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Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis pp 155–173Cite as

Controlled Polymerization by Incarceration of Monomers in Nanochannels

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Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 293))

Abstract

Porous Coordination Polymers (PCPs) composed of transition metal ions and bridging organic ligands have been extensively studied. The characteristic features of PCPs are highly regular channel structures, controllable channel sizes approximating molecular dimensions, designable surface potentials and functionality, and flexible frameworks responsive to guest molecules. Owing to these advantages, successful applications of PCPs range from molecular storage and separation to heterogeneous catalysts. In particular, use of their regulated and tunable nanochannels in the field of polymerization has allowed multi-level control of polymerization via control of stereoregularlity, molecular weight, etc. In this chapter, we focus on recent progress in polymerization utilizing the nanochannels of PCPs, and demonstrate why this polymerization system is attractive and promising from the viewpoint of precision control of polymeric structures.

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Abbreviations

adc:

9,10-Anthracenedicarboxylate

bdc:

1,4-Benzenedicarboxylate

bpd:

Biphenyl-4,4′-dicarboxylate

bpy:

4,4′-Bipyridine

DVB:

Divinylbenzene

GPC:

Gel permeation chromatography

M n :

Number-average molecular weight

M w :

Weight-average molecular weight

MMA:

Methyl methacrylate

ndc:

1,4-Naphthalenedicarboxylate

PCP:

Porous coordination polymer

PMMA:

Poly(methyl methacrylate)

PSt:

Polystyrene

PVAc:

Poly(vinyl acetate)

pzdc:

Pyrazine-2,3-dicarboxylate

St:

Styrene

ted:

Triethylenediamine

VAc:

Vinyl acetate

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Acknowledgments

We thank all our collaborators and colleagues, whose names appear with us in a number of references, for their contributions. We are also grateful for financial supports from JST-PRESTO program, a Grant-in-Aid for Scientific Research in a Priority Area “Chemistry of Coordination Space,” and a Grant-in-Aid for Young Scientists (A) and (B) from the Ministry of Education, Culture, Sports, Science and Technology, Government of Japan.

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Authors and Affiliations

  1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan

    Takashi Uemura & Susumu Kitagawa

  2. Institute for Integrated Cell-Material Science (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, Japan

    Susumu Kitagawa

Authors
  1. Takashi Uemura
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  2. Susumu Kitagawa
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Correspondence to Susumu Kitagawa .

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Editors and Affiliations

  1. Faculty of Science, School of Chemistry, University of Nottingham, University Park, Nottingham, NG72RD, United Kingdom

    Martin Schröder

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Uemura, T., Kitagawa, S. (2009). Controlled Polymerization by Incarceration of Monomers in Nanochannels. In: Schröder, M. (eds) Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis. Topics in Current Chemistry, vol 293. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2009_6

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