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Heterofullerenes

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Fullerenes and Related Structures

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 199))

Abstract

The state of the art in heterofullerene chemistry and physics is reviewed with emphasis on azafullerenes. The macroscopic synthetic methods that have been developed for aza[60] fullerene compounds since 1995 have led to a whole new and rich area in the science of fullerenes: cage modification chemistry. The synthetic routes towards aza[60]fullerene and its derivatives are reviewed in Sect. 2. The synthetic routes for aza[70]fullerene and its derivatives are summarized in Sect. 3. Section 4 comprises the theoretical and experimental work on the physicochemical properties of azafullerene compounds. Finally, in Sect. 5, the literature regarding heterofullerenes other than monoazafullerenes is reviewed.

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Authors and Affiliations

  1. Stratingh Institute & Materials Science Center, University of Groningen, Nijenborgh 4, NL-9747 AG, Groningen, The Netherlands

    Jan C. Hummelen

  2. SYMYX Technologies, 3100 Central Expressway, Santa Clara, CA, 95051, USA

    Cheryl Bellavia-Lund

  3. Department of Chemistry and Biochemistry, 4505A Molecular Science Building, University of California, 405 Hilgard Ave, Los Angeles, CA, 90095-1569, USA

    Fred Wudl

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  1. Jan C. Hummelen
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  2. Cheryl Bellavia-Lund
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  3. Fred Wudl
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  1. Institut für Organische Chemie, Universität Erlangen-Nürnberg, Henkestraße 42, D-91054, Erlangen, Germany

    Andreas Hirsch

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Hummelen, J.C., Bellavia-Lund, C., Wudl, F. (1999). Heterofullerenes. In: Hirsch, A. (eds) Fullerenes and Related Structures. Topics in Current Chemistry, vol 199. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-68117-5_3

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