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Dissolved Oxygen in Rivers: Concepts and Measuring Techniques

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Achievements, History and Challenges in Geophysics

Abstract

This chapter presents the basic concepts of methods and techniques used in the measurement of dissolved oxygen in flowing water. Based on field tests carried out on the Narew, Świder and Vistula Rivers, sensor performance was analysed. The results show that the comparability of sensors depends not only on their accuracy, but also on the hydrological conditions under measurement, as well as the duration of measurement and sensor location. For diel measurement, the time delay between the maximum temperature and minimum oxygen concentration is acknowledged and briefly discussed. Moreover, in contrast to other studies, the main attention has been focused on abiotic factors that affect oxygen conditions in rivers. Finally, the key research challenges are highlighted.

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References

  • AHPA (1995) Standard methods for the examination of water and wastewater. 19th edition. American public health association, American waterworks association, and water environment federation, Washington, DC

    Google Scholar 

  • Allen JA (1955) Solubility of oxygen in water. Nature 175:83

    Article  Google Scholar 

  • Amao Y (2003) Probes and polymers for optical sensing of oxygen. Microchim Acta 2143:1–12

    Article  Google Scholar 

  • Birkel C, Soulsby C, Malcolm I, Tetzlaff D (2013) Modeling the dynamics of metabolism in montane streams using continuous dissolved oxygen measurements. Water Resour Res 49:5260–5275

    Article  Google Scholar 

  • Butts T, Evans R (1983) Small stream channel dam aeration characteristics. J Environ Eng 109(3):555–573

    Article  Google Scholar 

  • Caraco NF, Cole JJ (2002) Contrasting impacts of native and alien macrophytes on dissolved oxygen in a large river. Ecol Appl 12:1496–1509

    Article  Google Scholar 

  • Chu ChS, Lo YL, Sung TW (2011) Review on recent developments of fluorescent oxygen and carbon optical fiber sensors. Photonic Sensors 1(3):234–250

    Article  Google Scholar 

  • Clark LC Jr (1956) Monitor and control of blood and tissue O2 tensions. Trans Am Soc Artif Intern Organs 2:41–48

    Google Scholar 

  • Cygański A (1995) Metody elektroanalityczne (Electroanalytical methods). WNT, Warszawa. ISBN 83-204-1876-3 (in Polish)

    Google Scholar 

  • Demars BOL, Manson JR, Olafsson JS, Gislason GM, Gudmundsdottir R, Woodward G, Reiss J, Pichler D, Rasmussen JJ, Friberg N (2011a) Temperature and metabolic balance of streams. Freshwater Biol 56:1106–1121

    Article  Google Scholar 

  • Demars BOL, Manson JR, Olafsson JS, Gislason GM, Friberg N (2011b) Stream hydraulics and temperature determine the metabolism of geothermal Icelandic streams. Knowl Manag Aquat Ecosyst 402(5):1-17

    Google Scholar 

  • Demas JN, De Graff BA, Coleman P (1999) Oxygen sensors based on luminescence quenching. Anal Chem 71:793A–800A

    Article  Google Scholar 

  • Dojlido J (1980) Instrumentalne metody badania wody i ścieków (Instumental methods for the examination of water and wastewater). Arkady, Warszawa

    Google Scholar 

  • Dojlido J (1997) Water quality in the Vistula basin. In: Best GA, Bogacka T, Niemirycz E (eds) International river water quality. Pollution and Restoration. Taylor and Francis, London, p 21–32

    Google Scholar 

  • Gewehr PM, Delpy DT (1994) Analysis of non-linearity of optical oxygen sensors based upon phosphorescence lifetime quenching. Med Biol Eng Comput 32:659–664

    Article  Google Scholar 

  • Gradziński R, Baryła J, Dotor M, Gmur D, Gradziński M, Kędzior A, Paszkowski M, Soja R, Zieliński T, Żurek S (2003) Vegetation-controlled modern anastomosing system of the upper Narew River (NE Poland) and its sediments. Sed Geol 157:253–276

    Article  Google Scholar 

  • Grist S, Chrostowski L, Cheung KC (2010) Optical oxygen sensors for applications in microfluidic cell culture. Sensors 10:9286–9316

    Article  Google Scholar 

  • Gulliver JS, Rindels A (1993) Measurement of air-water oxygen transfer at hydraulic structures. J Hydraul Eng 119(3):327–349

    Article  Google Scholar 

  • Gulliver JS, Wilhelms SC, Parkhill KL (1998) Predictive capabilities in oxygen transfer at hydraulic strucures. J Hydraul Eng 124(7):664–671

    Article  Google Scholar 

  • Harvey D (1999) Modern analytical chemistry. McGraw-Hill, Boston

    Google Scholar 

  • Helman I, Jalukse L, Leito I (2012) A highly accurate method for determination of dissolved oxygen: Gravimetric Winkler method. Anal Chim Acta 741:21–31

    Article  Google Scholar 

  • Helton AM, Poole GC, Payn RA, Izurieta C, Stanford JA (2012) Scaling flow path processes to fluvial landscapes: an integrated field and model assessment of temperature and dissolved oxygen dynamics in a river-floodplain-aquifer system. J Geophys Res 117:G00N14

    Google Scholar 

  • Hondzo M, Voller VR, Morris M, Foufoula-Georgiou E, Finlay J, Ganti V, Power ME (2013) Estimating and scaling stream ecosystem metabolism along channels with heterogeneous substrate. Ecohydrology 6:679–688

    Article  Google Scholar 

  • Jalukse L, Helm I, Saks O (2008) On the accuracy of micro Winkler titration procedures: a case study. Accred Qual Assur 13:575–589

    Article  Google Scholar 

  • Johnston MW, Williams JS (2005) Filed comparison of optical and Clark cell dissolved oxygen sensors in the Tualatin River, Oregon, 2005. USGS Open-File Report 2006–1047

    Google Scholar 

  • Kaenel BR, Buehrer H, Uehlinger U (2000) Effects of aquatic plant management on stream metabolism and oxygen balance in streams. Freshwater Biol 45(1):85–95

    Article  Google Scholar 

  • Kalinowski A, Burandt P, Glińska-Lewczuk K (2011) Wpływ czynników hydrologicznych na warunki termiczno-tlenowe starorzeczy na przykładzie Doliny Drwęcy (Effect of hydrological factors on temperature and oxygen distribution in floodplain lakes. A case study of the Drwęca floowdplain). Proc of ECOpole 5(1):245-250

    Google Scholar 

  • Kautsky H, Hirsch A (1931) Neue Versuche zur Kohlensaureassimilation. Naturwissenschaften 19:964

    Article  Google Scholar 

  • Kautsky H (1939) Quenching of luminescence by oxygen. Trans Fariday Soc 35:216–219

    Article  Google Scholar 

  • Lakowicz JR (2006) Principle of fluorescence spectroscopy. Springer, Baltimore

    Book  Google Scholar 

  • Li J, Liu H, Li Y, Mei K, Dahlgren R, Zhang M (2013) Monitoring and modeling dissolved oxygen dynamics through continuous longitudinal sampling: a case study in Wen-Rui Tang River, Wenzhou, China. Hydrol Process 27:3502–3510

    Article  Google Scholar 

  • Manson JR, Demars BOL, Wallis SG (2011) Integrated experimental and computational hydraulic science in a unique natural laboratory. In: Rowinski P (ed) Experimental methods in hydraulic research. Springer Book Series, Geoplanet: Earth and Planetary Sciences 1:123–131

    Google Scholar 

  • McCutchan JH Jr, Lewis WM Jr, Saunders JF III (1998) Uncertainty in the estimation of stream metabolism from open-channel oxygen concentrations. J North Am Benthol Soc 17:155–164

    Article  Google Scholar 

  • Mills A (1997) Optical oxygen sensors. Platinum Met Rev 41:115–127

    Google Scholar 

  • Mitchell TO (2006) Luminescence based measurement of dissolved oxygen in natural waters. Hach Company, p 1-8

    Google Scholar 

  • Narayanaswamy R, Wolfbeis OS (2004) Optical sensors: industrial, environmental and diagnostic applications. springer series on chemical sensors and biosensors 01. Springer, Berlin

    Google Scholar 

  • Odum HT (1956) Primary production in flowing waters. Limnol Oceanogr 1(2):102–117

    Article  Google Scholar 

  • O’Connor BL, Harvey JW, McPhillips LE (2012) Thresholds of flow-induced bed disturbances and their effects on stream metabolism in an agricultural river. Water Resour Res 48:W08504

    Google Scholar 

  • O’Connor DJ (1967) The temporal and spatial distribution of dissolved oxygen in streams. Water Resour Res 3(1):65–79

    Article  Google Scholar 

  • Opaliński KW, Puczko M (2009) Oxygen consumption in Vistula River sandy beach. In: J Dojlido, K Dyguś (ed) Problems of water protection in the Bug and Narew river catchments. Monograph—Oficyna WSEiZ, Warsaw, p 33–64

    Google Scholar 

  • Reichert P, Uehlinger U, Acuña V (2009) Estimating stream metabolism from oxygen concentrations: effect of spatial heterogeneity. J Geophys Res 114:G03016

    Google Scholar 

  • Rommel K (2004) Oxygen measurement: optically or electrochemically?—comparison of theory and practical experience in online measurements. Asian Environ Technol 8(4):1-2

    Google Scholar 

  • Skoog DA, West DM, Holler FJ (1988) Fundamentals of analytical chemistry, 5th edn. Saunders, Philadelphia

    Google Scholar 

  • Stern O, Volmer M (1919) The fading time of fluorescence. Phys Z 20:183–188

    Google Scholar 

  • Tebbutt THY (1972) Some studies on reaeration in cascades. Water Res 6(3):297–304

    Article  Google Scholar 

  • Toombes L, Chanson K (2005) Air–water mass transfer on a stepped waterway. J Environ Eng 131(10):1377–1386

    Article  Google Scholar 

  • Truesdale GA, Downing AL (1954) Solubility of oxygen in water. Nature 173:1236

    Article  Google Scholar 

  • UMCES, (2004) Workshop Proceedings, State of Technology in the Development and Application of Dissolved Oxygen Sensors, Alliance for coastal technologies, UMCES Technical report Series: TS-444-04-CBL/Ref No [UMCES] CBL 04-089

    Google Scholar 

  • Winkler LW (1888) Die Bestimmung des im Wasser gelösten Sauerstoffes. Ber Dtsch Chem Ges 21:2843–2854

    Article  Google Scholar 

  • YSI (2009), The Dissolved Oxygen Handbook

    Google Scholar 

  • YSI (2003, 2005) Environmental Dissolved Oxygen Values Above 100 % Air Saturation. Pure Data for a Healthy Planet. Technical Note

    Google Scholar 

Download references

Acknowledgments

Funding for this research was provided in part by the Institute of Geophysics of the Polish Academy of Sciences through the project for Young Scientists No. 500-10-15 and by the Ministry of Sciences and Higher Education within statutory activities No 3841/E-41/S/2014 and within the “IUVENTUS PLUS II” project No. 0028/IP2/2011/71. The authors are grateful to P.M. Rowiński for stimulating discussions on this topic. The authors would also like to thank three reviewers for their constructive comments, which helped to improve the manuscript.

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Correspondence to Agnieszka Rajwa .

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Rajwa, A., Bialik, R.J., Karpiński, M., Luks, B. (2014). Dissolved Oxygen in Rivers: Concepts and Measuring Techniques. In: Bialik, R., Majdański, M., Moskalik, M. (eds) Achievements, History and Challenges in Geophysics. GeoPlanet: Earth and Planetary Sciences. Springer, Cham. https://doi.org/10.1007/978-3-319-07599-0_19

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