Abstract
In the study, a thermally activated sodium peroxydisulphate (PDS; Na2S2O8) was applied in order to disintegrate wastewater activated sludge (WAS). Chemical disintegration of WAS results in organic matter and polymer transfer from the solid phase to the liquid phase. Soluble chemical oxygen demand (SCOD) is often used to characterise the disintegration efficiency of WAS flocs and microorganisms cells. The present study was conducted in order to chemically disintegrate WAS using PDS in doses of 0.2 %, 0.4 %, 0.6 %, 0.8 % and 1.0 % activated at temperatures of 50°C, 70°C and 90°C for 30 min. The temperature rise induced the PDS to form free radicals, which resulted in an increase in SCOD, i.e. for the highest dose of PDS, the SCOD value attained 2140 mg dm−3 (almost a 15-fold increase over the WAS value). A further positive effect from using this method was a decrease in the sludge volume index (SVI) from 89.8 cm3 g−1 to 30.6 cm3 g−1. On the basis of the results obtained, it may be concluded that thermally activated PDS is suitable for disintegration and has a positive impact on WAS sedimentation properties.
Similar content being viewed by others
References
Abelleira, J., Pérez-Elvira, S. I., Sánchez-Oneto, J., Portela, J. R., & Nebot, E. (2012). Advanced thermal hydrolysis of secondary sewage sludge: A novel process combining thermal hydrolysis and hydrogen peroxide addition. Resources, Conservation and Recycling, 59 52–57. DOI: 10.1016/j.resconrec.2011.03.008.
Ahmad, M., Teel, A. L., & Watts, R. J. (2013). Mechanism of persulfate activation by phenols. Environmental Science & Technology, 47 5864–5871. DOI: 10.1021/es400728c.
Block, P. A., Brown, R. A., & Robinson, D. (2004). Novel activation technologies for sodium persulfate in situ chemical oxidation. In Proceedings of the 4th International Conference on the Remediation of Chlorinated and Recalcitrant Compounds, May 24–27, 2004 (Paper 2A-05). Monterrey, Mexico: Battelle Press.
Bougrier, C., Albasi, C., Delgenès, J. P., & Carrère, H. (2006). Effect of ultrasonic, thermal and ozone pre-treatments on waste activated sludge solubilisation and anaerobic biodegradability. Chemical Engineering and Processing: Process Intensification, 45 711–718. DOI: 10.1016/j.cep.2006.02.005.
Bougrier, C., Delgenès, J. P., & Carrère, H. (2008). Effects of thermal treatments on five different waste activated sludge samples solubilisation, physical properties and anaerobic digestion. Chemical Engineering Journal, 139 236–244. DOI: 10.1016/j.cej.2007.07.099.
Braguglia, C. M., Gianico, A., & Mininni, G. (2011). Laboratory-scale ultrasound pre-treated digestion of sludge: heat and energy balance. Bioresource Technology, 102 7567–7573. DOI: 10.1016/j.biortech.2011.05.025.
Burgess, J. E., & Platschke, B. I. (2008). Hydrolytic enzymes in sewage sludge treatment: A mini-review. Water SA, 34 343–349.
Cabirol, N., Barragán, E. J., Durán, A., & Noyola, A. (2003). Effect of aluminium and sulphate on anaerobic digestion of sludge from wastewater enhanced primary treatment. Water Science and Technology, 48 235–240.
Carrère, H., Dumas, C., Battimelli, A., Batstone, D. J., Delgenes, J. P., Steyer, J. P., & Ferrer, I. (2010). Pretreatment methods to improve sludge anaerobic degradability: A review. Journal of Hazardous Materials, 183 1–15. DOI: 10.1016/j.jhazmat.2010.06.129.
Cloete, T. E., & Oosthuizen, D. J. (2001). The role of extracellular exopolymers in the removal of phosphorous from activated sludge. Water Research, 35 3595–3598. DOI: 10.1016/s0043-1354(01)00093-8.
Eskicioglu, C., Kennedy, K. J., & Droste, R. L. (2006). Enhancement of batch waste activated sludge digestion by microwave pretreatment. Water Environment Research, 79 2304–2317. DOI: 10.2175/106143007x184069.
Esparza-Soto, M., & Westerhoff, P. (2003). Biosorption of humic and fulvic acids to live activated sludge biomass. Water Research, 37 2301–2310. DOI: 10.1016/s0043-1354(02)00630-9.
Fang, G. D., Gao, J., Dionysiou, D. D., Liu, C., & Zhou, D. M. (2013). Activation of persulfate by quinones: Free radical reactions and implication for the degradation of PCBs. Environmental Science & Technology, 47 4605–4611. DOI: 10.1021/es400262n.
Gray, N. F. (2004). Biology of wastewater treatment (Vol. 4, 2nd ed.). London, UK: Imperial College Press.
Grübel, K., & Suschka, J. (2015). Hybrid alkali-hydrodynamic disintegration of waste-activated sludge before two-stage anaerobic digestion process. Environmental Science and Pollution Research, 22 7258–7270. DOI: 10.1007/s11356-014-3705-y.
Guan, B. H., Yu, J., Fu, H. L., Guo, M. H., & Xu, X. H. (2012). Improvement of activated sludge dewaterability by mild thermal treatment in CaCl2 solution. Water Research, 46 425–432. DOI: 10.1016/j.watres.2011.11.014.
Guellil, A., Thomas, F., Block, J. C., Bersillon, J. L., & Ginestet, P. (2001). Transfer of organic matter between wastewater and activated sludge flocs. Water Research, 35 143–150. DOI: 10.1016/s0043-1354(00)00240-2.
Hiraoka, M., Takeda, N., Sakai, S., & Yasuda, A. (1984). Highly efficient anaerobic digestion with thermal pretreatment. Water Science and Technology, 17 529–539.
Huang, K. C., Couttenye, R. A., & Hoag, G. E. (2002). Kinetics of heat-assisted persulfate oxidation of methyl tert-butyl ether (MTBE). Chemosphere, 49 413–420. DOI: 10.1016/s0045-6535(02)00330-2.
Houdková, L., Borán, J., Ucekaj, V., Elsäßer, T., & Stehlík, P. (2008). Thermal processing of sewage sludge — II. Applied Thermal Engineering, 28 2083–2088. DOI: 10.1016/j.applthermaleng.2008.04.005.
Jenkins, D., Richard, M. G., & Daigger, G. T. (1993). Manual on the causes and control of activated sludge bulking and foaming (2nd ed.). Fort Worth, TX, USA: Lewis Publishers.
Kennedy, K. J., Thibault, G., & Droste, R. L. (2007). Microwave enhanced digestion of aerobic SBR sludge. Water SA, 33 261–270.
Kjellerup, B. V., Keiding, K., & Nielsen, P. H. (2001). Monitoring and troubleshooting of non-filamentous settling and dewatering problems in an industrial activated sludge treatment plant. Water Science and Technology, 44 155–162.
Latimer, W. M. (1952). Oxidation potentials (2nd ed.). Englewood Cliffs, NJ, USA: Prentice-Hall.
Liang, C. J., Bruell, C. J., Marley, M. C., & Sperry, K. L. (2004). Persulfate oxidation for in situ remediation of TCE. I. Activated by ferrous ion with and without a persulfate-thiosulfate redox couple. Chemosphere, 55 1213–1223. DOI: 10.1016/j.chemosphere.2004.01.029.
Liang, C. J., & Guo, Y. Y. (2012). Remediation of diesel-contaminated soils using persulfate under alkaline condition. Water Air & Soil Pollution, 223 4605–4614. DOI: 10.1007/s11270-012-1221-6.
Liu, X., Wang, W., Gao, X. B., Zhou, Y. J., & Shen, R. J. (2012). Effect of thermal pretreatment on the physical and chemical properties of municipal biomass waste. Waste Management, 32 249–255. DOI: 10.1016/j.wasman.2011.09.027.
Neyens, E., Baeyens, J., Weemaes, M., & De Heyder, B. (2003a). Hot acid hydrolysis as a potential treatment of thickened sewage sludge. Journal of Hazardous Materials, 98 275–293. DOI: 10.1016/s0304-3894(03)00002-5.
Neyens, E., Baeyens, J., & Creemers, C. (2003b). Alkaline thermal sludge hydrolysis. Journal of Hazardous Materials, 97 295–314. DOI: 10.1016/s0304-3894(02)00286-8.
Oncu, N. B., & Balcioglu, I. A. (2013). Microwave-assisted chemical oxidation of biological waste sludge: Simultaneous micropollutant degradation and sludge solubilization. Bioresource Technology, 146 126–134. DOI: 10.1016/j.biortech.2013.07.043.
Peeters, B., Vernimmen, L., & Meeusen, W. (2009). Lab protocol for a spin tube test, simulating centrifugal compaction of activated sludge. Filtration, 9 205–217.
Rice, E. W., Baird, R. B., Eaton, A. D., & Clesceri, L. S. (2012). Standard methods for the examination of water and wastewater (22nd ed.). Washington, DC, USA: American Public Health Association.
Romero, A., Santos, A., Vicente, F., & González, C. (2010). Diuron abatement using activated persulphate: Effect of pH, Fe(II) and oxidant dosage. Chemical Engineering Journal, 162 257–265. DOI: 10.1016/j.cej.2010.05.044.
Sanin, F. D., Clarkson, W. W., & Vesilind, P. A. (2011). Sludge engineering: the treatment and disposal of wastewater sludges (1st ed.). Lancaster, PA, USA: DEStech Publications.
Sezgin, M. (1982). Variation of sludge volume index with activated sludge characteristics. Water Research, 16 83–88. DOI: 10.1016/0043-1354(82)90056-2.
Siegrist, R. L., Crimi, M., & Simpkin, T. J. (2011). In situ chemical oxidation for groundwater remediation. New York, NY, USA: Springer.
Stasta, P., Boran, J., Bebar, L., Stehlik, P., & Oral, J. (2006). Thermal processing of sewage sludge. Applied Thermal Engineering, 26 1420–1426. DOI: 10.1016/j.applthermaleng.2005.05.030.
Sun, D. D., Liang, H. M., & Ma, C. (2012). Enhancement of sewage sludge anaerobic digestibility by sulfate radical pretreatment. Advanced Materials Research, 518–523, 3358–3362. DOI: 10.4028/www.scientific.net/amr.518-523.3358.
Wang, F., Lu, S. H., & Ji, M. (2006). Components of release liquid from ultrasonic waste activated sludge disintegration. Ultrasonics Sonochemistry, 13 334–338. DOI: 10.1016/j.ultsonch.2005.04.008.
Wei, C. H., Wang, W. X., Deng, Z. Y., & Wu, C. F. (2007). Characteristics of high-sulfate wastewater treatment by two-phase anaerobic digestion process with Jet-loop anaerobic fluidized bed. Journal of Environmental Sciences, 19 264–270. DOI: 10.1016/s1001-0742(07)60043-6.
Wett, B., Phothilangka, P., & Eladawy, A. (2010). Systematic comparison of mechanical and thermal sludge disintegration technologies. Waste Management, 30 1057–1062. DOI: 10.1016/j.wasman.2009.12.011.
Wilson, C. A., & Novak, J. T. (2009). Hydrolysis of macromolecular components of primary and secondary wastewater sludge by thermal hydrolytic pretreatment. Water Research, 43 4489–4498. DOI: 10.1016/j.watres.2009.07.022.
Yin, F. B., Wang, D. L., Li, Z. F., Ohlsen, T., Hartwig, P., & Czekalla, S. (2015). Study on anaerobic digestion treatment of hazardous colistin sulphate contained pharmaceutical sludge. Bioresources Technology, 177 188–193. DOI: 10.1016/j.biortech.2014.11.091.
Yuan, S. H., Liao, P., & Alshawabkeh, A. N. (2014). Electrolytic manipulation of persulfate reactivity by iron electrodes for trichloroethylene degradation in groundwater. Environmental Science & Technology, 48 656–663. DOI: 10.1021/es404535q.
Zhen, G. G., Lu, X. Q., Li, Y. Y., Zhao, Y. C., Wang, B. Y., Song, Y., Chai, X. L., Niu, D. J., & Cao, X. Y. (2012a). Novel insights into enhanced dewaterability of waste activated sludge by Fe(II)-activated persulfate oxidation. Bioresource Technology, 119 7–14. DOI: 10.1016/j.biortech.2012.05.115.
Zhen, G. G., Lu, X. Q., Wang, B. Y., Zhao, Y. C., Chai, X. L., Niu, D. J., Zhao, A. H., Li, Y. Y., Song, Y., & Cao, X. Y. (2012b). Synergetic pretreatment of waste activated sludge by Fe(II)-activated persulfate oxidation under mild temperature for enhanced dewaterability. Bioresource Technology, 124 29–36. DOI: 10.1016/j.biortech.2012.08.039.
Zhen, G. Y., Lu, X. Q., Li, Y. Y., & Zhao, Y. C. (2013). Innovative combination of electrolysis and Fe(II)-activated persulfate oxidation for improving the dewaterability of waste activated sludge. Bioresource Technology, 136 654–663. DOI: 10.1016/j.biortech.2013.03.007.
Zhou, L., Zheng, W., Ji, Y. F., Zhang, J. F., Zeng, C., Zhang, Y., Wang, Q., & Yang, X. (2013). Ferrous-activated persulfate oxidation of arsenic(III) and diuron in aquatic system. Journal of Hazardous Materials, 263 422–430. DOI: 10.1016/j.jhazmat.2013.09.056.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wacławek, S., Grübel, K., Chłąd, Z. et al. Impact of peroxydisulphate on disintegration and sedimentation properties of municipal wastewater activated sludge. Chem. Pap. 69, 1473–1480 (2015). https://doi.org/10.1515/chempap-2015-0169
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1515/chempap-2015-0169