Abstract
Solvent formulation is important in the optimization of the mass-transfer through supported liquid membranes (SLM) in pertraction and membrane extraction. Oleyl alcohol (OA) is frequently used as the solvent or diluent in the extraction of carboxylic acids. A disadvantage of OA is its relatively high viscosity of 28.32 mPa s at 25°C. This can be decreased by the application of a less viscous OA diluent, e.g. dodecane. The relationship between the ratio of the distribution coefficient of butyric acid (BA), D F, and the viscosity of OA-dodecane solvents, µ, as extraction and transport characteristics, and the overall mass-transfer coefficient, K p, through SLMs was analyzed. Dependence of the D F/µ ratio on the OA concentration showed a maximum at the OA concentration of 15 mass % to 30 mass %. The OA concentration dependence of K p for SLMs exhibited also a maximum at about 30 mass % and 20 mass % of OA at the BA concentration driving force of 0.12 kmol m−3 and 0.3 kmol m−3, respectively. Shifting of the maximum in K p dependences towards lower OA concentrations by increasing the BA concentration driving force is in agreement with the D F/µ ratio dependence. Using pure OA as the solvent or diluent is not preferable and a mixture of a low viscosity diluent with the OA concentration below 40 mass % should be used. The presented results show the potential of the D F/µ ratio in the screening and formulation of solvents in extraction and SLM optimization.
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References
Bilgin, M. (2006). Phase equilibria of liquid (water + butyric acid + oleyl alcohol) ternary system. The Journal of Chemical Thermodynamics, 38, 1634–1639. DOI: 10.1016/j.jct.2006.03.017.
Bilgin, M., Kirbaşlar, Ş. İ., Özcan, Ö., & Dramur, U. (2006). Distribution of butyric acid between water and several solvents. Journal of Chemical & Engineering Data, 51, 1546–1550. DOI: 10.1021/je060025z.
Blahušiak, M., Schlosser, Š., & Marták, J. (2010). Simulation of a hybrid fermentation-separation process for production of butyric acid. Chemical Papers, 64, 213–222. DOI: 10.2478/s11696-009-0114-7.
Blahušiak, M., Schlosser, Š., & Marták, J. (2011). Extraction of butyric acid by a solvent impregnated resin containing ionic liquid. Reactive and Functional Polymers, 71, 736–744. DOI: 10.1016/j.reactfunctpolym.2011.04.002.
Evans, P. J., & Wang, H. Y. (1988). Enhancement of butanol formation by Clostridium acetobutylicum in the presence of decanol-oleyl alcohol mixed extractants. Applied and Environmental Microbiology, 54, 1662–1667.
Evans, P. J., & Wang, H. Y. (1990). Effects of extractive fermentation on butyric acid production by Clostridium acetobutylicum. Applied Microbiology and Biotechnology, 32, 393–397. DOI: 10.1007/bf00903771.
Grzenia, D. L., Schell, D. J., & Wickramasinghe, S. R. (2012a). Membrane extraction for detoxification of biomass hydrolysates. Bioresource Technology, 111, 248–254. DOI: 10.1016/j.biortech.2012.01.169.
Grzenia, D. L., Wickramasinghe, S. R., & Schell, D. J. (2012b). Fermentation of reactive-membrane-extracted and ammonium-hydroxide-conditioned dilute-acid-pretreated corn stover. Applied Biochemistry and Biotechnology, 166, 470–478. DOI: 10.1007/s12010-011-9442-5.
Hatzinikolaou, D. G., & Wang, H. Y. (1992). Extractive fermentation systems for organic acids production. The Canadian Journal of Chemical Engineering, 70, 543–552. DOI: 10.1002/cjce.5450700318.
Ingale, M. N., & Mahajani, V. V. (1994). Recovery of butyric acid, valeric acid, and caproic acid (BVC acids) from an aqueous waste stream using tributylphosphate (TBP) as an extractant. Separations Technology, 4, 252–257. DOI: 10.1016/0956-9618(94)80030-8.
Ingale, M. N., & Mahajani, V. V. (1996). Recovery of carboxylic acids, C2-C6, from an aqueous waste stream using tributylphosphate( TBP): Effect of presence of inorganic acids and their sodium salts. Separations Technology, 6, 1–7. DOI: 10.1016/0956-9618(95)00132-8.
Kertész, R., Schlosser, Š., & Šimo, M. (2004). Mass-transfer characteristics of a spiral-channel SLM module in pertraction of phenylalanine. Desalination, 163, 103–117. DOI: 10.1016/s0011-9164(04)90182-8.
Keshav, A., Wasewar, K. L., & Chand, S. (2009). Extraction of acrylic, propionic, and butyric acid using Aliquat 336 in oleyl alcohol: Equilibria and effect of temperature. Industrial & Engineering Chemistry Research, 48, 888–893. DOI: 10.1021/ie8010337.
Li, Z. Y., Qin, W., & Dai, Y. Y. (2002). Liquid-liquid equilibria of acetic, propionic, butyric, and valeric acids with trioctylamine as extractant. Journal of Chemical & Engineering Data, 47, 843–848. DOI: 10.1021/je015526t.
Marták, J., Schlosser, Š., Sabolová, E., Krištofíkova, L., & Rosenberg, M. (2003). Fermentation of lactic acid with Rhizopus arrhizus in a stirred tank reactor with a periodical bleed and feed operation. Process Biochemistry, 38, 1573–1583. DOI: 10.1016/s0032-9592(03)00059-1.
Marták, J., & Schlosser, Š. (2007). Extraction of lactic acid by phosphonium ionic liquids. Separation and Purification Technology, 57, 483–494. DOI: 10.1016/j.seppur.2006.09.013.
Marták, J., & Schlosser, Š. (2008). Liquid-liquid equilibria of butyric acid for solvents containing a phosphonium ionic liquid. Chemical Papers, 62, 42–50. DOI: 10.2478/s11696-007-0077-5.
Marták, J., Schlosser, Š., & Vlčkova, S. (2008). Pertraction of lactic acid through supported liquid membranes containing phosphonium ionic liquid. Journal of Membrane Science, 318, 298–310. DOI: 10.1016/j.memsci.2008.02.064.
Marták, J., Schlosser, Š., & Blahušiak, M. (2011). Mass-transfer in pertraction of butyric acid by phosphonium ionic liquids and dodecane. Chemical Papers, 65, 608–619. DOI: 10.2478/s11696-011-0069-3.
Reid, R. C., Prausnitz, J. M., & Sherwood, T. K. (1977). The properties of gases and liquids (3rd ed.). New York, NY, USA: McGraw-Hill.
Sabolová, E., Schlosser, Š., & Marták, J. (2001). Liquid-liquid equilibria of butyric acid in water + solvent systems with trioctylamine as extractant. Journal of Chemical & Engineering Data, 46, 735–745. DOI: 10.1021/je000323a.
Shan, X. C., Qin, W., & Dai, Y. Y. (2006). Dependence of extraction equilibrium of monocarboxylic acid from aqueous solutions on the relative basicity of extractant. Chemical Engineering Science, 61, 2574–2581. DOI: 10.1016/j.ces.2005.11.026.
Vandák, D., Zigová, J., Šturdik, E., & Schlosser, Š. (1997). Evaluation of solvent and pH for extractive fermentation of butyric acid. Process Biochemistry, 32, 245–251. DOI: 10.1016/s0032-9592 (96)00084-2.
Wilke, C. R., & Chang, P. (1955). Correlation of diffusion coefficients in dilute solutions. AIChE Journal, 1, 264–270. DOI: 10.1002/aic.690010222.
Wu, Z. T., & Yang, S. T. (2003). Extractive fermentation for butyric acid production from glucose by Clostridium tyrobutyricum. Biotechnology and Bioengineering, 82, 93–102. DOI: 10.1002/bit.10542.
Zigová, J., Vandák, D., Schlosser, Š., & Šturdík, E. (1996). Extraction equilibria of butyric acid with organic solvents. Separation Science and Technology, 31, 2671–2684. DOI: 10.1080/01496399608000819.
Zigová, J., Šturdík, E., Vandák, D., & Schlosser, Š. (1999). Butyric acid production by Clostridium butyricum with integrated extraction and pertraction. Process Biochemistry, 34, 835–843. DOI: 10.1016/s0032-9592(99)00007-2.
Zigová, J., Švitel, J., & Šturdík, E. (2000). Possibilities of butyric acid production by butanol oxidation with Gluconobacter oxydans coupled with extraction. Chemical & Biochemical Engineering Quarterly, 14, 95–100.
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Blahušiak, M., Marták, J., Miranda, F. et al. Effect of viscosity of a liquid membrane containing oleyl alcohol on the pertraction of butyric acid. Chem. Pap. 67, 1560–1568 (2013). https://doi.org/10.2478/s11696-013-0370-4
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DOI: https://doi.org/10.2478/s11696-013-0370-4