Abstract
Electroanalytical methods are a common tool for the assessment of chemical peculiarities of aqueous solutions. Also, the analysis of water based on optical sensors is a mature field of research, which already led to industrial applications and standard laboratory practices. Nevertheless, scientific literature is still offering new sensor techniques and innovative measurement approaches in both fields. In particular, for fast characterisation of liquids and change detection applications in a continuous monitoring context, the technology of taste sensors based on electrochemical techniques is still witnessing a growing interest. Such devices are often defined as “electronic tongues” or “e-tongues”. In addition, emerging inexpensive and portable devices with optical-sensing capabilities can be used for monitoring applications with a novel approach. This chapter gives an overview of recent techniques developed in both fields and presents several potential applications and case studies that deal with the context of water quality assessment. A brief introduction about the basics of each measurement technology, even if not exhaustive, is also provided.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsAbbreviations
- CSPT:
-
Computer screen photo-assisted technique
- HPCA:
-
Hierarchical PCA
- ISE:
-
Ion-selective electrode
- LAPV:
-
Large amplitude pulse voltammetry
- MLAPS:
-
Multiple light-addressable potentiometric sensor
- PCA:
-
Principal components analysis
- REF:
-
Reference electrode
- ST:
-
Slantnet transform
- WE:
-
Working electrode
References
Hauptmann P, Borngraeber R, Schroeder J, Auge J (2000) Artificial electronic tongue in comparison to the electronic nose—state of the art and trends. In: Proceedings of IEEE/EIA international frequency control symposium and exhibition, p 22–29
Krantz-Rulcker C, Stenberg M, Winquist F, Lundstrom I (2001) Electronic tongues for environmental monitoring based on sensor arrays and pattern recognition: a review. Anal Chim Acta 426(2):217–226
Lindquist M, Wide P (2001) Virtual water quality tests with an electronic tongue. In: Proceedings of IEEE IMTC, Budapest, Hungary, May 21–23, p 1320–1324
Vlasov Y, Legin A, Rudnitskaya A, Di Natale C, D’Amico A (2005) Nonspecific sensor arrays (“electronic tongue”) for chemical analysis of liquids: (IUPAC technical report). Pure Appl Chem 77:1965–1983
Scozzari A (2008) Electrochemical sensing methods: a brief review. In: Evangelista V et al. (eds) Algal toxins: nature, occurrence, effect and detection. NATO science for peace and security series A: chemistry and biology. Springer Science + Business Media B.V., p 335–351. doi:10.1007/978-1-4020-8480-5_16
Bard AJ, Faulkner LR (1980, 2000) (1st, 2nd edn) Electrochemical methods, fundamentals and applications. Wiley, New York
Janata J (1989, 2009) (1st, 2nd edn) Principles of chemical sensors. Springer, New York, 340 pp
Di Natale C, Macagnano A, Davide F, D’Amico A, Legin A, Vlasov Y, Rudnitskaya A, Selezenev B (1997) Multicomponent analysis on polluted waters by means of an electronic tongue. Sens Actuator B Chem 44:423–428
Winquist F, Wide P, Lundstrom I (1997) An electronic tongue based on voltammetry. Anal Chim Acta 357(1/2):21–31
Legin A, Rudnitskaya A, Vlasov Y, Di Natale C, Mazzone E, D’Amico A (1999) Application of electronic tongue for quantitative analysis of mineral water and wine. Electroanalysis 11:814–820
Paolesse R, Di Natale C, Burgio M, Martinelli E, Mazzone E, Palleschi G, D’Amico A (2003) Porphyrin-based array of cross-selective electrodes for analysis of liquid samples. Sens Actuator B 95:400–405
Ciosek P, Brzózka Z, Wróblewski W (2004) Classification of beverages using a reduced sensor array. Sens Actuator B 103:76–83
Lvova L, Martinelli E, Mazzone E, Pede A, Paolesse R, Di Natale C, D’Amico A (2006) Electronic tongue based on an array of metallic potentiometric sensors. Talanta 70:833–839
Scozzari A (2007) Application of an e-tongue to groundwater monitoring: a measurement perspective. In: Bullen TD, Wang Y (eds), Twelfth symposium on water-rock interaction. Taylor & Francis, Kunming (China), vol 2, p 1115–1118
Scozzari A, Acito N, Corsini G (2007) A novel method based on voltammetry for the qualitative analysis of water. IEEE Trans Instrum Meas 56(6). doi:10.1109/TIM.2007.903600
Men H, Zou S, Li Y, Wang Y, Ye X, Wang P (2005) A novel electronic tongue combined MLAPS with stripping voltammetry for environmental detection. Sens Actuator B Chem 110(2):350–357. doi:10.1016/j.snb.2005.02.032
Tymeszki L, Zwierkowska W, Koncki R (2004) Screen printed electrode for potentiometric measurements. Anal Chim Acta 526:3–11
Otto M, Thomas J (1985) Model studies on multiple channel analysis for free magnesium, calcium, sodium and potassium at physiological concentration levels with ion-selective electrode. Anal Chem 57:2647
Gardner JW, Bartlett PN (1994) A brief history of electronic noses. Sens Actuator B 18–19:211–220
Hayashi H, Yamanaka M, Toko K, Yamafiji K (1990) Multichannel taste sensor using lipid membrane. Sens Actuator B 2:205–213
Di Natale C, Davide F, Brunink J, D’Amico A, Vlasov Y, Legin A, Rudnitskaya A (1996) Multicomponent analysis of heavy metal cations and inorganic anions in liquids by a non-selective chalcogenide glass sensor array. Sens Actuator B 34:539–542
Riul A, Malmegrim RR, Fonseca FJ, Mattoso LHC (2003) An artificial taste sensor based on conducting polymers. Biosens Bioelectron 18:1365–1369
Winquist F, Krantz-Rulcker C, Wide P, Lundstrom I (1999) Monitoring of freshness of milk by an electronic tongue on the basis of voltammetry. Meas Sci Technol 9(12):1937–1946. doi:10.1088/0957-0233/9/12/002
Winquist F, Lundstrom I, Wide P (1999) The combination of an electronic tongue and an electronic nose. Sensors and Actuators B: Chemical. In: Twelfth European conference on solid-state transducers—9th UK conference on sensors and their applications, Southampton, UK, vol 58, issue 1–3, p 512–517. doi:10.1016/S0925-4005(99)00155-0
Heyrovský J (1924) The processes at the mercury dropping cathode. Part I. The deposition of metals. Trans Faraday Soc 19:692–702. doi:10.1039/TF9241900692
Heyrovský J (1924) The processes at the mercury dropping cathode. Part II. The hydrogen overpotential. Trans Faraday Soc 19:785–788. doi:10.1039/TF9241900785
Semerano G, Griggio L (1957) Selected values of polarographic data. Arti grafiche Panetto & Petrelli, Spoleto, p 286
Hickling A (1942) Studies in electrode polarisation. Part IV.—the automatic control of the potential of a working electrode. Trans Faraday Soc 38:27–33
Korthum G (1965) Treatise on electrochemistry. University of Tubingen, Germany, 2nd ed. American Elsevier, New York
Mirceski V, Komorsky-Lovric S, Lovric M (2007) Square-wave voltammetry. ISBN 978-3-540-73739-1, Springer
Scozzari A, Wide P (2008) The process from a redundant and general sensor concept—towards an optimal sensor strategy for the assessment of drinking water quality. In: IEEE instrumentation and measurement technology conference, proceedings, p 836–841. doi:10.1109/IMTC.2008.4547153
Iliev B, Lindquist M, Robertsson L, Wide P (2006) A fuzzy technique for food and water quality assessment with an electronic tongue. Fuzzy Set Syst 157(9):1155–1168
Pereira JMD, Postolache O, Girao PS (2007) A smart and portable solution for heavy metals concentration measurements. In: Proceedings of the IEEE instrumentation and measurement technology conference, p 2427–2430
Scozzari A, Acito N, Corsini G (2006) A supervised algorithm for water classification by voltammetric measurements. In: Proceedings of the IEEE instrumentation and measurement technology conference, p 725–728
Buehler MG, Kuhlman GM, Keymeulen D, Kounaves SP (2002) In: Advanced electronic tongue concept, 2002 I.E. aerospace conference proceedings, p 407–416
Brainina KZ, Kubysheva IV, Miroshnikova EG, Parshakov SI, Maksimov YG, Volkonsky AE (2001) Small-size sensors for the in-field stripping voltammetric analysis of water. Field Anal Chem Tech 5(6):260–271
Landgrebe DA (2003) Signal theory methods in multispectral remote sensing. Wiley, Hoboken, NJ
Richards JA (2012) Remote sensing digital image analysis: an introduction. Springer, Berlin, Heidelberg
Artursson T, Holmberg M (2002) Wavelet transform of electronic tongue data. Sens Actuator B 87:379–391
Scozzari A (2005) Signal analysis of voltammetric data series for water quality tests and classification. In: Proceedings of the IEEE instrumentation and measurement technology conference, p 89–92
Holmin S, Spångeus P, Krantz-Rülcker C, Winquist F (2001) Compression of electronic tongue data based on voltammetry—a comparative study. Sens Actuator B Chem 76(1–3):455–464. doi:10.1016/S0925-4005(01)00585-8
Herrero A, Cruz OM (1999) Qualitative and quantitative aspects of the application of genetic algorithm-based variable selection in polarography and stripping voltammetry. Anal Chim Acta 378(1–3):245–259. doi:10.1016/S0003-2670(98)00619-9
Kundu PK, Chatterjee A, Panchariya PC (2011) Electronic tongue system for water sample authentication: a slantlet-transform-based approach. IEEE Trans Instrum Meas 60(6):1959–1966. doi:10.1109/TIM.2011.2115410
Scozzari A, Peruzzi P, Cioni R, Guidi M (2006) An innovative approach to urban water management based on taste sensors. EGU General Assembly, Wien
Segawa H, Ohnishi E, Arai Y, Yoshida K (2003) Sensitivity of fiber-optic carbon dioxide sensors utilizing indicator dye. Sens Actuator B 94:276–281
Paolesse R, Monti D, Dini F, Di Natale C (2011) Fluorescence based sensor arrays. Top Curr Chem 300:139–174
Filippini D, Svensson SPS, Lundström I (2003) Computer screen as a programmable light source for visible absorption characterization of (bio)chemical assays. Chem Commun 2:240–241
Filippini D, Alimelli A, Di Natale C, Paolesse R, D’Amico A, Lundstrom I (2006) Chemical sensing with familiar devices. Angew Chem Int Ed 45:3800–3803. doi:10.1002/anie.200600050
Filippini D, Alimelli A, Di Natale C, Paolesse R, D’Amico A, Lundström I (2006) Chemical sensing with familiar devices. Angew Chem 118:3884–3887
Schubert EF, Kyu Kim J (2005) Solid-state light sources getting smart. Science 308:1274–1278
Jackson R, Mac Donald L, Freeman K (1994) Computer generated color. Wiley, New York
Filippini D, Lundström I (2006) Preferential color substances and optimized illuminations for computer screen photo-assisted classification. Anal Chim Acta 557:393–398
Santonico M, Scozzari A, Brozzo G, Marini L, D’Amico A, Filippini D, Lundstrom I, Di Natale C (2009) Detection of natural Xr(VI) with computer screen photo-assisted technology. Proc Chem 1:317–320
Nriagu J, Niebner E (eds) (1988) Chromium in the natural and human environments. Wiley, New York
Fantoni D, Brozzo G, Canepa M, Cipolli F, Marini L, Ottonello G, Vetuschi Zoccolino M (2002) Natural hexavalent chromium in groundwaters interacting with opholitic rocks. Environ Geol 42:871–882
Oze C, Bird D, Fendorf S (2007) Genesis of hexavalent chromium from natural sources in soil and groundwater. Proc Natl Acad Sci U S A 104:6544–6549
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Di Natale, C., Dini, F., Scozzari, A. (2014). Non-conventional Electrochemical and Optical Sensor Systems. In: Scozzari, A., Dotsika, E. (eds) Threats to the Quality of Groundwater Resources. The Handbook of Environmental Chemistry, vol 40. Springer, Berlin, Heidelberg. https://doi.org/10.1007/698_2013_254
Download citation
DOI: https://doi.org/10.1007/698_2013_254
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-48594-1
Online ISBN: 978-3-662-48596-5
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)