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Multistate and Phase Change Selection in Constitutional Multivalent Systems

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Book cover Constitutional Dynamic Chemistry

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 322))

Abstract

Molecular architectures and materials can be constitutionally self-sorted in the presence of different biomolecular targets or external physical stimuli or chemical effectors, thus responding to an external selection pressure. The high selectivity and specificity of different bioreceptors or self-correlated internal interactions may be used to describe the complex constitutional behaviors through multistate component selection from a dynamic library. The self-selection may result in the dynamic amplification of self-optimized architectures during the phase change process. The sol–gel resolution of dynamic molecular/supramolecular libraries leads to higher self-organized constitutional hybrid materials, in which organic (supramolecular)/inorganic domains are reversibily connected.

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Abbreviations

CA:

Carbonic anhydrases

CDC:

Constitutional dynamic chemistry

DCC:

Dynamic combinatorial chemistry

DCL:

Dynamic combinatorial library(ies)

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Acknowledgments

This work was financed as part of the Marie Curie Research Training Network – “DYNAMIC” (MRTN-CT-2005-019561), a EURYI scheme award. (www.esf.org/euryi) and ANR 2010 BLAN 717 2.

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  1. Institut Européen des Membranes – ENSCM-UMII-CNRS 5635, Place Eugène Bataillon, CC 047, 34095, Montpellier Cedex 5, France

    Mihail Barboiu

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Correspondence to Mihail Barboiu .

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  1. , Adaptive Supramolecular Nanosystems Grou, Institut Européen des Membranes, Montpellier, 34095, France

    Mihail Barboiu

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Barboiu, M. (2011). Multistate and Phase Change Selection in Constitutional Multivalent Systems. In: Barboiu, M. (eds) Constitutional Dynamic Chemistry. Topics in Current Chemistry, vol 322. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2011_196

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