Abstract
Active collision theory and activated complex theory are used to derive the general kinetic equations of the mechanoactivation of tribochemical processes in systems with boundary and mixed sliding friction. The nature of the weak temperature dependence of the velocities of tribochemical reactions compared to the corresponding thermoactivated processes is discussed. Various specific cases of mechanoactivation kinetics are considered and some of them are illustrated using examples of reactions with the selective transfer and wear of rubbing solids.
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Kolesnikov, V.I., Bulgarevich, S.B., Boiko, M.V., Korets, K.E., and Feizova, V.A., Presentations about Mechanical Activation at Friction Interactions and Laws of Sliding and Rolling Friction, Tribofatika: trudy VI Mezhdunarodnogo simpoziuma po tribofatike MSTF 2010 (Proc. 6th Int. Workshop on Tribofatics MSTF-2010), Minsk: Belar. Gos. Univ., 2010.
Hainike, G., Tribochemistry, Berlin: Akademie-Verlag, 1984.
Rabinovich, V.A. and Khavin, Z.Ya., Kratkii khimicheskii spravochnik (Short Chemical Handbook), Moscow: Khimiya, 1978.
Kuzharov, A.S., Bulgarevich, S.B., Burlakova, V.E., and Akimova, E.E., Molecular Mechanisms of Self-Organization at Friction. Part 6. Analysis of Thermodynamic Features of Tribochemical Reactions, J. Friction Wear, 2007, vol. 28, no. 2, pp. 212–216.
Panchenkov, G.M. and Lebedev, V.P., Khimicheskaya kinetika i kataliz (Chemical Kinetics and Catalysis), Moscow: Khimiya, 1974.
Trenie, iznashivanie i smazka: Spravochnik. T. 2 (Friction, Wear and Lubrication. Vol. 2), Kragel’skii, I.V. and Alisin, V.V., Eds., Moscow: Mashinostroenie, 1978.
Alberty, R.A. and Daniels, F., Physical Chemistry, New York: Wiley, 1978.
Emanuel’, N.M. and Knorre, D.G., Kurs khimicheskoi kinetiki (Chemical Kinetics Course), Moscow: Vysshaya Shkola, 1984.
Bulgarevich, S.B., Boiko, M.V., Kolesnikov, V.I., and Feizova, V.A., Thermodynamic and Kinetic Analyses of Probable Chemical Reactions in the Tribocontact Zone and the Effect of Heavy Pressure on Evolution of Adsorption Processes, J. Friction Wear, 2011, vol. 32, no. 4, pp. 201–309.
Bulgarevich, S.B., Boiko, M.V., Kolesnikov, V.I., and Korets, K.E., Population of Transition States of Triboactivated Chemical Processes, J. Friction Wear, 2010, vol. 31, no. 4, pp. 288–293.
Bulgarevich, S.B., Thermodynamic Characteristics of Nonspontaneous Chemical Reaction, Induced by Friction, in Kontaktnoe vzaimodeistvie i sukhoe trenie. Sb. trudov III Mezhd. seminara (Proc. 3rd Int. Workshop ‘Contact Interaction and Dry Friction’), Moscow: Mos. Gos. Technol. Univ. 2005.
Bulgarevich, S.B., Akimova, E.E., and Boiko, M.V., Thermodynamics of Nonspontaneous Chemical Reaction, Induced by Friction, Vestnik Rostov. Gos. Univ. Putei Soobshchen., 2006, no. 3, pp. 107–112.
Minkin, V.I., Olekhnovich, L.P., and Zhdanov, Yu.A., Molekulyarnyi dizain tautomernykh system (Molecular Design of Tautomeric Systems), Rostov-on-Don: Rostov. Gos. Univ., 1977.
Bulgarevich, S.B., Chigarenko, G.G., Bulgarevich, A.F., Movshovich, D.Ya., Osipov, O.A., and Barchan, G.P., Chemical and Kinetic Approach to Friction Phenomenon Description and Kinetic Regularities for Rubbing Pairs with Selected Transfer, Trenie Iznos, 1984, vol. 5, no. 3, pp. 481–488.
Kuzharov, A.S., Bulgarevich, S.B., Kuzharov, A.A., Burlakova, V.A., Novikova, E.E., and Tishchenko, L.G., Thermal Balance and Stationary States in Tribosystems with Boundary Friction, Vestnik Rostov. Gos. Univ., 2002, vol. 2, no. 2 (12), pp. 168–176.
Akimova, E.E., Thermodynamic and Electrochemical Properties of Tribosystems with Selected Transfer Effect, Candidate Sci. (Eng.) Dissertation, Rostov-on-Don: Rostov. State Univ. Means of Communications, 2007.
Eremin, E.N., Osnovy khimicheskoi kinetiki (Foundations of Chemical Kinetics), Moscow: Vysshaya Shkola, 1976.
Kashcheev, V.N., Protsessy v zone friktsionnogo kontakta metallov, (Processes in the Friction Contact Zone of Metals), Moscow: Mashinostroenie, 1978.
Blednova, Zh.M., Increasing of Wear and Fatigue Characteristics of Steels by Surface Modification with Shape Memory Materials, Tribofatika: trudy VI Mezhdunarodnogo simpoziuma po tribofatike MSTF 2010 (Proc. 6th Int. Workshop on Tribofatics MSTF-2010), Minsk, 2010, pp. 219–228.
Hongtan, L., Shirong, G., Jingqian, D., and Shibo, W., Effect of Contact Area of Brass Pin-on-40cr Disk Friction Pairs on Wear, Tribofatika: trudy VI Mezhdunarodnogo simpoziuma po tribofatike MSTF 2010 (Proc. 6th Int. Workshop on Tribofatics MSTF-2010), Minsk, 2010, pp. 407–412.
Lis, I.N. and Bogdanovich, A.V., Experimental Study of Regularities of Reverse Effect of Metalpolymer Force System at Friction-Mechanical Fatigue, Tribofatika: trudy VI Mezhdunarodnogo simpoziuma po tribofatike MSTF 2010 (Proc. 6th Int. Workshop on Tribofatics MSTF-2010), Minsk, 2010, pp. 707–712.
Lobova, T.A. and Marchenko, E.A., Optimization of Structure and Tribilogic Characteristics of Solid Lubricating Coatings Based on Dichalcogenides of Refractory Metals, Tribofatika: trudy VI Mezhdunarodnogo simpoziuma po tribofatike MSTF 2010 (Proc. 6th Int. Workshop on Tribofatics MSTF-2010), Minsk, 2010, pp. 713–719.
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Original Russian Text © S.B. Bulgarevich, M.V. Boiko, E.N. Tarasova, V.A. Feizova, K.S. Lebedinskii, 2012, published in Trenie i Iznos, 2012, Vol. 33, No. 5, pp. 473–485.
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Bulgarevich, S.B., Boiko, M.V., Tarasova, E.N. et al. Kinetics of mechanoactivation of tribochemical processes. J. Frict. Wear 33, 345–353 (2012). https://doi.org/10.3103/S1068366612050042
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DOI: https://doi.org/10.3103/S1068366612050042