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Activation of Unreactive Bonds and Organic Synthesis pp 131–159Cite as

Activation of Si—Si Bonds by Transition-Metal Complexes

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Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 3))

Abstract

Transition-metal complexes have enabled the effective activation of Si-Si bonds, having led to the synthetic utilization of new, reactive organisilyl transition-metal species thus generated. Recent detailed investigations on this subject have shed new light on application on the basis of the activation for efficient synthesis of useful organosilicon compounds. This chapter describes the stoichiometric and catalytic generation of organosilyl transition-metal complexes through the activation of the Si-Si bonds with emphasis on the catalytic reactions of organodisilanes mediated by transition-metal complexes. The application of these catalytic reactions to organic synthesis is also mentioned briefly.

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Authors and Affiliations

  1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, 606-8501, Japan

    Michinori Suginome & Yoshihiko Ito

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  1. Michinori Suginome
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  2. Yoshihiko Ito
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Editors and Affiliations

  1. Department of Applied Chemistry Faculty of Engineering, Osaka University, Yamadaoka 2-1, Suita shi, Osaka, 565-0817

    Shinji Murai

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Suginome, M., Ito, Y. (1999). Activation of Si—Si Bonds by Transition-Metal Complexes. In: Murai, S., et al. Activation of Unreactive Bonds and Organic Synthesis. Topics in Organometallic Chemistry, vol 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-68525-1_6

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  • DOI: https://doi.org/10.1007/3-540-68525-1_6

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