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Clusters – Contemporary Insight in Structure and Bonding pp 1–40Cite as

Cooperative Effects in Clusters and Oligonuclear Complexes of Transition Metals in Isolation

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Part of the book series: Structure and Bonding ((STRUCTURE,volume 174))

Abstract

This short review presents concepts of Transition Metal (TM) clusters and oligonuclear TM complexes and recent work on these when isolated. It focuses on experimental studies of such TM clusters and complexes in isolation and on quantum chemical calculations wherever needed. It introduces contemporary methods of TM cluster generation and of oligonuclear TM complex isolation, as well as options for their analysis. Exemplified by recent studies, the review elucidates shortly the kinetics of small molecule adsorption and of CH activation by TM clusters, the vibrations of adsorbates on TM cluster surfaces, the magnetism of TM clusters and of Single Molecule Magnets (SMMs) when isolated, and the vibrational fingerprints of oligonuclear TM complexes.

The original version of this chapter was revised. An erratum to this chapter can be found at DOI 10.1007/430_2016_14.

Dedicated to Professor Hansgeorg Schnöckel on the occasion of his 75th birthday, and to Professor Michael A. Duncan and Professor Peter B. Armentrout in recognition of their seminal contributions to the field of transition metal cluster research.

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Notes

  1. 1.

    Transition Metals (TM) in the sense of this review are the d-block non-main group metals of groups 3–11, excluding closed shell group 12 metals (Zn, Cd, and Hg), all of which possess open shell 3d4s or 4d5s or 5d6s configurations. This TM terminology includes the noble 4d and 5d metals of groups 9, 10, and 11.

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Acknowledgments

The author thanks his many prior and current co-workers, all of whom have enabled him to gain insight beyond his own imagination into the fascinating realms of TM clusters and TM complexes. Particular thanks go to Matthias Tombers and Manfred Kappes for critical reading and valuable comments. Sebastian Dillinger helped to prepare Fig. 6. The author acknowledges financial support by the state research center OPTIMAS, by the DFG funded collaborative research center “Cooperative effects in homo and heteronuclear transition metal complexes” 3MET.de, and by the Carl Zeiss Stiftung. The stated definitions of cooperative effects are in line with the 3MET working definitions as defined by its consortium of principal investigators.

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  1. Fachbereich Chemie and State Research Center OPTIMAS, TU Kaiserslautern, 67663, Kaiserslautern, Germany

    Gereon Niedner-Schatteburg

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  1. Gereon Niedner-Schatteburg
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Correspondence to Gereon Niedner-Schatteburg .

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  1. Fachbereich Chemie, Philipps-Universität Marburg and Wissenschaftliches Zentrum für Materialwissenschaften, Marburg, Germany

    Stefanie Dehnen

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Niedner-Schatteburg, G. (2016). Cooperative Effects in Clusters and Oligonuclear Complexes of Transition Metals in Isolation. In: Dehnen, S. (eds) Clusters – Contemporary Insight in Structure and Bonding. Structure and Bonding, vol 174. Springer, Cham. https://doi.org/10.1007/430_2016_11

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