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Olefin Metathesis by Well-Defined Complexes of Molybdenum and Tungsten

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Book cover Alkene Metathesis in Organic Synthesis

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 1))

Abstract

Olefin metathesis is a catalytic process whose key step consists of a reaction between an olefin and a transition metal alkylidene complex. Some of the best understood alkylidene catalysts contain Mo or W in its highest possible oxidation state, along with “supporting” alkoxide ligands and an imido ligand. Recent advances in our understanding of these catalysts from a fundamental perspective, and in ring opening metathesis polymerization (ROMP) and ring closing metathesis (RCM), in particular, are reviewed.

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Authors
  1. Richard R. Schrock
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  1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470, Mülheim an der Ruhr, Germany

    Alois Fürstner

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Schrock, R.R. (1998). Olefin Metathesis by Well-Defined Complexes of Molybdenum and Tungsten. In: Fürstner, A. (eds) Alkene Metathesis in Organic Synthesis. Topics in Organometallic Chemistry, vol 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-69708-X_1

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  • DOI: https://doi.org/10.1007/3-540-69708-X_1

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