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Triaminoguanidinium-Based Ligands in Supramolecular Chemistry

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Guanidines as Reagents and Catalysts II

Part of the book series: Topics in Heterocyclic Chemistry ((TOPICS,volume 51))

Abstract

This chapter will give an insight into the chemistry of triaminoguanidinium salts (TAGX), their synthesis, and potential application. The main focus will be on the utilization of triaminoguanidinium salts as building blocks for C 3-symmetric ligand systems. Both the direct application and the coordination chemistry leading to molecular and supramolecular coordination compounds will be presented. The formation of basic coordination compounds and different discrete coordination cages will be described in more detail.

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Abbreviations

a :

Anti

acac:

Acetylacetonate

DMAB:

Dimethylaminoborane

DMF:

N,N-Dimethylformamide

en:

Ethylenediamine

H5 L′:

2-(4-(2-Hydroxybenzyl)amino)-5-(2-(2-hydroxybenzylidene) hydrazinyl)-4H-1,2,4-triazol-3-yl)phenol

H5 L :

tris(2-Hydroxybenzylidene)triaminoguanidine

NaHbar :

Sodium 5,5-diethylbarbiturate

pTsOH:

para-Toluenesulfonic acid

s :

Syn

TAG :

Triaminoguanidine

TAGX:

Triaminoguanidinium salt

[H6 Br 3 L]Cl:

tris(5-Bromo-2-hydroxybenzylidene)triaminoguanidinium chloride

[H3 Me 3 Br 3 L]Cl:

tris(5-Bromo-2-methoxybenzylidene)triaminoguanidinium chloride

[H6(OMe)3 Br 3 L]Cl:

tris(5-Bromo-2-hydroxy-3-methoxybenzylidene)triaminoguanidinium chloride

[H6 L]Cl:

tris(2-Hydroxybenzylidene)triaminoguanidinium chloride

[H6 Br 3 L]Cl:

tris(5-Bromo-2-hydroxybenzylidene)triaminoguanidinium chloride

[H6 Br 6 (OMe) 3 L]Cl:

tris(3,5-Dibromo-2-hydroxy-4-methoxybenzylidene)triaminoguanidinium chloride

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Author information

Authors and Affiliations

  1. Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52074, Aachen, Germany

    Carolina von Eßen, Christian R. Göb & Iris M. Oppel

Authors
  1. Carolina von Eßen
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  2. Christian R. Göb
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  3. Iris M. Oppel
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Corresponding author

Correspondence to Iris M. Oppel .

Editor information

Editors and Affiliations

  1. Patheon Inc. , Linz, Austria

    Philipp Selig

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von Eßen, C., Göb, C.R., Oppel, I.M. (2015). Triaminoguanidinium-Based Ligands in Supramolecular Chemistry. In: Selig, P. (eds) Guanidines as Reagents and Catalysts II. Topics in Heterocyclic Chemistry, vol 51. Springer, Cham. https://doi.org/10.1007/7081_2015_172

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