Scholar 

  59. B. E. Nieuwenhuys and W. M. H. Sachtler, Surf. Sci., 34 (1973) 317.

    Article  CAS  Google Scholar 

  60. R. Blanco and J. M. Orts, Electrochim. Acta, 53 (2008) 7796.

    Article  CAS  Google Scholar 

  61. J. Clavilier, K. El Achi, and A. Rodes, J. Electroanal. Chem., 272 (1989) 253.

    Article  CAS  Google Scholar 

  62. A. Rodes, K. El Achi, M. A. Zamakhchari, and J. Clavilier, J. Electroanal. Chem., 284 (1990) 245.

    Article  CAS  Google Scholar 

  63. V. Climent, G. A. Attard, and J. M. Feliu, J. Electroanal. Chem., 532 (2002) 67.

    Article  CAS  Google Scholar 

  64. J. Ren and S. Meng, Phys. Rev. B, 77 (2008) 054110.

    Article  Google Scholar 

  65. R. Parsons and T. VanderNoot, J. Electroanal. Chem., 257 (1988) 9.

    Article  CAS  Google Scholar 

  66. T. D. Jarvi and E. M. Stuve, in Electrocatalysis, Ed. by J.Lipkowski and P.N.Ross, Wiley-VCH, New York, 1998

    Google Scholar 

  67. E. Leiva, T. Iwasita, E. Herrero, and J. M. Feliu, Langmuir, 13 (1997) 6287.

    Article  CAS  Google Scholar 

  68. P. Liu and J. K. Norskov, Phys. Chem. Chem. Phys., 3 (2001) 3814.

    Article  CAS  Google Scholar 

  69. M. Mazinangokoudi and C. Argile, Surf. Sci., 262 (1992) 307.

    Article  CAS  Google Scholar 

  70. M. T. Paffett, C. T. Campbell, and T. N. Taylor, J. Chem. Phys., 85 (1986) 6176.

    Article  CAS  Google Scholar 

  71. M. Kiskinova, A. Szabo, and J. T. Yates, J. Chem. Phys., 89 (1988) 7599.

    Article  CAS  Google Scholar 

  72. J. Billy and M. Abon, Surf. Sci., 146 (1984) L525-L532.

    Article  CAS  Google Scholar 

  73. W.-F. Lin, S.-G. Sun, and Z.-W. Tian, J. Electroanal. Chem., 364 (1994) 1.

    Article  CAS  Google Scholar 

  74. S.-C. Chang and M. J. Weaver, Surf. Sci., 241 (1991) 11.

    Article  CAS  Google Scholar 

  75. E. Herrero, A. Rodes, J. M. Perez, J. M. Feliu, and A. Aldaz, J. Electroanal. Chem., 393 (1995) 87.

    Article  Google Scholar 

  76. E. Herrero, J. M. Feliu, and A. Aldaz, J. Catal., 152 (1995) 264.

    Article  CAS  Google Scholar 

  77. N. Hoshi, I. T. Bae, and D. A. Scherson, J. Phys. Chem. B, 104 (2000) 6049.

    Article  CAS  Google Scholar 

  78. J. Greeley, T. F. Jaramillo, J. Bonde, I. B. Chorkendorff, and J. K. Norskov, Nat. Mater., 5 (2006) 909.

    Article  CAS  Google Scholar 

  79. V. Stamenkovic, B. S. Mun, K. J. J. Mayrhofer, P. N. Ross, N. M. Markovic, J. Rossmeisl, J. Greeley, and J. K. Norskov, Angew. Chem. Int. Ed., 45 (2006) 2897.

    Article  CAS  Google Scholar 

  80. W. Breck, G. Cadenhead, and M. Hammerli, Trans. Faraday Soc., 61 (1965) 37.

    Article  CAS  Google Scholar 

  81. CRC Handbook of Chemistry and Physics, 79th ed., Ed. by C.R. Lide, CRC Press, Boca Raton, 1998.

    Google Scholar 

  82. A. N. Frumkin and O. A. Petrii, Electrochim. Acta, 20 (1975) 347.

    Article  CAS  Google Scholar 

  83. E. Dutkiewicz and R. Parsons, J. Electroanal. Chem., 11 (1966) 100.

    Article  CAS  Google Scholar 

  84. H. D. Hurwitz, J. Electroanal. Chem., 10 (1965) 35.

    Article  CAS  Google Scholar 

  85. N. Garcia-Araez, V. Climent, E. Herrero, J. Feliu, and J. Lipkowski, J. Electroanal. Chem., 582 (2005) 76.

    Article  CAS  Google Scholar 

  86. J. Mostany, E. Herrero, J. M. Feliu, and J. Lipkowski, J. Electroanal. Chem., 558 (2003) 19.

    Article  CAS  Google Scholar 

  87. M. T. M. Koper, J. Electroanal. Chem., 450 (1998) 189.

    Article  CAS  Google Scholar 

  88. Rotenberg.Y.Z.A, Prishchepa.Y.A, and Y. V. Pleskov, J. Electroanal. Chem., 56 (1974) 345.

    Article  CAS  Google Scholar 

  89. M. Von Allmen and A. Blatter, Laser-beam interactions with materials physical principles and applications, 2nd updated / ed., Springer, Berlin ; London, 1995.

    Google Scholar 

  90. J. P. Holman, Heat Transfer, 9th ed., McGraw-Hill Science, Blacklick, Ohio, U.S.A., 2001.

    Google Scholar 

  91. Handbook of Optical Constants of Solids, in Academic Press Handbook Series, Ed. by E.D.Palik, Academic Press, London, 1985.

    Google Scholar 

  92. S. Trasatti, J. Electroanal. Chem., 33 (1971) 351.

    Article  CAS  Google Scholar 

  93. R. H. Williams and J. I. Polanco, J. Phys. C: Solid State Phys., 7 (1974) 2745.

    Article  CAS  Google Scholar 

  94. W. Gordy and W. J. O. Thomas, J. Chem. Phys., 24 (1956) 439.

    Article  CAS  Google Scholar 

  95. K. B. Oldham, J. Electroanal. Chem., 208 (1986) 1.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Instituto de Electroquímica, Universidad de Alicante, Ap. 99, E-03080, Alicante, Spain

    Nuria Garcia-Araez, Victor Climent & Juan M. Feliu

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  1. Nuria Garcia-Araez
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  2. Victor Climent
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  3. Juan M. Feliu
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  1. , Department of Chemical Engineering, University of Patras, Patras, 265 00, Greece

    Constantinos G. Vayenas

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Garcia-Araez, N., Climent, V., Feliu, J.M. (2011). 1 Temperature Effects on Platinum Single-Crystal/Aqueous Solution Interphases. Combining Gibbs Thermodynamics with Laser-Pulsed Experiments. In: Vayenas, C. (eds) Interfacial Phenomena in Electrocatalysis. Modern Aspects of Electrochemistry, vol 51. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-5580-7_1

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