Abstract
Surface tension, fluorescence quenching, and intradiffusion measurements have been performed on sodium decyl sulfonate and sodium decyl sulfate aqueous solutions in the presence and in the absence of poly(vinylpyrrolidone). Despite their chemical similarity, these two surfactants show differences in their behavior even in binary aqueous solution. In fact, the cmc values are different as are their aggregation numbers. Furthermore, the overall picture of the properties we have studied suggests the presence of a preferential interaction of poly (vinylpyrrolidone) toward sodium decyl sulfate with respect to sodium decyl sulfonate, for which no complex formation has been detected. The aqueous poly(vinylpyrrolidone)sodium decyl sulfate system has been extensively studied in order to obtain details on the micellar aggregates bound on the polymer. This includes an estimation of the number of micellelike clusters per polymer molecule and the number of surfactant molecules present in these micelles.
Keywords
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Taber JJ (1980) Pure Appl Chem 52:1323
Goddard DE, Ananthapadmanabhan KP (1998) In: Kwak JCT (ed) Polymer-surfactant systems, vol 77. Dekker, New York, pp 143–192
Saito S (1954) Kolloid Z 137:93
Saito S (1958) Kolloid Z 158:120
Jones MN (1967) J Colloid Interface Sci 23:36
Jones MN (1968) J Colloid Interface Sci 26:532
Arai H, Horin S (1969) J Colloid Interface Sci 30:372
Arai H, Murata M, Shinoda K (1971) J Colloid Interface Sci 37:223
Shirahama K, Tsuji K, Takagi T (1974) J Biochem 75:309
Goddard ED, Ananthapadmanabhan KP (1993) Interactions of surfactants with polymers and proteins. CRC, Boca Raton
Shirahama K (1998) In: Kwak JCT (ed) Polymer-surfactant systems, vol 77. Dekker, New York, pp 143–192
Isemura T, Imanishi A (1958) J Polym Sci 33:337
Cabane B, (1977) J Phys Chem 81:1639
Breuer MM, Robb ID (1972) Chem Ind 13:530
Shirahama K, Ide N (1976) J Colloid Interface Sci 3:54
Roscigno P, Paduano L, D’Errico G, Vitagliano V (2001) Langmuir 17:4510
Ortona O, D’Errico G, Paduano L, Sartorio R (2002) Phys Chem Chem Phys 4:2604
Arai H, Murata MJ (1973) J Colloid Interface Sci 44:475
Stilbs P (1987) NMR Spectrosc 19:1
Goldarmer EV, Hertz HG (1970) J Phys Chem 74:3734
Jansson M, Stilbs P (1985) J Phys Chem 89:4868
Infelta PP, Gratzel M, Thomas JK (1975) J Phys Chem 78:190
Tachiya M (1975) Chem Phys Lett 33:289
Gehlen MH, De Schryver FC (1993) Chem Rev 93:199
Turro NJ, Yekta A (1978) J Am Chem Soc 73:1904
McNeil R, Thomas JK (1981) J Colloid Interface Sci 83:57
Mukerjee P, Mysels KJ (1971) Critical micelle concentrations of aqueous surfactant systems. National standards reference data series no 36. US Government Printing Office, Washington, DC
Rassing J, Sams PJ, Wyn-Jones EJ (1974) J Chem Soc Faraday Trans II 70:1247
Sesta B, Segre AL, D’Aprano A, Proietti N (1997) J Phys Chem B 101:198
Annunziata O, Costantino L, D’Errico G, Paduano L, Vitagliano V (1999) J Colloid Interface Sci 216:16
Tyrrell HJV, Harris R (1994) Diffusion in liquids. Butterworth, London
Jonsson B, Wennerstrom H, Nilsson PG, Linse P (1986) Colloid Polym Sci 264:77
Carlsson A, Karlstrom G, Lindman B (1989) J Phys Chem 93:3673
Jansson M, Stilbs P (1985) J Phys Chem 89:4868
Ranganathan R, Peric M, Bales BL (1998) J Phys Chem B 102:8436
D’Aprano A, La Mesa C, Persi L (1997) Langmuir 13:5876
Annunziata O, Paduano L, Costantino L, D’Errico G, Vitagliano V (1999) J Colloid Interface Sci 216:8
Huibers PDT (1999) Langmuir 15:7546
Lekkerkerker HNW, Poon WCK, Pusey PN, Stroobants A, Warren PB (1992) Europhys Lett 20:559
Annunziata O, Paduano L, Pealrstein AJ, Miller DG, Albright JG (2000) J Am Chem Soc 122:5916
Vergara A, Paduano L, Vitagliano V, Sartorio R (2000) J Phys Chem B 104:8086
Cabane B, Duplessix R (1982) J Phys (Paris) 43:1529
Cabane B, Duplessix R, Zemb T (1985) J Phys (Paris) 46:2161
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 2003 Springer-Verlag
About this paper
Cite this paper
Roscigno, P., D’Errico, G., Ortona, O., Sartorio, R., Paduano, L. (2003). A comparison study between sodium decyl sulfonate and sodium decyl sulfate with respect to the interaction with poly(vinylpyrrolidone). In: Anghel, D.F. (eds) Aqueous Polymer — Cosolute Systems. Progress in Colloid and Polymer Science, vol 122. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-36114-6_14
Download citation
DOI: https://doi.org/10.1007/3-540-36114-6_14
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-00099-0
Online ISBN: 978-3-540-36114-5
eBook Packages: Springer Book Archive