Abstract
This paper presents the principal methods available for phase change material (PCM) implementation in different storage applications. The first part is devoted to a non-exhaustive overview of the various chemical processes used to develop stable PCM (such as microencapsulation, emulsion polymerization or suspension polycondensation, polyaddition, etc.) based on the available literature. The second part deals with shape-stabilized PCM, developed from an intimate combination of a polymer matrix and a phase change element. Materials able to include more thermal energy as usual ones are interesting as they increase the thermal inertia of the system that presents by this way advantages. The energy efficiency of buildings may be improved including PCMs that store and provide enthalpy from one hand and without any significant temperature modification during the phase change process on the other hand. If the solid phase of the PCM does not present any problem, it is not the same for the liquid phase which must be maintained mechanically at its assigned location. Furthermore, the PCM in the solid (and furthermore in the liquid phase) does not have mechanical properties which allow to use it as a structural material able to support charge loads. This paper presents different methods to distribute and maintain the PCM in the thermal solid matrix.
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Agyenim F, Hewitt N, Eames P, Smyth M (2010) A review of materials, heat transfer and phase change problem formulation for latent heat thermal energy storage systems (LHTESS). Renew Sustain Energy Rev 14:615–628
Jeon J, Lee J-H, Seo J, Jeong S-G, Kim S (2013) Application of PCM thermal energy storage system to reduce building energy consumption. J Therm Anal Calorim 111:279–288
Li G, Hwang Y, Radermacher R, Chun HH (2013) Review of cold storage materials for subzero applications. Energy 51:1–17
Tyagi VV, Kaushik SC, Tyagi SK, Akiyam T (2011) Development of phase change materials based microencapsulated technology for buildings: a review. Renew Sustain Energy Rev 15:1373–1391
Yokota T, Murayama M, Howe JM (2003) In situ transmission-electron-microscopy investigation of melting in submicron Al-Si alloy particles under electron-beam irradiation. Phys Rev Lett 91:265504
Hawlader MNA, Uddin MS, Zhu HJ (2002) Encapsulated phase change materials for thermal energy storage. Int J Energy Res 26:159–171
Farid MM, Khudhair AM, Razack SAK, Al-Hallaj S (2004) A review on phase change energy storage: materials and applications. Energy Convers Manag 45(9):1597–1615
Cho JS, Kwon A, Cho C-G (2002) Microencapsulation of octadecane as a phase-change material by interfacial polymerization in an emulsion system. Colloid Polym Sci 280:260–266
Delgado M, Lazaro A, Mazo J, Zalba B (2012) Review on phase change material emulsions and microencapsulated phase change material slurries: materials, heat transfer studies and applications. Renew Sust Energ Rev 16:253–273
Wei J, Li Z, Liu L, Liu X (2013) Preparation and characterization of novel polyamide paraffin MEPCM by interfacial polymerization technique. J Appl Polym Sci 127:4588–4593
Hu W, Yu X (2014) Thermal and mechanical properties of bio-based PCMs encapsulated with nanofibrous structure. Renew Energy 62:454–458
Benita S (1996) Microencapsulation: methods and industrial applications. Marcel Dekker, New York
Hawlader MNA, Uddin MS, Khin MM (2003) Microencapsulated PCM thermal-energy storage system. Appl Energy 74:195–202
Ozonur Y, Mazman M, Paksoy HO, Evliya H (2006) Microencapsulation of coco fatty acid mixture for thermal energy storage with phase change material. Int J Energy Res 30:741–749
Lee SH, Yoon SJ, Kim YG, Choi YC, Kim JH, Lee JG (2007) Development of building materials by using micro-encapsulated phase change material. Korean J Chem Eng 24:332–335
Chen L, Xu L, Shang H, Zhang Z (2009) Microencapsulation of butyl stearate as a phase change material by interfacial polycondensation in a polyurea system. Energy Convers Manag 50:723–729
Yu F, Chen ZH, Zeng XR (2009) Preparation, characterization, and thermal properties of microPCMs containing n-dodecanol by using different types of styrene–maleic anhydride as emulsifier. Colloid Polym Sci 287:549–560
Fang G, Li H, Yang F, Liua X, Wu S (2009) Preparation and characterization of nano-encapsulated n-tetradecane as phase change material for thermal energy storage. Chem Eng J 153:217–221
Su J, Ren L, Wang L (2003) China material report: p. 141.
Su J, Wang L, Ren L (2006) Fabrication and thermal properties of microPCMs: used melamine–formaldehyde resin as shell material. J Appl Polym Sci 101:1522–1528
Mulligan JC, Colvin DP, Bryant YG (1996) Microencapsulated phase-change material suspensions for heat transfer in spacecraft thermal systems. J Spacecr Rocket 33:278–284
Zalba B, Marın JM, Cabeza LF, Mehling H (2003) Review on thermal energy storage with phase change: materials, heat transfer analysis and applications. Appl Therm Eng 23:251–283
Alkan C, Sari A, Karaipekli A, Uzun O (2009) Preparation, characterization, and thermal properties of microencapsulated phase change material for thermal energy storage. Sol Energy Mater Sol Cells 93:143–147
Alvarado JL, Marsh C, Sohn C, Vilceus M, Hock V, Phetteplace G et al (2006) Characterization of supercooling suppression of microencapsulated phase change material by using DSC. J Therm Anal Calorim 86(2):505–509
Fan YF, Zhang XX, Wang XC, Li J, Zhu QB (2004) Super-cooling prevention of microencapsulated phase change material. Thermochim Acta 413:1–6
Zhang S, Niu JL (2010) Experimental investigation of effects of supercooling on microencapsulated phase-change material (MPCM) slurry thermal storage capacities. Sol Energy Mater Sol Cells 94:1038–1048
Fang YT, Kuang SY, Gao XN, Zhang ZG (2008) Preparation and characterization of novel nanoencapsulated phase change materials. Energy Convers Manag 49:3704–3707
Yang R, Xu H, Zhang YP (2003) Preparation, physical property and thermal physical property of phase change microcapsule slurry and phase change emulsion. Sol Energy Mater Sol Cells 80:405–416
Hoffman F, Delbrück K (1909) German Patent. 250,690, 12 Sept 1909
Jin Z, Wang Y, Liu J, Yang Z (2008) Synthesis and properties of paraffin capsules as phase change materials. Polymer 49:2903–2910
Peng S, Fuchs A, Wirtz RA (2004) Polymeric phase change composites for thermal energy storage. J Appl Polym Sci 93:1240–1251
Alay S, Göde F, Alkan C (2011) Synthesis and thermal properties of poly(n-butylacrylate)/n-hexadecane microcapsules using different cross-linkers and their application to textile fabrics. J Appl Polym Sci 120:2821–2829
Luyt AS, Krupa I (2009) Phase change materials formed by uv curable epoxy matrix and Fischer–Tropsch paraffin wax. Energy Convers Manag 50:57–61
Zhang H, Wang X (2009) Synthesis and properties of microencapsulated n-octadecane with polyurea shell containing different soft segments for heat energy storage and thermal regulation. Sol Energy Mater Sol Cells 93:1366–1376
Sarı A, Alkan C, Döğüşcü DK, Bicer A (2014) Micro/nano-encapsulated n-heptadecane with polystyrene shell for latent heat thermal energy storage. Sol Energy Mater Sol Cells 126:42–50
Zhang GH, Zhao CY (2011) Thermal and rheological properties of microencapsulated phase change materials. Renew Energy 36:2959–2966
Jyothi NVN, Prasanna PM, Sakarkar SN, Prabha KS, Ramaiah PS, Srawan G (2010) Microencapsulation techniques, factors influencing encapsulation efficiency. J Microencapsul 27:187–197
Hawlader MNA, Uddin MS, Zhu HJ (2000) Preparation and evaluation of a novel solar storage material: microencapsulated paraffin. Int J Sol Energy 22:227–238
Su JF, Wang LX, Ren L, Huang Z (2007) Mechanical properties and thermal stability of double-shell thermal-energy-storage microcapsules. J Appl Polym Sci 103:1295–1302
Sari A, Alkan C, Karaipekli A, Uzun O (2009) Microencapsulated n-octacosane as phase change material for thermal energy storage. Sol Energy 83:1757–1763
Bayés-García L, Ventolà L, Cordobilla R, Benages R, Calvet T, Cuevas-Diarte MA (2010) Phase change materials(PCM) microcapsules with different shell compositions: preparation, characterization and thermal stability. Sol Energy Mater Sol Cells 94:1235–1240
Sanchez L, Sanchez P, de Lucas A, Carmona M, Rodriguez JF (2007) Microencapsulation of PCMs with a polystyrene shell. Colloid Polym Sci 285:1377–1385
Sánchez L, Sánchez P, Carmona M, deLucas A, Rodríguez J (2008) Influence of operation conditions on the microencapsulation of PCMs by means of suspension-like polymerization. Colloid Polym Sci 286:1019–1027
Sánchez L, Lacasa E, Carmona M, Rodriǵuez JF, Sánchez P (2008) Applying an experimental design to improve the characteristics of microcapsules containing phase change materials for fabric uses. Ind Eng Chem Res 47:9783–90
Sánchez-Silva L, Carmona M, de Lucas A, Sánchez P, Rodríguez JF (2010) Scale-up of a suspension-like polymerization process for the microencapsulation of phase change materials. J Microencapsul 27:583–593
Li W, Song G, Tang G, Chu X, Ma S, Liu C (2011) Morphology, structure and thermal stability of microencapsulated phase change material with copolymer shell. Energy 36:785–791
Wang H, Wang JP, Wang X, Li W, Zhang X (2013) Preparation and properties of microencapsulated phase change materials containing two-phase core materials. Ind Eng Chem Res 52:14706–14712
Yin D, Ma L, Liu J, Zhang Q (2014) Pickering emulsion: an oval template for microencapsulated phase change materials with polymer–silica hybrid shell. Energy 64:575–581
Ma S, Song G, Li W, Fan P, Tang G (2010) UV irradiation-initiated MMA polymerization to prepare microcapsules containing phase change paraffin. Sol Energy Mater Sol Cells 94(10):1643–1647
Alkan C, Sari A, Karaipekli A (2011) Preparation, thermal properties and thermal reliability of microencapsulated n-eicosane as novel phase change material for thermal energy storage. Energy Convers Manag 52:687–692
Baek KH, Lee JY, Kim JH (2007) Core/shell structured PCM nanocapsules obtained by resin fortified emulsion process. J Dispers Sci Technol 28:1059–1065
Alay S, Göde F, Alkan C (2010) Preparation and characterization of poly(methyl-methacrylate-co-glycidyl methacrylate)/n-hexadecane nanocapsules as a fiber additive for thermal energy storage. Fibers Polym 11:1089–1093
Sari A, Karaipekli A (2008) Preparation, thermal properties and thermal reliability of capric acid/expanded perlite composite for thermal energy storage. Mater Chem Phys 109:459–464
Alay S, Alkan C, Göde F (2011) Synthesis and characterization of poly(methyl methacrylate)/n-hexadecane microcapsules using different cross-linkers and their application to some fabrics. Thermochim Acta 518:1–8
SarI A, Alkan C, Karaipekli A (2010) Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid–liquid microPCM for thermal energy storage. Appl Energy 87:1529–1534
Wang Y, Zhang Y, Xia T, Zhao W, Yang W (2014) Effects of fabricated technology on particle size distribution and thermal properties of stearic–eicosanoic acid/polymethylmethacrylate nanocapsules. Sol Energy Mater Sol Cells Part B 120:481–490
Blackley DC (1975) Emulsion polymerization, theory and practice. Applied Science, London
Zhang H, Wang X, Wu D (2010) Silica encapsulation of n-octadecane via sol–gel process: a novel microencapsulated phase change material with enhanced thermal conductivity and performance. J Colloid Interface Sci 343:246–255
Yang R, Zhang Y, Wang X, Zhang Y, Zhang Q (2009) Preparation of n-tetradecane-containing microcapsules with different shell materials by phase separation method. Sol Energy Mater Sol Cells 93:1817–1822
Jin Y, Lee W, Musinab Z, Ding Y (2010) A one-step method for producing microencapsulated phase change materials. Particuology 8:588–590
Wang JP, Zhang XX, Wang XC (2011) Preparation, characterization and permeation kinetics description of calcium alginate macro-capsules containing shape-stabilize phase change materials. Renew Energy 36:2984–2991
Su J, Ren L, Wang L (2005) Preparation and mechanical properties of thermal energy storage microcapsules. Colloid Polym Sci 284:224–228
Zhang X, Tao XM, Yick K-L, Wang X-C (2004) Structure and thermal stability of microencapsulated phase-change materials. Colloid Polym Sci 282:330–336
Zhang X, Fan Y, Tao X, Yick K (2005) Crystallization and prevention of supercooling of microencapsulated n-alkanes. J Colloid Interface Sci 281:299–306
Trigui A, Karkri M, Boudaya C, Candau Y, Ibos L (2013) Development and characterization of composite phase change material: thermal conductivity and latent heat thermal energy storage. Compos Part B 49:22–35
Trigui A, Karkri M, Boudaya C, Candau Y, Ibos L, Fois M (2014) Experimental investigation of a composite phase change material: thermal-energy storage and release. J Compos Mater 48:49–62
Trigui A, Karkri M, Krupa I (2014) Thermal conductivity and latent heat thermal energy storage properties of LDPE/wax as a shape-stabilized composite phase change material. Energy Convers Manag 77:586–596
Aadmi M, Karkri M, El hammouti M (2014) Heat transfer characteristics of thermal energy storage of a composite phase change materials: numerical and experimental investigation. Energy 72:381–392
Krupa I, Nógellová Z, Špitalsky Z, Janigová I, Boh B, Sumiga B, Kleinová A, Karkri M, AlMaadeed MA (2014) Phase change materials based on high-density polyethylene filled with microencapsulated paraffin wax. Energy Convers Manag 87:400–409
Karkri M, Lachheb M, Nogellová Z, Boh B, Sumiga B, AlMaadeed MA, Albouchi F, Krupa I (2015) Thermal properties of phase-change materials based on high-density polyethylene filled with micro-encapsulated paraffin wax for thermal energy storage. Energy Build 88:144–152
Karkri M, Lachheb M, Albouchi F, Ben Nasrallah S, Krupa I (2015) Thermal properties of smart microencapsulated paraffin/plaster composites for the thermal regulation of buildings. Energy Build 88:183–192
Krupa I, Nogellova Z, Špitalský Z, Malíková M, Sobolciak P, Ouederni M, Karkri M, AlMaadeed M (2014) Phase change materials based on high density polyethylene filled with microencapsulated paraffin wax. Energy Convers Manag 87:400–409
AlMaadeed M, Labidi S, Krupa I, Karkri M (2014) Effect of expanded graphite on the phase change materials of high density polyethylene/wax blends. Thermochim Acta 600:35–44
Trigui I, Karkri M, Krupa I (2014) Thermal conductivity and latent heat thermal energy storage properties of LDPE/wax as a shape-stabilized composite phase change material. Energy Convers Manag 77:586–596
Hong Y, Xin-shi G (2000) Preparation of polyethylene/paraffin compound as a form–stable solid–liquid phase change material. Sol Energy Mater Sol Cells 64:37–44
Sari A (2004) Form–stable paraffin/high density polyethylene composites as solid–liquid phase change material for thermal energy storage: preparation and thermal properties. Energy Convers Manag 45:2033–2042
Kaygusuz K, Sari A (2007) High density polyethylene/paraffin composites as form–stable phase change material for thermal energy storage. Energy Sources Part A 29:261–270
Krupa I, Mikova G, Luyt A (2007) Phase change materials based on low-density polyethylene/paraffin wax blends. Eur Polym J 43:4695–4705
Cai Y, Hu Y, Song L, Lu H, Chen Z, Fan W (2006) Preparation and characterizations of HDPE–EVA alloy/OMT nanocomposites/paraffin compounds as a shape stabilized phase change thermal energy storage material. Thermochim Acta 451:44–51
Alkan C, Sari A, Uzun O (2006) Poly(ethylene glycol)/acrylic polymer blends for latent heat thermal energy storage. AICHE J 52:3310–3314
Sari A, Alkan C, Kolemen U, Uzun O (2006) Eudragit S (methyl methacrylate methacrylic acid copolymer)/fatty acid blends as form–stable phase change material for latent heat thermal energy storage. J Appl Polym Sci 101:1402–1406
Kaygusuz K, Alkan C, Sari A, Uzun O (2008) Encapsulated fatty acids in an acrylic resin as shape-stabilized phase change materials for latent heat thermal energy storage. Energy Sources Part A 30:1050–1059
Alkan C, Sari A (2008) Fatty acid/poly(methyl methacrylate) (PMMA) blends as form–stable phase change materials for latent heat thermal energy storage. Sol Energy 82:118–124
Zhang L, Zhu J, Zhou W, Wang J, Wang Y (2011) Characterization of polymethyl methacrylate/polyethylene glycol/aluminum nitride composite as form–stable phase change material prepared by in situ polymerization method. Thermochim Acta 254:128–134
Sari A, Karaipekli A, Akcay M, Onal A, Kavak F (2005) Polymer/palmitic acid blends as shape-stabilized phase change material for latent heat thermal energy storage. Asian J Chem 18:439–446
Sari A, Kaygusuz K (2006) Studies on poly(vinyl chloride)/fatty acid blends as shape-stabilized phase change material for latent heat thermal energy storage. Indian J Eng Mater Sci 13:253–258
Sarier N, Onder E (2007) Thermal characteristics of polyurethane foams incorporated with phase change materials. Thermochim Acta 454:90–98
Sarier N, Onder E (2008) Thermal insulation capability of PEG-containing polyurethane foams. Thermochim Acta 475:15–21
You M, Zhang XX, Li W, Wang XC (2008) Effects of microPCMs on the fabrication of microPCMs/polyurethane composite foams. Thermochim Acta 472:20–24
Ke GZ, Xie JHF, Ruan RP, Yu WD (2010) Preparation and performance of porous phase change polyethylene glycol/polyurethane membrane. Energy Convers Manag 51:2294–2298
Sari A, Kaygusuz K (2007) Poly(vinyl alcohol)/fatty acid blends for thermal energy storage. Energy Sources Part A 29:873–883
Sari A, Alkan C, Karaipekli A, Onal A (2008) Preparation, characterization and thermal properties of styrene maleic anhydride copolymer (SMA)/fatty acid composites as form stable phase change materials. Energy Convers Manag 49:373–380
Mengjin J, Xiaoqing S, Jianjun X, Guangdou Y (2008) Preparation of a new thermal regulating fiber based on PVA and paraffin. Sol Energy Mater Sol Cells 92:1657–1660
Chen C, Wang L, Huang Y (2009) Ultrafine electrospun fibers based on stearyl stearate/polyethylene terephthalate composite as form stable phase change materials. Chem Eng J 150:269–274
Chen C, Wang L, Huang Y (2008) Morphology and thermal properties of electrospun fatty acids/polyethylene terephthalate composite fibers as novel form–stable phase change materials. Sol Energy Mater Sol Cells 92:1382–1387
Cai Y, Ke H, Dong J, Wei Q, Lin J, Zhao Y et al (2011) Effects of nano-SiO2 on morphology, thermal energy storage, thermal stability, and combustion properties of electrospun lauric acid/PET ultrafine composite fibers as form–stable phase change materials. Appl Energy 88:2106–2112
Luyt AS, Krupa I, Assumption HJ, Ahmad EEM, Mofokeng JP (2010) Blends of polyamide 12 and maleic anhydride grafted paraffin wax as potential phase change materials. Polym Test 29:100–106
Fang Y, Kang H, Wang W, Liu H, Gao X (2010) Study on polyethylene glycol/epoxy resin composite as a form–stable phase change material. Energy Convers Manag 51:2757–2761
Zhang X, Deng P, Feng R, Song J (2011) Novel gelatinous shape-stabilized phase change materials with high heat storage density. Sol Energy Mater Sol Cells 95:1213–1218
Sari A, Karaipekli A (2007) Thermal conductivity and latent heat thermal energy storage characteristics of paraffin/expanded graphite composite as phase change material. Appl Therm Eng 27:1271–1277
Sari A, Karaipekli A, Kaygusuz K (2008) Fatty acid/expanded graphite composites as phase change material for latent heat thermal energy storage. Energy Sources Part A 30:464–474
Sari A, Karaipekli A (2009) Preparation, thermal properties and thermal reliability of palmitic acid/expanded graphite composite as form–stable PCM for thermal energy storage. Sol Energy Mater Sol Cells 93:571–576
Feng L, Zheng J, Yang H, Guo Y, Li W, Li X (2011) Preparation and characterization of polyethylene glycol/active carbon composites as shape-stabilized phase change materials. Sol Energy Mater Sol Cells 95:644–650
Zhang Z, Fang X (2006) Study on paraffin/expanded graphite composite phase change thermal energy storage material. Energy Convers Manag 47:303–310
Wang W, Yang X, Fang Y, Ding J, Yan J (2009) Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage. Appl Energy 86:1479–1483
Xia L, Zhang P, Wang RZ (2010) Preparation and thermal characterization of expanded graphite/paraffin composite phase change material. Carbon 48:2538–2548
Xing L, Hongyan L, Shujun W, Lu Z, Hua C (2006) Preparation and thermal properties of form stable paraffin phase change material encapsulation. Energy Convers Manage 47:2515–2522
Wang W, Yang X, Fang Y, Ding J (2009) Preparation and performance of form–stable polyethylene glycol/silicon dioxide composites as solid–liquid phase change materials. Appl Energy 86:170–174
Tang B, Qiu M, Zhang S (2012) Thermal conductivity enhancement of PEG/SiO2 composite PCM by in situ Cu doping. Sol Energy Mater Sol Cells 105:242–248
Zhang D, Zhou J, Wu K, Li Z (2005) Granular phase changing composites for thermal energy storage. Sol Energy 78:471–480
Karaipekli A, Sari A (2008) Capric–myristic acid/expanded perlite composite as form–stable phase change material for latent heat thermal energy storage. Renew Energy 33:2599–2605
Sari A, Karaipekli A, Alkan C (2009) Preparation, characterization and thermal properties of lauric acid/expanded perlite as novel form–stable composite phase change material. Chem Eng J 155:899–904
Karaipekli A, Sari A (2009) Capric–myristic acid/vermiculite composite as form–stable phase change material for thermal energy storage. Sol Energy 83:323–332
Li M, Wu M, Kao H (2011) Study on preparation, structure and thermal energy storage property of capric–palmitic acid/ attapulgite composite phase change materials. Appl Energy 88:3125–3132
Li M, Wu Z, Kao H (2011) Study on preparation and thermal properties of binary fatty acid/diatomite shape-stabilized phase change materials. Sol Energy Mater Sol Cells 95:2412–2416
Karaman S, Karaipekli A, Sari A, Bicer A (2011) Polyethylene glycol (PEG)/diatomite composite as a novel form–stable phase change material for thermal energy storage. Sol Energy Mater Sol Cells 95:1647–1653
Mesalhy O, Lafdi K, Elgafy A (2006) Carbon foam matrices saturated with PCM for thermal protection purposes. Carbon 44:2080–2088
Wanga Y, Xia TD, Zheng H, Feng HX (2011) Stearic acid/silica fume composite as form–stable phase change material for thermal energy storage. Energy Build 43:2365–2370
Li M, Wu Z, Kao H, Tan J (2011) Experimental investigation of preparation and thermal performances of paraffin/bentonite composite phase change material. Energy Convers Manag 52:3275–3281
Mei D, Zhang B, Liu R, Zhang Y, Liu J (2011) Preparation of capric acid/halloysite nanotube composite as form–stable phase change material for thermal energy storage. Sol Energy Mater Sol Cells 95:2772–2777
Zhou M, Lin T, Huang F, Zhong Y, Wang Z, Tang Y et al (2013) Highly conductive porous graphene/ceramic composites for heat transfer and thermal energy storage. Adv Funct Mater 23:2263–2269
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Karkri, M., Lefebvre, G., Royon, L. (2015). Different Phase Change Material Implementations for Thermal Energy Storage. In: Lefebvre, G., Jiménez, E., Cabañas, B. (eds) Environment, Energy and Climate Change II. The Handbook of Environmental Chemistry, vol 34. Springer, Cham. https://doi.org/10.1007/698_2015_332
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