Metal Dihydrogen and σ-Bond Complexes

Structure Theory and Reactivity

Authors:

ISBN: 978-0-306-46465-2 (Print) 978-0-306-47597-9 (Online)

Table of contents (13 chapters)

  1. No Access

    Book Chapter

    Pages 1-16

    Introduction

  2. No Access

    Book Chapter

    Pages 17-31

    Background and Discovery of Dihydrogen Coordination

  3. No Access

    Book Chapter

    Pages 33-57

    Synthesis and General Properties of Dihydrogen Complexes

  4. No Access

    Book Chapter

    Pages 59-141

    Bonding and Activation of Dihydrogen and σ Ligands: Theory versus Experiment

  5. No Access

    Book Chapter

    Pages 143-169

    Structural and NMR Studies of Dihydrogen Complexes

  6. No Access

    Book Chapter

    Pages 171-205

    Intramolecular Dynamics of Dihydrogen-hydride Ligand Systems: Hydrogen Rotation, Exchange, and Quantum-mechanical Effects

  7. No Access

    Book Chapter

    Pages 207-244

    Thermodynamics, Kinetics, and Isotope Effects of the Binding and Cleavage of σ Ligands versus Classical Ligands

  8. No Access

    Book Chapter

    Pages 245-258

    Vibrational Studies of Coordinated Dihydrogen

  9. No Access

    Book Chapter

    Pages 259-295

    Reactions and Acidity of Dihydrogen Complexes

  10. No Access

    Book Chapter

    Pages 297-325

    Activation of Hydrogen and Related Small Molecules by Metalloenzymes and Sulfur Ligand Systems

  11. No Access

    Book Chapter

    Pages 327-364

    Coordination and Activation of Si-H, Ge-H, and Sn-H Bonds

  12. No Access

    Book Chapter

    Pages 365-415

    C-H Bond Coordination and Activation

  13. No Access

    Book Chapter

    Pages 417-439

    Coordination and Activation of B-H and Other X-H and X-Y Bonds