Conclusion
It is clear that many new fluoropolymers can be synthesized by direct fluorination technology that cannot be obtained through other routes. The information in this chapter should serve as a strong indication that perhaps the best and ultimate synthetic method for fluoropolymers on both laboratory and manufacturing scales in the future will be direct fluorination reactions.
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References
R. J. Lagow and J. L. Margrave, J. Inorg. Nucl. Chem. 35, 2084–2085 (1973).
J. L. Adcock, and R. J. Lagow, Inorg. Chim. Acta. 10, 9–11 (1974).
E. S. K. Liu and R. J. Lagow, J. Am. Chem. Soc. 98, 8270 (1976).
E. S. K. Liu and R. J. Lagow, J. C. S. Chem. Commun. 1977, 450–451.
J. P. DeYoung, H. Kawa, and R. J. Lagow, J. C. S. Chem. Commun. 1992, 811–812.
W. H. Lin and R. J. Lagow, J. Fluorine Chem. 50, 348–358 (1990).
H. N. Huang, H. Roesky, and R. J. Lagow, Inorg. Chem. 30, 789–794 (1991).
H. C. Wei, S. Corbelin, and R. J. Lagow, J. Org. Chem. 61, 1643–1644 (1996).
R. J. Lagow and J. L. Margrave, Proc. Natl. Acad. Sci. US.A. 67(4), 8A (1970).
R. J. Lagow and J. L. Margrave, Progress in Inorganic Chemistry Vol. 26, John Wiley and Sons, New York (1979), pp. 161–210.
T. R. Bierschenk, R. J. Lagow, T. J. Juhlke, and H. Kawa, US. Patent 5,093,432 (1992).
R. J. Lagow and J. L. Margrave, Polym. Lett. 12, 177–184 (1974).
A. J. Otsuka and R. J. Lagow, J. Fluorine Chem. 4, 371–380 (1974).
D. T. Clark, W. T. Feast, W. K. R. Musgrave, and I. Ritchie, J. Polym. Sci. Polym. Chem. Ed. 13, 857–890 (1975).
D. T. Clark, W. T. Feast, W. K. R. Musgrave, and I. Ritchie, Advances in Friction and Wear, Vol. 5A (L. H. Lee, ed.), Plenum Press, New York (1975), p. 373.
O. Ruff, D. Bretschneider, and F. Elert, Z. Anorg. Allg. Chem. 217, 1 (1934).
W. Rudorff and G. Rudorff, Z. Anorg. Allg. Chem. 253, 281 (1947).
W. Rudorff and G. Rudoff, Chem. Ber. 80, 417423 (1947).
A. K. Kuriakase and J. L. Margrave, Inorg. Chem. 4, 1639–1641 (1965).
R. J. Lagow, R. B. Badachhape, J. L. Wood, and J. L. Margrave, J. Am. Chem. Soc. 96, 2628–2629 (1974).
R. J. Lagow, R. B. Badachhape, J. L. Wood, and J. L. Margrave, J. C. S. Dalton Trans. 1974, 1268–1273.
R. L. Fusaro and H. E. Sliney, NASA Technical Memorandum NASA TMX 5262Y (1969).
N. Gisser, M. Petronio, and A. Shapiro, J. Am. Soc. Lubric. Eng. 61 (May 1970).
K. Braner, Technical Report ECOM-3322, US. Army Electronics Command, Fort Monmouth, N.J.
H. F. Hunger, G. J. Heymark, Technical Report ECOM-4047, U.S. Army Electronics Command Fort Monmouth, N.J.
G. E. Gerhardt and R. J. Lagow, J. C. S. Chem. Commun. 1977, 259–260.
G. E. Gerhardt and R. J. Lagow, J. Org. Chem. 43, 4505–4509 (1978).
G. V. D. Tiers, J. Am. Chem. Soc. 77, 4837–4840 (1955).
G. V. D. Tiers, J. Am. Chem. Soc. 77, 6703–6704 (1955).
G. V. D. Tiers, J. Am. Chem. Soc. 77, 6704–6706 (1955).
J. T. Hill, J. Macromol. Sci.—Chem. 8, 499–520 (1974).
H. S. Eleuterio, J. Macromol. Sci.—Chem. 6, 1027 (1972).
D. Sianesi, G. Benardi, and F. Moggi, French Patent 1,531,092 (1968).
D. Sianesi and R. Fontanelli, British Patent 1,226,566 (1971).
Y. Ohsaka, T. Tohzuka, and S. Takaki, European Patent Application 841160039 (1984).
R. J. Lagow and S. Inoue, US. Patent 4,113,772 (1972).
G. E. Gerhardt and R. J. Lagow, US. Patent 4,523,039 (1985).
D. F. Persico and R. J. Lagow, U.S. Patent 4,675,452 (1987).
R. J. Lagow, US. Patent Application Serial No. 147,173 (1988).
G. E. Gerhardt and R. J. Lagow, J. C. S. Perkin Trans. J. 1981, 1321–1328.
D. F. Persico and R. J. Lagow, Macromolecules 18, 1383–1387 (1985).
D. E Persico, G. E. Gerhardt, and R. J. Lagow, J. Am. Chem. Soc. 107, 1197–1201 (1985).
D. E Persico and R. J. Lagow, J. Polym. Sci.: Polym. Chem. Ed. 29, 233–242 (1991).
T. R. Bierschenk, T. J. Juhlke, and R. J. Lagow, US. Patent 4,760,198 (1988).
T. R. Bierschenk, T. J. Juhlke, and R. J. Lagow, U.S. Patent 4,827,042 (1989).
W. R. Jones, Jr., T. R. Bierschenk, T. J. Juhlke, H. Kawa, and R. J. Lagow, Ind. Eng. Chem. Res. 27, 1497–1502 (1988).
R. J. Lagow, T. R. Bierschenk, T. J. Juhlke, H. Kawa, U.S. Patent 4,931,199 (1989).
W. H. Lin, W. I. Bailey, and R. J. Lagow, J. C. S. Chem. Commun. 1985, 1350–1352.
W. D. Clark, T. Y. Lin, S. D. Maleknia, and J. R. Lagow, J. Org. Chem. 55, 5933–5934 (1990).
T. Y. Lin and R. J. Lagow, J. C. S. Chem. Commun. 1991, 12–13.
H. C. Wei, V. M. Lynch, and R. J. Lagow, J. Org. Chem. 62, 1527–1528 (1997).
J. S. Brodbelt, S. D. Maleknia, C. C. Liou, and R. J. Lagow, J. Am. Chem. Soc. 113, 5913–5914 (1991).
J. S. Brodbelt, S. D. Maleknia, R. J. Lagow, and T. Y. Lin, J. C. S. Chem. Commun. 1991, 1705–1707.
J. S. Brodbelt, C. C. Liou, S. D. Maleknia, T. Y. Lin and R. J. Lagow, J. Am. Chem. Soc. 115, 11069–11073 (1993).
T. Y. Lin, W. H. Lin, W. D. Clark, R. J. Lagow, S. D. Larson, S. H. Simonsen, V. M. Lynch, J. S. Brodbelt, S. D. Maleknia, and C. C. Liou, J. Am. Chem. Soc. 116, 5172–5179 (1994).
H. C. Wei and R. J. Lagow, Unpublished results (1997).
J. J. Kampa and R. J. Lagow, Chem. Mat. 5, 427429 (1993).
G. Resnati and D. D. DesMarteau, J. Org. Chem. 56, 49254929 (1991).
Z. Wu, D. D. MesMarteau, and M. Witz, J. Org. Chem. 57, 629–635 (1992).
G. Resnati, W. T. Pennington, and D. D. DesMarteau, J. Org. Chem. Soc. 57, 1536–1539 (1992).
G. Resnati and D. D. DesMarteau, J. Org. Chem. Soc. 57, 42814284 (1992).
C. L. Kiplinger, D. F. Persico, R. J. Lagow, and D. R. Paul, J. Appl. Polym. Sci. 22, 2617–2626 (1986).
J. M. Mohr, D. R. Paul, T. E. Mlsna, and R. J. Lagow, J. Membrane Sci. 55, 131–148 (1991).
J. M. Mohr, D. R. Paul, Y. Taru, T. E. Mlsna, and R. J. Lagow, J. Membrane Sci. 55, 149–171 (1991).
J. D. Le Roux, D. R. Paul, J. J. Kampa, and R. J. Lagow, J. Membrane Sci. 90, 21–35 (1994).
J. D. Le Roux, D. R. Paul, J. J. Kampa, and R. J. Lagow, J. Membrane Sci. 94, 121–141 (1994).
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Lagow, R.J., Wei, HC. (2002). Direct Fluorination of Polymers. In: Hougham, G., Cassidy, P.E., Johns, K., Davidson, T. (eds) Fluoropolymers 1: Synthesis. Topics in Applied Chemistry. Springer, Boston, MA. https://doi.org/10.1007/0-306-46918-9_14
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