Chapter

Ion Cyclotron Resonance Spectrometry II

Volume 31 of the series Lecture Notes in Chemistry pp 119-139

Gas-Phase Atomic Metal Cations. Ligand Binding Energies, Oxidation Chemistry and Catalysis

  • Manfred M. KappesAffiliated withMassachusetts Institute of Technology
  • , Ralph H. StaleyAffiliated withMassachusetts Institute of Technology

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Abstract

Ion cyclotron resonance (ICR) spectroscopy with a pulsed laser volatilization/ ionization source of atomic metal cations has recently been applied to studies of the reactions of gas-phase metal ions with neutral molecules 11,2]. Initial results from this laboratory have included a variety of mechanistic studies [1–4] as well as measurements of gas-phase ligand binding energies for a number of different metal cations [5–9]. These mechanistic and thermodynamic studies yield data which is useful in developing models for understanding molecular interactions.