Proceedings of the XXIII Russian Conference on Electron Microscopy

Bulletin of the Russian Academy of Sciences: Physics

, 75:1205

First online:

Investigating the structure of electrolytically deposited alloys of the CoP-CoNiP system under thermal action

  • E. B. ModinAffiliated withFar Eastern State University Email author 
  • , O. V. VoitenkoAffiliated withFar Eastern State University
  • , A. P. GlukhovAffiliated withFar Eastern State University
  • , A. V. KirillovAffiliated withFar Eastern State University
  • , E. V. PustovalovAffiliated withFar Eastern State University
  • , V. S. PlotnikovAffiliated withFar Eastern State University
  • , B. N. GrudinAffiliated withFar Eastern State University
  • , S. S. GrabchikovAffiliated withJoint Institute of Solid State Physics and Semiconductors, National Academy of Sciences of Belarus
  • , L. B. SosnovskayaAffiliated withJoint Institute of Solid State Physics and Semiconductors, National Academy of Sciences of Belarus

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Abstract

The problems of structural relaxation and crystallization of electrolytically deposited amorphous metal alloys of the CoP-CoNiP system are investigated. The onset of the structural relaxation and crystallization is found to occur through the nucleation of nanocrystalline particles of an unrecognized Co x Ni y P1−xy phase. An increase in the concentration of Ni is shown to yield a substantial thickening of the amorphous structure and to increase the temperature of the onset of structural relaxation and crystallization by 50–70°C.