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Unusual potassium-oxalate coordination in the two-dimensional trimetallic [CoCl(NH3)5][KCr(C2O4)3]·0.5H2O complex

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Central European Journal of Chemistry

Abstract

A new heterometallic compound, [CoCl(NH3)5][KCr(C2O4)3]·0.5H2O (1), has been synthesized and characterized by elemental analysis, IR and electronic spectra, thermal analysis, variable temperature magnetic susceptibility measurements, and single crystal X-ray diffraction. Compound 1 consists of two-dimensional [{KCr(C2O4)3}n]2n− layers, [CoCl(NH3)5]2+ ions and water molecules. Within the 2-D layer, three different types of oxalate coordination modes are present. Each K cation is coordinated by eight oxygen atoms from oxalate groups and also weakly interacts with the ninth oxygen atom. The extensive network of hydrogen bond is formed between the [KCr(C2O4)3]2− layer and the [CoCl(NH3)5]2+ ions. These interactions involve all hydrogen atoms of ammonia ligads and water molecule.

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Authors and Affiliations

  1. Faculty of Chemistry, Nicolaus Copernicus University, 87-100, Toruń, Poland

    Grzegorz Wrzeszcz, Andrzej Wojtczak & Magdalena Zawadzka

Authors
  1. Grzegorz Wrzeszcz
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  2. Andrzej Wojtczak
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  3. Magdalena Zawadzka
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Correspondence to Grzegorz Wrzeszcz.

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Wrzeszcz, G., Wojtczak, A. & Zawadzka, M. Unusual potassium-oxalate coordination in the two-dimensional trimetallic [CoCl(NH3)5][KCr(C2O4)3]·0.5H2O complex. cent.eur.j.chem. 12, 652–658 (2014). https://doi.org/10.2478/s11532-014-0517-3

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  • DOI: https://doi.org/10.2478/s11532-014-0517-3

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