This work reports the results of a study of the microstructural and dynamical properties of self-assembled triblock copolymers. It was performed using adiabatic calorimetry, ultrasonic spectroscopy and dynamic light scattering. In the vicinity of supramolecular transitions, first aggregates occur; with further increasing temperature a spontaneous forming of compact structures was observed in the system. These results are supported by data of the shear viscosity and free internal volume parameters calculated in the framework of the Frenkel-Andrade approach.
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References
L. Tianbo et al., Prog. Polym. Sci. 28, 5 (2003).
M.J. Kositza et al., Langmuir 15, 322 (1999).
Z.S. Bakaeva et al., J. Eng. Phys. Thermophys. 79, 153 (2006).
P. Stepanek et al., Int. J. Polym. Anal. Charact. 12, 3 (2007).
P. Alexandris and R.A. Hatton, Collods Surf. A. 96, 1 (1995).
Mamatkulov S.I. et al., Langmuir, 20, 4756–4763 (2004).
Ya. I. Frenkel, Theory of Kinetics in LiquIDs (in Russian), (NAUKA, Leningrad, 1975), p. 589.
M.M. Jebari et al., Polym. Int. 55, 176 (2006).
Z. Tuzar and P. KratochvÍl. In: E. Matijevic (Ed.), Surface and ColloID Science 15, (Plenum Press, New York, 1993), p. 1.
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Bakaeva, Z., Igamberdiev, K., Khabibulaev, P., Stepanek, P., Cernoch, P. (2009). The Collapse of Hydrodynamic Radii In Pluronic Pe6400 Micelles In Vicinity of Supramolecular Transition: Dynamic Light Scattering, Heat Capacity and Sound Velocity Measurements. In: Reithmaier, J.P., Petkov, P., Kulisch, W., Popov, C. (eds) Nanostructured Materials for Advanced Technological Applications. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-9916-8_13
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DOI: https://doi.org/10.1007/978-1-4020-9916-8_13
Publisher Name: Springer, Dordrecht
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