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Triphosphine Ligands: Coordination Chemistry and Recent Catalytic Applications

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The Chemical Bond III

Part of the book series: Structure and Bonding ((STRUCTURE,volume 171))

Abstract

Phosphines are a long established class of ligand that are known to form a vast array of transition metal complexes. They behave as neutral electron pair donors, or Lewis bases, that alter the solubility and stereoelectronic properties of the metal centre. A key motivation for their continued development is for homogeneous catalysis. For over five decades, transition metal–phosphine complexes have been used for catalytic reactions, mainly exploiting monodentate or bidentate phosphine ligands. Multidentate phosphines by comparison have received much less attention in part because they tend to form more stable complexes with a saturated coordination environment around the metal centre. Recent developments in the areas of catalytic reduction of carboxylic acid derivatives using molecular hydrogen and in the field of biomass up-conversion have exploited catalysts based on tridentate phosphines. This chapter highlights the use of these multidentate phosphines for synthesis of coordination complexes and discusses some of their recent applications in homogeneous catalysis.

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Abbreviations

acac:

Acetylacetone

Ad:

Adamantyl

BINAP:

2,2′-bis(Diphenylphosphino)-1,1′-binaphthyl

tBu:

tert-Butyl

nBu:

n-Butyl

Bz:

Benzyl

cod:

Cyclooctadiene

DMO:

Dimethyl oxalate

DOTA:

1,4,7,10-Tetraazacyclododecane-1,4,7,10-tetraacetic acid

dppf:

1,1′-bis(Diphenylphosphanyl) ferrocene

dppe:

Ethane-1,2-diylbis(diphenylphosphane)

dpmp:

bis[(Diphenylphosphino)methyl]phenylphosphine

dppm:

Methylenebis(diphenylphosphane)

dppp:

Propane-1,3-diylbis(diphenylphosphane)

EDTA:

2-({2-[bis(Carboxymethyl)amino]ethyl}(carboxymethyl)amino)acetic acid

EG:

Ethylene glycol

Et:

Ethyl

etp:

bis[2-(Diphenylphosphino)ethyl]phenylphosphine

fac :

Facial

HNTf2 :

bis(Triflimide)

2-MTHF:

2-Methyltetrahydrofuran

LA:

Levulinic acid

Me:

Methyl

MeCEtP3 Ph :

MeC(CH2CH2PPh2)3

mer :

Meridional

MG:

Methyl glycolate

MSA:

Methanesulfonic acid

NEtP3 Ph :

N(CH2CH2PPh2)3

o-:

ortho-

p-:

para-

p-TsOH:

para-Toluenesulfonic acid

PEtP3 Ph :

P(CH2CH2PPh2)3

Ph:

Phenyl

1,4-PDO:

1,4-Pentanediol

R′EP3 :

R′E(CH2PR2)3 (E = C B, P, Si, Sn, N)

Tf:

Triflate

THF:

Tetrahydrofuran

tmm:

Trimethylenemethane

TON:

Turnover numbers

TriSulfBu :

MeC(CH2SnBu)3

Ttp:

bis[3-(Diphenylphosphino)propyl]phenylphosphine

v:

Stretching frequency

Xantphos:

4,5-bis(Diphenylphosphino)-9,9-dimethylxanthene

γVL:

γ-Valerolactone

References

  1. van Leeuwen PWNM, Kamer PCJ, Reek JNH, Dierkes P (2000) Chem Rev 100:2741

    Article  CAS  Google Scholar 

  2. Cotton FA, Hong B (1992) Polydentate phosphines: their syntheses, structural aspects, and selected applications. In: Lippard SJ (ed) Progress in inorganic chemistry, vol 40. Wiley, Hoboken

    Chapter  Google Scholar 

  3. Tolman CA (1970) J Am Chem Soc 92:2956

    Article  CAS  Google Scholar 

  4. Tolman CA, Seidel WC, Gosser LW (1974) J Am Chem Soc 96:53

    Article  CAS  Google Scholar 

  5. Tolman CA (1977) Chem Rev 77:313

    Article  CAS  Google Scholar 

  6. Müller TE, Mingos DMP (1995) Transition Met Chem 20(6):533

    Google Scholar 

  7. Tolman CA (1970) J Am Chem Soc 92:2953

    Article  CAS  Google Scholar 

  8. Andersen NG, Keay BA (2001) Chem Rev 101:997

    Article  CAS  Google Scholar 

  9. Allen DW, Taylor BF (1982) J Chem Soc Dalton Trans 51

    Google Scholar 

  10. Dyer PW, Fawcett J, Hanton MJ, Kemmitt RDW, Padda R, Singh N (2001) Dalton Trans 104

    Google Scholar 

  11. Tuxworth L, Baiget L, Phanopoulos A, Metters OJ, Batsanov AS, Fox MA, Howard JAK, Dyer PW (2012) Chem Commun 48:10413

    Article  CAS  Google Scholar 

  12. Hierso JC, Amardeil R, Bentabet E, Broussier R, Gautheron B, Meunier P, Kalck P (2003) Coord Chem Rev 236:143

    Article  CAS  Google Scholar 

  13. DuBois DL, Miedaner A, Haltiwanger RC (1991) J Am Chem Soc 113:8753

    Article  CAS  Google Scholar 

  14. Chakraborty S, Blacque O, Fox T, Berke H (2014) Chem Eur J 20:12641

    Article  CAS  Google Scholar 

  15. Arashiba K, Kinoshita E, Kuriyama S, Eizawa A, Nakajima K, Tanaka H, Yoshizawa K, Nishibayashi Y (2015) J Am Chem Soc 137:5666

    Article  CAS  Google Scholar 

  16. Hanna BS, MacIntosh AD, Ahn S, Tyler BT, Palmore GTR, Williard PG, Bernskoetter WH (2014) Organometallics 33:3425

    Article  CAS  Google Scholar 

  17. Balch AL, Catalano VJ (1992) Inorg Chem 31:2569

    Article  CAS  Google Scholar 

  18. Fleischmann M, Duetsch L, Moussa ME, Schindler A, Balazs G, Lescop C, Scheer M (2015) Chem Commun 51:2893

    Article  CAS  Google Scholar 

  19. Welsch S, Lescop C, Balazs G, Reau R, Scheer M (2011) Chem Eur J 17:9130

    Article  CAS  Google Scholar 

  20. Takemura Y, Nakajima T, Tanase T (2009) Eur J Inorg Chem 2009:4820

    Article  CAS  Google Scholar 

  21. Dau TM, Shakirova RJ, Domenech A, Jaenis J, Haukka M, Grachova EV, Pakkanen TA, Tunik SP, Koshevoy OI (2013) Eur J Inorg Chem 2013:4976

    CAS  Google Scholar 

  22. Bardaji M, Laguna A, Orera VM, Villacampa MD (1998) Inorg Chem 37:5125

    Article  CAS  Google Scholar 

  23. Xiao H, Weng YX, Wong WT, Mak TCW, Che CM (1997) J Chem Soc Dalton Trans 221

    Google Scholar 

  24. Li D, Che CM, Peng SM, Liu ST, Zhou ZY (1993) J Chem Soc Dalton Trans 189

    Google Scholar 

  25. Lu W, Chan MCW, Cheung KK, Che CM (2001) Organometallics 20:2477

    Article  CAS  Google Scholar 

  26. Shao P, Sun W (2007) Inorg Chem 46:8603

    Article  CAS  Google Scholar 

  27. Kui SCF, Sham IHT, Cheung CCC, Ma HW, Yan B, Zhu N, Che CM, Fu WF (2007) Chem Eur J 13:417

    Article  CAS  Google Scholar 

  28. Balch AL, Fossett LA, Olmstead MM (1987) Organometallics 6:1827

    Article  CAS  Google Scholar 

  29. Balch AL, Linehan JC, Olmstead MM (1986) Inorg Chem 25:3937

    Article  CAS  Google Scholar 

  30. Balch AL, Fossett LA, Linehan JC, Olmstead MM (1986) Organometallics 5:691

    Article  CAS  Google Scholar 

  31. Balch AL, Fossett LA, Guimerans RR, Olmstead MM, Reedy PE, Wood FE (1986) Inorg Chem 25:1248

    Article  CAS  Google Scholar 

  32. Balch AL, Linehan JC, Olmstead MM (1985) Inorg Chem 24:3975

    Article  CAS  Google Scholar 

  33. Balch AL, Fossett LA, Guimerans RR, Olmstead MM (1985) Organometallics 4:781

    Article  CAS  Google Scholar 

  34. Balch AL, Olmstead MM, Guimerans RR (1984) Inorg Chim Acta 84:L21

    Article  CAS  Google Scholar 

  35. Balch AL, Guimerans RR, Olmstead MM (1984) J Organomet Chem 268:C38

    Article  CAS  Google Scholar 

  36. Olmstead MM, Guimerans RR, Balch AL (1983) Inorg Chem 22:2473

    Article  CAS  Google Scholar 

  37. Yamamoto Y, Kosaka Y, Tsutsumi Y, Sunada Y, Tatsumi K, Fumie T, Shigetoshi T (2004) Dalton Trans 2969

    Google Scholar 

  38. Yamamoto Y, Kosaka Y, Tsutsumi Y, Kaburagi Y, Kuge K, Sunada Y, Tatsumi Y (2004) Eur J Inorg Chem 2004:134

    Article  CAS  Google Scholar 

  39. Kosaka Y, Shinozaki Y, Tsutsumi Y, Kaburagi Y, Yamamoto Y, Sunada Y, Tatsumi K (2003) J Organomet Chem 671:8

    Article  CAS  Google Scholar 

  40. Zhang YL, Xu LJ, Zhang X, Wang JY, Li J, Chen ZN (2013) Inorg Chem 52:5167

    Article  CAS  Google Scholar 

  41. Xu LJ, Wang JY, Zhang LY, Shi LX, Chen ZN (2013) Organometallics 32:5402

    Article  CAS  Google Scholar 

  42. Xu LJ, Wang JY, Zhu XF, Zeng XC, Chen ZN (2015) Adv Funct Mater 25:3033

    Article  CAS  Google Scholar 

  43. Krytchankou IS, Krupenya DV, Karttunen AJ, Tunik SP, Pakkanen TA, Chou PT, Koshevoy IO (2014) Dalton Trans 43:3383

    Article  CAS  Google Scholar 

  44. Raoof F, Esmaeilbeig AR, Nabavizadeh SM, Hosseini FN, Kubicki M (2013) Organometallics 32:3850

    Article  CAS  Google Scholar 

  45. Chen ZH, Zhang YL, Chen ZN (2012) Organometallics 31:256

    Article  CAS  Google Scholar 

  46. Effendy C Pettinari, Pettinari R, Ricciutelli M, Skelton BW, White AH (2005) Inorg Chim Acta 358:4009

    Google Scholar 

  47. Ning Y, Sarjeant AA, Stern CL, Peterson TH, Nguyen SBT (2012) Inorg Chem 51:3051

    Article  CAS  Google Scholar 

  48. Mukhopadhyay TK, Flores M, Feller RK, Scott BL, Taylor RD, Paz-Pasternak M, Henson NJ, Rein FN, Smythe NC, Trovitch RJ, Gordon JC (2014) Organometallics 33:7101

    Article  CAS  Google Scholar 

  49. Mukhopadhyay TK, Feller RK, Rein FN, Henson NJ, Smythe NC, Trovitch RJ, Gordon JC (2012) Chem Commun 48:8670

    Article  CAS  Google Scholar 

  50. Eckert NA, Dougherty WG, Yap GPA, Riordan CG (2007) J Am Chem Soc 129:9286

    Article  CAS  Google Scholar 

  51. vom Stein T, Weigand T, Merkens C, Klankermayer J, Leitner W (2013) ChemCatChem 5:439

    Google Scholar 

  52. Suarez T, Fontal B (1988) J Mol Catal 45:335

    Article  CAS  Google Scholar 

  53. van Engelen MC, Teunissen HT, de Vries JG, Elsevier CJ (2003) J Mol Catal A: Chem 206:185

    Article  CAS  Google Scholar 

  54. Muller TE, Lercher JA, Van Nhu N (2003) AIChE J 49:214

    Article  CAS  Google Scholar 

  55. Richmond E, Moran J (2015) J Org Chem 80:6922

    Article  CAS  Google Scholar 

  56. Van Leeuwen PWNM, Roobeek CF (1985) J Mol Catal 31:345

    Article  Google Scholar 

  57. Beck CM, Rathmill SE, Park YJ, Chen J, Crabtree RH, Liable-Sands LM, Rheingold AL (1999) Organometallics 18:5311

    Article  CAS  Google Scholar 

  58. Schmitt DC, Lee J, Dechert-Schmitt AMR, Yamaguchi E, Krische MJ (2013) Chem Commun 49:6096

    Article  CAS  Google Scholar 

  59. Zhao SB, Wang RY, Nguyen H, Becker JJ, Gagne MR (2012) Chem Commun 48:443

    Article  CAS  Google Scholar 

  60. Shakirova JR, Grachova EV, Melnikov AS, Gurzhiy VV, Tunik SP, Haukka M, Pakkanen TA, Koshevoy IO (2013) Organometallics 32:4061

    Article  CAS  Google Scholar 

  61. Shakirova JR, Grachova EV, Melekhova AA, Krupenya DV, Gurzhiy VV, Karttunen AJ, Koshevoy IO, Melnikov AS, Tunik SP (2012) Eur J Inorg Chem 2012:4048

    Article  CAS  Google Scholar 

  62. Shakirova JR, Grachova EV, Gurzhiy VV, Koshevoy IO, Melnikov AS, Sizova OV, Tunik SP, Laguna A (2012) Dalton Trans 41:2941

    Article  CAS  Google Scholar 

  63. Takahashi Y, Akita M, Moro-Oka Y (1997) Chem Commun 1557

    Google Scholar 

  64. Fornies J, Martinez F, Navarro R, Tomas M, Urriolabeitia EP (1994) J Chem Soc Dalton Trans 505

    Google Scholar 

  65. Mrutu A, William WN, Kemp RA (2012) Inorg Chem Commun 18:110

    Article  CAS  Google Scholar 

  66. Fornies J, Navarro R, Urriolabeitia EP (1993) J Organomet Chem 452:241

    Article  CAS  Google Scholar 

  67. Mayer HA, Kaska WC (1994) Chem Rev 94:1239

    Article  CAS  Google Scholar 

  68. Cecconi F, Midollini S, Orlandini A, Sacconi L (1980) Inorg Chim Acta 42:59

    Article  CAS  Google Scholar 

  69. Bianchini B, Ghilardi CA, Meli A, Midollini S, Orlandini A (1985) Inorg Chem 24:924

    Article  CAS  Google Scholar 

  70. Broadwood-Strong GTL, Chaloner PA, Hitchcock PB (1993) Polyhedron 12:721

    Article  CAS  Google Scholar 

  71. Mealli C, Ghilardi CA, Orlandini A (1992) Coord Chem Rev 120:361

    Article  CAS  Google Scholar 

  72. Ghilardi CA, Midollini S, Moneti S, Orlandini A, Scapacci G, Traversi A (1990) J Chem Soc Dalton Trans 2293

    Google Scholar 

  73. Mellmann D, Barsch E, Bauer M, Grabow K, Boddien A, Kammer A, Sponholz P, Bentrup U, Jackstell R, Junge H, Laurenczy G, Ludwig R, Beller M (2014) Chem Eur J 20:13589

    Article  CAS  Google Scholar 

  74. Boddien A, Mellmann D, Gaertner F, Jackstell R, Junge H, Dyson PJ, Laurenczy G, Ludwig R, Beller M (2011) Science 333:1733

    Article  CAS  Google Scholar 

  75. Pouessel J, Jacquet O, Cantat T (2013) ChemCatChem 5:3552

    Article  CAS  Google Scholar 

  76. Drake JL, Manna CM, Byers JA (2013) Organometallics 32:6891

    Article  CAS  Google Scholar 

  77. Federsel C, Boddien A, Jackstell R, Jennerjahn R, Dyson PJ, Scopelliti R, Laurenczy G, Beller M (2010) Angew Chem Int Ed 49:9777

    Article  CAS  Google Scholar 

  78. Wienhoefer G, Westerhaus FA, Jagadeesh RV, Junge K, Junge H, Beller M (2012) Chem Commun 48:4827

    Article  CAS  Google Scholar 

  79. Wienhoefer G, Sorribes I, Boddien A, Westerhaus F, Junge K, Junge H, Llusar R, Beller M (2011) J Am Chem Soc 133:12875

    Article  CAS  Google Scholar 

  80. Aizawa SI, Majumder A, Yokoyama Y, Tamai M, Maeda D, Kitamura A (2009) Organometallics 28:6067

    Article  CAS  Google Scholar 

  81. Wan XK, Yuan SF, Lin ZW, Wang QM (2014) Angew Chem Int Ed 53:2923

    Article  CAS  Google Scholar 

  82. Hewertson W, Watson HR (1962) J Chem Soc 1490

    Google Scholar 

  83. Bianchini C, Meli A, Peruzzini M, Vizza F, Zanobini F (1992) Coord Chem Rev 120:193

    Article  CAS  Google Scholar 

  84. Phanopoulos A, Miller PW, Long NJ (2015) Coord Chem Rev 299:39

    Article  CAS  Google Scholar 

  85. Chaplin AB, Dyson PJ (2011) J Organomet Chem 696:2485

    Article  CAS  Google Scholar 

  86. Costello MT, Fanwick PE, Green MA, Walton RA (1992) Inorg Chem 31:2359

    Article  CAS  Google Scholar 

  87. Bianchini C, Peruzzini M, Zanobini F (1993) J Organomet Chem 451:97

    Article  CAS  Google Scholar 

  88. Ott J, Venanzi LM (1985) J Organomet Chem 291:89

    Article  CAS  Google Scholar 

  89. Arif AM, Hefner JG, Jones RA, Whittlesey BR (1986) Inorg Chem 25:1080

    Article  Google Scholar 

  90. Browning J, Penfold BR (1973) J Chem Soc Chem Commun 198

    Google Scholar 

  91. Dapporto P, Midollini S, Orlandini A, Sacconi L (1976) Inorg Chem 15:2768

    Article  CAS  Google Scholar 

  92. Benelli C, Di Vaira M, Noccioli G, Sacconi L (1977) Inorg Chem 16:182

    Article  CAS  Google Scholar 

  93. Janser P, Venanzi LM (1985) J Organomet Chem 296:229

    Article  CAS  Google Scholar 

  94. Bianchini B, Masi D, Mealli C, Meli A, Sabat M, Vizza F (1988) Inorg Chem 27:3716

    Article  CAS  Google Scholar 

  95. Klein HF, Montag J, Zucha U, Flörke U, Haupt HJ (1990) Inorg Chim Acta 177:35

    Article  CAS  Google Scholar 

  96. Bianchini C, Marchi A, Marvelli L, Peruzzini M, Romerosa A, Rossi R, Vacca A (1995) Organometallics 14:3203

    Article  CAS  Google Scholar 

  97. Heinze K, Huttner G, Zsolnai L, Schober P (1997) Inorg Chem 36:5457

    Article  CAS  Google Scholar 

  98. Rupp R, Huttner G, Kircher P, Soltek R, Büchner M (2000) Eur J Inorg Chem 1745

    Google Scholar 

  99. Blackburn DW, Chi KM, Frerichs SR, Tinkham ML, Ellis JE (1988) Angew Chem Int Ed 27:437

    Article  Google Scholar 

  100. Chatt J, Watson HR (1961) J Chem Soc 4980

    Google Scholar 

  101. Fox MA, Campbell KA, Kyba EP (1981) Inorg Chem 20:4163

    Article  CAS  Google Scholar 

  102. Piana H, Schubert U (1991) J Organomet Chem 411:303

    Article  CAS  Google Scholar 

  103. Walter O, Huttner G, Zsolnai L (1993) Z Naturforsch 48b:636

    Google Scholar 

  104. Ellermann J, Linder HA (1976) Z Naturforsch 31b:1350

    CAS  Google Scholar 

  105. Connolly J, Genge ARJ, Levason W, Orchard SD, Pope SJA, Reid G (1999) J Chem Soc Dalton Trans 2343

    Google Scholar 

  106. Kraihanzel CS, Maples PK (1976) J Organomet Chem 117:159

    Article  CAS  Google Scholar 

  107. Ellermann J, Linder HA (1979) Z Naturforsch 34b:799

    CAS  Google Scholar 

  108. Cardoza LA, Angelici RJ (1999) Inorg Chem 38:1708

    Article  CAS  Google Scholar 

  109. Suzuki T, Tsukuda T, Kiki M, Kaizaki S, Isobe K, Takagi HD, Kashiwabara K (2005) Inorg Chim Acta 358:2501

    Article  CAS  Google Scholar 

  110. Bachechi F (1994) Acta Cryst C 50:1069

    Article  Google Scholar 

  111. Suzuki T, Isobe K, Kashiwabara K, Fujita J, Kaizaki S (1996) J Chem Soc Dalton Trans 3779

    Google Scholar 

  112. Behrens H, Feilner HD, Lindner E (1971) Z Anorg Allg Chem 385:321

    Article  CAS  Google Scholar 

  113. Ellermann J, Schindler JF (1975) Z Naturforsch 30b:914

    CAS  Google Scholar 

  114. Siegl WO, Lapporte SJ, Collman JP (1971) Inorg Chem 10:2158

    Article  CAS  Google Scholar 

  115. Guilera G, McGrady GS, Steed JW, Burchell RPL, Sirsch P, Deeming AJ (2008) New J Chem 32:1573

    Article  CAS  Google Scholar 

  116. Ellermann J, Schindler JF, Behrens H, Schlenker H (1976) J Organomet Chem 108:239

    Article  CAS  Google Scholar 

  117. Johnston GG, Baird MC (1989) Organometallics 8:1894

    Article  CAS  Google Scholar 

  118. Johnston GG, Hommeltoft SI, Barid MC (1989) Organometallics 8:1904

    Article  CAS  Google Scholar 

  119. Allevi C, Golding M, Heaton BT (1987) J Organomet Chem 326:C19

    Article  CAS  Google Scholar 

  120. Camalli M, Caruso F (1990) Inorg Chim Acta 169:189

    Article  CAS  Google Scholar 

  121. Cain MF, Hughes RP, Glueck DS, Golen JA, Moore CE, Rheingold AL (2010) Inorg Chem 49:7650

    Article  CAS  Google Scholar 

  122. Bruce MI, Zaitseva NN, Skelton BW, Somers N, White AH (2007) Inorg Chim Acta 360:681

    Article  CAS  Google Scholar 

  123. Gambarotta S, Strologo S, Floriani C, Chiesi-Villa A, Guastini C (1984) Organometallics 3:1444

    Article  CAS  Google Scholar 

  124. James SL, Mingos DMP, White AJP, Williams DJ (1998) Chem Commun 2323

    Google Scholar 

  125. Miller PW, Nieuwenhuyzen M, Xu X, James SL (2002) Chem Commun 2008

    Google Scholar 

  126. Wang XJ, Langetepe T, Fenske D, Kang BS (2002) Z Anorg Allg Chem 628:1158

    Article  CAS  Google Scholar 

  127. Montes JA, Rodriguez S, Fernandez D, Garcia-Seijo MI, Gould RO, Garcia-Fernandez ME (2002) J Chem Soc Dalton Trans 1110

    Google Scholar 

  128. Fernandez EJ, Gimeno MC, Laguna A, Laguna M, Lopez-de-Luzuriaga JM, Olmos E (1996) J Organomet Chem 514:169

    Article  CAS  Google Scholar 

  129. Sevillano P, Garcia ME, Habtemariam A, Parsons S, Sadler PJ (1999) Met Based Drugs 6:211

    Article  CAS  Google Scholar 

  130. Ferrer M, Julia A, Rossell O, Seco M, Pellinghelli MA, Tiripicchio A (1997) Organometallics 16:3715

    Article  CAS  Google Scholar 

  131. Hashimoto Y, Yoshinari N, Matsushita N, Konno T (2014) Eur J Inorg Chem 2014:3474

    Article  CAS  Google Scholar 

  132. Rodriguez L, Lodeiro C, Lima JC, Crehuet R (2008) Inorg Chem 47:4952

    Article  CAS  Google Scholar 

  133. Rodriguez L, Lima JC, Ferrer M, Rossell O, Engeser M (2012) Inorg Chim Acta 381:195

    Article  CAS  Google Scholar 

  134. Teunissen HT, Elsevier CJ (1997) Chem Commun 667

    Google Scholar 

  135. Teunissen HT, Elsevier CJ (1998) Chem Commun 1367

    Google Scholar 

  136. Rosi L, Frediani M, Frediani P (2010) J Organomet Chem 695:1314

    Article  CAS  Google Scholar 

  137. Núñez AA, Eastham GR, Cole-Hamilton DJ (2007) Chem Commun 3154

    Google Scholar 

  138. Coetzee J, Dodds DL, Klankermayer J, Brosinski S, Leitner W, Slawin AMZ, Cole-Hamilton DJ (2013) Chem Eur J 19:11039

    Article  CAS  Google Scholar 

  139. Savourey S, Lefèvre G, Berthet JC, Cantat T (2014) Chem Commun 50:14033

    Article  CAS  Google Scholar 

  140. Li Y, Sorribes I, Yan T, Junge K, Beller M (2013) Angew Chem Int Ed 52:12156

    Article  CAS  Google Scholar 

  141. Sorribes I, Junge K, Beller M (2014) Chem Eur J 20:7878

    Article  CAS  Google Scholar 

  142. Geilen FMA, Engendahl B, Harwardt A, Marquardt W, Klankermayer J, Leitner W (2010) Angew Chem Int Ed 49:5510

    Article  CAS  Google Scholar 

  143. Geilen FMA, Engendahl B, Hölscher M, Klankermayer J, Leitner W (2011) J Am Chem Soc 133:14349

    Article  CAS  Google Scholar 

  144. Boardman B, Hanton MJ, van Rensburg H, Tooze RP (2006) Chem Commun 2289

    Google Scholar 

  145. Zhang J, Leitus G, Ben-David Y, Milstein D (2006) Angew Chem Int Ed 45:1113

    Article  CAS  Google Scholar 

  146. Constable DJD, Dunn PJ, Hayler JD, Humphrey GR, Leazer JL, Linderman RJ Jr, Lorenz K, Manley J, Pearlman BA, Wells A, Zaks A, Zhang TY (2007) Green Chem 9:411

    Article  CAS  Google Scholar 

  147. Jacquet O, Frogneux X, Das Neves Gomes C, Cantat T (2013) Chem Sci 4:2127

    Google Scholar 

  148. Li Y, Fang X, Junge K, Beller M (2013) Angew Chem Int Ed 52:9568

    Article  CAS  Google Scholar 

  149. Beydoun K, vom Stein T, Klankermayer J, Leitner W (2013) Angew Chem Int Ed 52:9554

    Google Scholar 

  150. Beydoun K, Ghattas G, Thenert K, Klankermayer J, Leitner W (2014) Angew Chem Int Ed 53:11010

    Article  CAS  Google Scholar 

  151. Wesselbaum S, Moha V, Meuresch M, Brosinski S, Thenert KM, Kothe J, vom Stein T, Englert U, Hölscher M, Klankermayer J, Leitner W (2015) Chem Sci 6:693

    Google Scholar 

  152. Balaraman E, Gunanathan C, Zhang J, Shimon LJW, Milstein D (2011) Nat Chem 3:609

    Article  CAS  Google Scholar 

  153. Huff CA, Sandford MS (2011) J Am Chem Soc 133:18122

    Article  CAS  Google Scholar 

  154. Wesselbaum S, vom Stein T, Klankermayer J, Leitner W (2012) Angew Chem Int Ed 51:7499

    Google Scholar 

  155. vom Stein T, Meuresch M, Limper D, Schmitz M, Hölscher M, Coetzee J, Cole-Hamilton DJ, Klankermayer J, Leitner W (2014) J Am Chem Soc 136:13217

    Google Scholar 

  156. Märkl G, Jin GY (1981) Tetrahedron Lett 22:1105

    Article  Google Scholar 

  157. Miller PW, White AJP (2010) J Organomet Chem 695:1138

    Article  CAS  Google Scholar 

  158. JFillol JL, Kruckenberg A, Scherl P, Wadepohl H, Gade LH (2011) Chem Eur J 17:14047

    Article  CAS  Google Scholar 

  159. Rodríguez LI, Roth T, Fillol JL, Wadepohl H, Gade LH (2012) Chem Eur J 18:3721

    Article  CAS  Google Scholar 

  160. Scherl P, Kruckenberg A, Mader S, Wadepohl H, Gade LH (2012) Organometallics 31:7024

    Article  CAS  Google Scholar 

  161. Scherl P, Wadepohl H, Gade LH (2013) Organometallics 32:4409

    Article  CAS  Google Scholar 

  162. Phanopoulos A, White AJP, Long NJ, Miller PW (2015) ACS Catal 5:2500

    Article  CAS  Google Scholar 

  163. Phanopoulos A, Brown NJ, White AJP, Long NJ, Miller PW (2014) Inorg Chem 53:3742

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Imperial College London, South Kensington, London, SW7 2AZ, UK

    Andreas Phanopoulos, Nicholas J. Long & Philip W. Miller

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  1. Andreas Phanopoulos
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  2. Nicholas J. Long
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  3. Philip W. Miller
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Correspondence to Philip W. Miller .

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  1. Inorganic Chemistry Laboratory, University of Oxford Inorganic Chemistry Laboratory, Oxford, United Kingdom

    D. Michael P. Mingos

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Phanopoulos, A., Long, N.J., Miller, P.W. (2016). Triphosphine Ligands: Coordination Chemistry and Recent Catalytic Applications. In: Mingos, D. (eds) The Chemical Bond III. Structure and Bonding, vol 171. Springer, Cham. https://doi.org/10.1007/430_2015_211

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