Abstract
Microporous, transition metal ion-substituted aluminophosphate molecular sieves have attracted considerable attention over the last decade owing to their shape-selective catalytic properties for both acid-catalyzed conversion of methanol to lower olefins and aerobic oxyfunctionalization of saturated hydrocarbons. By controlling the types of transition metal ions that are substituted in place of Al(III) ions in the framework of the aluminophosphate structure and the pore structure of the microporous materials, it is now possible to perform both reactant- and product-selective catalytic reactions. Detailed structures of the molecular sieves, local structures of the active (transition metal ion) sites and their relationship to catalytic properties are discussed.
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Sankar, G., Raja, R. (2005). On the Structure of Cobalt-Substituted Aluminophosphate Catalysts and Their Catalytic Performance. In: Scott, S.L., Crudden, C.M., Jones, C.W. (eds) Nanostructured Catalysts. Nanostructure Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-30641-4_8
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DOI: https://doi.org/10.1007/978-0-387-30641-4_8
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