Abstract
An ultrasound assisted SPME method with a new nanoporous SBA-15 fiber functionalized with 3-[bis(2-hydroxyethyl)amino]propyl-triethoxysilane was successfully applied to the study of the essential oil composition of cumin (Cuminum cyminum L.) seeds. The sample was irradiated by ultrasound radiation and its volatile components were collected by the fiber from the sample headspace and directly injected into a GC-MS injection port for analysis. A simplex method was used for optimization of four different parameters affecting the efficiency of the extraction. Under the optimized conditions (i.e. sample weight, 0.6 g; temperature, 70 °C; sonication time, 12 min and extraction time, 28 min), the number of components identified by the proposed method and their amounts were identical to those of a hydrodistillation technique. The extraction efficiency of the SBA-15 fiber was superior to a PDMS commercial fiber. The major components identified were p-menta-1,3-dien-7-al, cuminaldehyde, γ-terpinene and p-cymene, respectively. The proposed method was applied to a comparative study of the essential oil composition of cumin in three different climate conditions of the Lorestan province in Iran. The results indicated that the essential oils in the temperate and tropical locations were 94.0 and 85.6% of the cold region, respectively.
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References
Zargari A (1989) Medicinal plants, vol II. Tehran University Press, Tehran, pp 519–521
Roman-Ramos R, Flores-Saenz JL, Alarcon-Aguilar FJ (1995) J Ethnopharmacol 48:25–32
Talpur N, Echard B, Ingram C, Bagchi D, Preuss H (2005) Diabetes Obes Metab 7:193–199
Dhandapani S, Subramanian VR, Rajagopal S, Namasivayam N (2002) Pharmacol Res 46:251–255
Malini T, Vanithakumari G (1987) Ind J Exp Biol 5:442–444
Behera S, Nagarajan S, Jagan Mohan Rao L (2004) Food Chem 87:25–29
Wang Z, Ding L, Li T, Zhou X, Wang L, Zhang H, Liu L, Li Y, Liu Z, Wang H, Zeng H, He H (2006) J Chromatogr A 1102:11–17
Gachkar L, Yadegari D, Rezaei MB, Taghizadeh M, Alipoor Astaneh S, Rasooli I (2007) Food Chem 102:898–904
Hashemi P, Yarahmadi A, Azizi K, Sabouri B (2008) Chromatographia 67:253–257
Lee H-S (2005) J Agric Food Chem 53:2446–2450
Lord H, Pawliszyn J (2000) J Chromatogr A 902:17–63
Riu-Aumatell M, Castellari M, Lopez-Tamames E, Galassi S, Buxaderas S (2004) Food Chem 87:627–637
Hashemi P, Abolghasemi MM, Fakhari AR, Ebrahimi SN, Ahmadi S (2007) Chromatographia 66:283–286
Besharati-Seidani A, Jabbari A, Yamini Y (2005) Anal Chim Acta 530:155–161
Fakhari AR, Salehi P, Heydari R, Nejad Ebrahimi S, Haddad PR (2005) J Chromatogr A 1098:14–18
Hashemi P, Shamizadeh M, Badiei A, Zarabadi Poor P, Ghiasvand AR, Yarahmadi A (2009) Anal Chim Acta 646:1–5
Adams RP (2005) Identification of essential oil components by gas chromatography/mass spectroscopy. Allured Publishing Corporation, Carol Stream, IL, USA
Miller JN, Miller JC (2000) Statistics and chemometrics for analytical chemistry, 4th edn. Pearson Education Limited, England
Lambropoulou DA, Albanis TA (2003) J Chromatogr A 993:197–203
Walton GH (1998) West Aust News Lett 11:3–4
Hassan F, Ali H, Cheema MA, Manaf A (2005) J Res Sci 16:65–72
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Hashemi, P., Shamizadeh, M., Badiei, A. et al. Study of the Essential Oil Composition of Cumin Seeds by an Amino Ethyl-Functionalized Nanoporous SPME Fiber. Chroma 70, 1147–1151 (2009). https://doi.org/10.1365/s10337-009-1269-7
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DOI: https://doi.org/10.1365/s10337-009-1269-7