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13C NMR investigation of local motions involved in secondary relaxation of polymers

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Part of the book series: Lecture Notes in Physics ((LNP,volume 277))

Abstract

The 13C NMR methods which can be used to study the local dynamics of solid samples through the cross-polarization and magic angle spinning technique are briefly reviewed. We present results obtained on solid polycycloalkyl methacrylates, polybutylene terephtalate, polystyrene and substituted polystyrenes and compare them with mechanical relaxation measurements.

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References

  1. Havens, J.R., Koenig, J.L., Appl. Spectroscopy 1983, 37, 226

    Google Scholar 

  2. Abragam, A., “The Principles of Nuclear Magnetism”, Oxford University, 1961

    Google Scholar 

  3. Wehrli, F.W., Wirthlin, T., “Interpretation of Carbon-13 N.M.R. spectra”, Heyden, London, 1976

    Google Scholar 

  4. Farrar, T.C., Becker, E.D., “Pulse and Fourier Transform N.M.R.”, Academic Press, New York, 1971

    Google Scholar 

  5. Mehring, M., “High Resolution N.M.R. Spectroscopy in Solids”, N.M.R., Vol. 11, Springer Verlag, Berlin, 1976

    Google Scholar 

  6. Heijboer, J., Ph.D. Theses, University of Leyden, 1972

    Google Scholar 

  7. Lauprêtre, F., Monnerie, L., Virlet, J., Macromolecules, 1984, 17, 1397

    Google Scholar 

  8. Lauprêtre, F., Virlet, J., Bayle, J.P., Macromolecules, 1985, 18, 1846

    Google Scholar 

  9. Jelinski, L.W., Schilling, F.C., Bovey, F.A., Macromolecules, 1981, 14, 1341

    Google Scholar 

  10. Jelinski, L.W., Macromolecules, 1981, 14, 1341

    Google Scholar 

  11. Jelinski, L.W., Dumais, J.J., Engel, A.K., Macromolecules, 1983, 16, 403

    Google Scholar 

  12. Jelinski, L.W., Dumais, J.J., Watnick, P.I., Engel, A.K., Sefcik, M.D., Macromolecules, 1983, 16, 409

    Google Scholar 

  13. Jelinski, L.W., Dumais, J.J., Engel, A.K., Macromolecules, 1983, 16, 492

    Google Scholar 

  14. Cholli, A.L., Dumais, J.J., Engel, A.K., Jelinski, L.W., Macromolecules, 1984, 17, 2399

    Google Scholar 

  15. Helfand, E., J. Chem. Phys., 1971, 54, 4651

    Google Scholar 

  16. Schatzki, T.F., Polym. Prepr. Am. Chem. Soc., Div. Polym. Chem., 1965, 6, 646

    Google Scholar 

  17. Gény, F., Monnerie, L., J. Polym. Sci., Polym. Phys. Ed., 1979, 17, 131, 147

    Google Scholar 

  18. Skolnick, J., Helfand, E., J. Chem. Phys., 1980, 72, 5489

    Google Scholar 

  19. Schaefer, J., Sefcik, M.D., Stejskal, E.O., Mc.Kay, R.A., Dixon, W.T., Cais, R.E., Macromolecules, 1984, 17, 1107

    Google Scholar 

  20. Gorin, S., J. Chim. Phys. (Fr.), 1970, 67, 878

    Google Scholar 

  21. Lauprêtre, F., Noël, C., Monnerie, L., J. Polym. Sci., Polym. Phys. Ed., 1977, 15, 2127

    Google Scholar 

  22. Garroway, AX, Ritchey, W.M., Moniz, W.B., Macromolecules, 1985, 15, 1051

    Google Scholar 

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Thomas Dorfmüller Graham Williams

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© 1987 Springer-Verlag

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Monnerie, L. (1987). 13C NMR investigation of local motions involved in secondary relaxation of polymers. In: Dorfmüller, T., Williams, G. (eds) Molecular Dynamics and Relaxation Phenomena in Glasses. Lecture Notes in Physics, vol 277. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-17801-5_8

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  • DOI: https://doi.org/10.1007/3-540-17801-5_8

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-17801-9

  • Online ISBN: 978-3-540-47838-6

  • eBook Packages: Springer Book Archive

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