Abstract
This chapter will give an insight into the chemistry of triaminoguanidinium salts (TAGX), their synthesis, and potential application. The main focus will be on the utilization of triaminoguanidinium salts as building blocks for C 3-symmetric ligand systems. Both the direct application and the coordination chemistry leading to molecular and supramolecular coordination compounds will be presented. The formation of basic coordination compounds and different discrete coordination cages will be described in more detail.
Keywords
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- a :
-
Anti
- acac:
-
Acetylacetonate
- DMAB:
-
Dimethylaminoborane
- DMF:
-
N,N-Dimethylformamide
- en:
-
Ethylenediamine
- H5 L′:
-
2-(4-(2-Hydroxybenzyl)amino)-5-(2-(2-hydroxybenzylidene) hydrazinyl)-4H-1,2,4-triazol-3-yl)phenol
- H5 L :
-
tris(2-Hydroxybenzylidene)triaminoguanidine
- NaHbar :
-
Sodium 5,5-diethylbarbiturate
- pTsOH:
-
para-Toluenesulfonic acid
- s :
-
Syn
- TAG :
-
Triaminoguanidine
- TAGX:
-
Triaminoguanidinium salt
- [H6 Br 3 L]Cl:
-
tris(5-Bromo-2-hydroxybenzylidene)triaminoguanidinium chloride
- [H3 Me 3 Br 3 L]Cl:
-
tris(5-Bromo-2-methoxybenzylidene)triaminoguanidinium chloride
- [H6(OMe)3 Br 3 L]Cl:
-
tris(5-Bromo-2-hydroxy-3-methoxybenzylidene)triaminoguanidinium chloride
- [H6 L]Cl:
-
tris(2-Hydroxybenzylidene)triaminoguanidinium chloride
- [H6 Br 3 L]Cl:
-
tris(5-Bromo-2-hydroxybenzylidene)triaminoguanidinium chloride
- [H6 Br 6 (OMe) 3 L]Cl:
-
tris(3,5-Dibromo-2-hydroxy-4-methoxybenzylidene)triaminoguanidinium chloride
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von Eßen, C., Göb, C.R., Oppel, I.M. (2015). Triaminoguanidinium-Based Ligands in Supramolecular Chemistry. In: Selig, P. (eds) Guanidines as Reagents and Catalysts II. Topics in Heterocyclic Chemistry, vol 51. Springer, Cham. https://doi.org/10.1007/7081_2015_172
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DOI: https://doi.org/10.1007/7081_2015_172
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