Skip to main content

Detectors

  • Chapter
  • First Online:
Practical Gas Chromatography

Abstract

A chromatographic separation is useless if the separated species are not detected. A chemical compound passing through a gas chromatographic detector generates an electric signal through a fascinating variety of means. Here the ten most common detectors of the non-hyphenated variety are described to show how different these detection principles can be. Knowing these in some detail enables the analyst to choose the best detector for a particular analytical problem but also, very importantly, to avoid the pitfalls that are associated with any kind of instrument. Concrete examples from all branches of chemistry show impressive uses of both universal and selective detectors as well as how a combination of different kinds of detectors can enhance their usefulness considerably by providing different types of information on the sample composition.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 149.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 199.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 279.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Miller JM (1987) Basic GC, chromatography and contrasts. Wiley, New York

    Google Scholar 

  2. e.g. E516-95 a “Standard practice for testing thermal-conductivity detectors used in GC”

    Google Scholar 

  3. Scott RPW (2003) Gas chromatography detectors. Library for Science

    Google Scholar 

  4. Grob RL, Barry EF (eds) (1995) Modern practice of gas chromatography, 3rd edn. Wiley, New York

    Google Scholar 

  5. Cammann K (ed) (2001) Instrumentelle Analytische Chemie. Spektrum, Heidelberg, pp 6–91

    Google Scholar 

  6. McNair HM, Reed GL (2000) Fast gas chromatography: the effect of fast temperature programming. J Microcolumn Sep 12:351–355

    Article  CAS  Google Scholar 

  7. Hegazi AH, Andersson JT (2007) Limitations to GC-MS determination of sulfur-containing polycyclic aromatic compounds in geochemical, petroleum and environmental investigations. Energ Fuel 21:3375–3384

    Article  CAS  Google Scholar 

  8. http://teaching.shu.ac.uk/hwb/chemistry/tutorials/chrom/gaschrm.htm

  9. Agilent 6890 Series GC, p 51. http://mmrc.caltech.edu/GCMS/detectors.pdf

  10. Uda T, Okuno K, Suzuki T, Naruse Y (1991) Gas-chromatography for measurement of hydrogen isotopes at tritium processing. J Chromatogr 586:131–137

    Article  CAS  Google Scholar 

  11. Agilent Application Note 228-387. http://www.youngin.com/application/AN-0511-0009EN.pdf

  12. Pulsed discharge detector model D-4-I-VA38-R instruction manual. Valco Instruments. http://www.vici.com/support/manuals/d4_var.pdf

  13. Roberge MT, Finley JW, Lukaski HC, Borgerding AJ (2004) Evaluation of the pulsed discharge helium ionization detector for the analysis of hydrogen and methane in breath. J Chromatogr A 1027:19–23

    Article  CAS  Google Scholar 

  14. Left: http://www.chemistry.adelaide.edu.au/external/soc-rel/content/pid.htm. Right: http://pubs.acs.org/doi/pdf/10.1021/ac50025a723

  15. Agilent (2003) Flame photometric detector. Introduction and theory. http://de.slideshare.net/sandeepshinde81123/fer-smbt

  16. Application note 17630302. OI Analytical, Publ. # 1763. http://www.oico.com/Modules/productliteraturepopup.aspx?id=product&productid=57&doccatID=21

  17. Howard AL, Taylor LT (1991) Ozone-based sulfur chemiluminescence detection: its applicability to gas, supercritical fluid, and high performance liquid chromatography. J High Resolut Chromatogr 14:785–794

    Article  CAS  Google Scholar 

  18. Agilent (2007) Low-level analysis of sulfur compounds in beer by purge and trap. Technical overview. http://www.chem.agilent.com/Library/technicaloverviews/Public/5989-6797EN.pdf

  19. Grob RL, Barry EF (eds) (2004) Modern practice of gas chromatography, 4th edn. Wiley, New York, http://de.scribd.com/doc/83900365/Modern-Practice-of-Gas-Chromatography-4th-Ed-Robert-L

    Google Scholar 

  20. Sabik H, Jeannot R (1998) Determination of organonitrogen pesticides in large volumes of surface water by liquid–liquid and solid-phase extraction using gas chromatography with nitrogen–phosphorus detection and liquid chromatography with atmospheric pressure chemical ionization mass spectrometry. J Chromatogr A 818:197–207

    Article  CAS  Google Scholar 

  21. Agilent Technologies (2000) Agilent series 6890 gas chromatograph. http://mmrc.caltech.edu/GCMS/detectors.pdf

  22. Arend MW, Ballschmiter K (2000) A new sample preparation technique for organochlorines in cod liver oil combining SPE and NP-HPLC with HRGC-ECD Fresenius. J Anal Chem 366:324–328

    Article  CAS  Google Scholar 

  23. http://www.chemistry.adelaide.edu.au/external/soc-rel/content/pid.htm

  24. Boselli E, Grob K, Lercker G (2000) Determination of furan fatty acids in extra virgin olive oil. J Agric Food Chem 48:2868–2873

    Article  CAS  Google Scholar 

  25. http://www.thermo.com/eThermo/CMA/PDFs/Articles/articlesFile_28987.pdf

  26. Meng C-K (2006) Using RTL and 3-way splitter to identify unknown in strawberry extract. Application brief. Agilent Technologies

    Google Scholar 

  27. Munch JW (ed) (1995) Volatile organic compounds in water by purge and trap capillary column gas chromatography with photoionization and electrolytic conductivity detectors in series. Revision 2.1. U.S. Environmental Protection Agency. http://www.caslab.com/EPA-Methods/PDF/502_2.pdf

  28. Pfannkoch EA, Whitecavage JA (2005) A selectable single or multidimensional GC system with heart-cut fraction collection and dual detection for trace analysis of complex samples. AppNote 4/2005. Gerstel, Germany. http://www.gerstel.de/pdf/p-gc-an-2005-04.pdf

  29. Galceran MT, Moyano E, Poza JM (1995) Pentafluorobenzyl derivatives for the gas chromatographic determination of hydroxy-polycyclic aromatic hydrocarbons in urban aerosols. J Chromatogr A 710:139–148

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jan T. Andersson .

Editor information

Editors and Affiliations

Literature

Literature

All modern textbooks include a discussion of detectors. Here are given some references to research papers discussing only detector issues.

General topics

  • Ševčík J, Lips JE (1979) Meaning of GC detector characteristics. Chromatographia 12:693–702

  • Westmoreland DG, Rhodes GR (1989) Analytical techniques for trace organic compounds II. Detectors for gas chromatography. Pure Appl Chem 61:1147–1160

  • Mühlen Cv, Khummueng W, Zini CA, Caramão EB, Marriott PJ (2006) Detector technologies for comprehensive two-dimensional gas chromatography. J Sep Sci 29:1909–1921

Individual detectors

  • Hinshaw JV (2006) The flame ionization detector. LC-GC Eur 19:206–216

  • Holm T (1999) Aspects of the mechanism of the flame ionization detector. J Chromatogr A 842:221–227

  • Hinshaw JV (2006) The thermal conductivity detector. LC GC Eur 19:344–351

  • Yan X (2006) Unique selective detectors for gas chromatography: Nitrogen and sulfur chemiluminescence detectors. J Sep Sci 29:1931–1945

  • Forsyth DS (2004) Pulsed discharge detector: theory and applications. J Chromatogr A 1050:63–68

  • Poole CF (1982) The electron-capture detector in capillary column gas chromatography. J High Resolut Chromatogr Chromatogr Commun 5:454–471

  • Amirav A, Jing HW (1995) Pulsed flame photometer detector for gas-chromatography. Anal Chem 67:3305–3318

  • Visser T (2002) FT-IR detection in gas chromatography. Trends Anal Chem 1:627–636

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Andersson, J.T. (2014). Detectors. In: Dettmer-Wilde, K., Engewald, W. (eds) Practical Gas Chromatography. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-54640-2_6

Download citation

Publish with us

Policies and ethics