Abstract
A simple multidimensional system for direct injection of large volumes has been developed for the determination of three naphthalene-derivative pesticides [2-(1-naphthyl) acetamide (NAD), 1-naphthyl methylcarbamate (carbaryl) and 1-naphthol] in water using fluorescence detection. The capability of restricted-access medium (RAM), pre-columns for eliminating large interfering molecules, combined with an optimised, coupled-column separation procedure, large volume injection (LVI) and fluorescence detection, gave excellent sensitivity for target analytes. The maximum admissible concentration levels established by the European Union (EU) for individual pesticides and their related compounds in drinking water (0.1 μg L−1) were easily reached. Detection limits were lower than, or equal to, 0.003 μg L−1. Average recoveries ranged: 81–104% (n=3) with relative standard deviation (RSD) values: 2–7%. Application of the coupled-column liquid chromatography (LC-LC) method was by determining target analytes in ground water samples from five agricultural zones of Almería, (Spain) over three months.
Similar content being viewed by others
References
The e-Pesticides manual 2000–2001 (twelfth edition) version 2.0. British Crop Protection Council.
Tomlin C (ed), (2000) The pesticide manual, 12th ed., Crop Protection Publications, Surrey, UK, pp. 133–134
Vettorazi G (1975) Residue Rev. 56:1–5
Morgan DR (1981) Recognition and Management of Pesticides Poisonings, US Environmental, Protection Agency
Sanchez-Camazano M, Sanchez-Martin M (1988) Environ. Toxicol. Chem. 5:559–568
Miyamoto J, Mikami N, Takimoto Y (1990). In: Hutson DH, Roberts TR (eds.) Environmental Fate of Pesticides, Wiley, Chichester, UK, pp. 123–147
de Bertrand N, Barceló D (1991) Anal Chim Acta 254:235–244
Samanidou V, Fytianos K, Pfister G, Bahadir M (1998) Sci Total Environ 76:85–92
Roberts TR, Hutson DH (1999) Metabolic Pathways of Agrochemicals, part 1, The Royal Society of Chemistry, Cambridge
Oh-Shin YS, Ko M, Shin HS (1997) J Chromatogr A 769:285–291
Massey KA, Van Engelen DL, Warner IM (1995) Talanta 42:1457–1463
García de Llasera MP, Bernal-Gonzalez M (2001) Wat Res 35(8):1933–1940
Barceló D (1993) J Chromatogr 643:117–143
Vassilakis I, Tsipi D, Scoullos M (1998) J Chromatogr A 823:49–58
Aguilar C, Ferrer I, Borrull F, Marcé RM, Barceló D (1999) Anal. Chim. Acta 386:237–248
Daghbouche Y, Garrigues S, de la Guardia M (1995) Anal Chim Acta 314:203–212
Marco MP, Chiron S, Gascón J, Hammock BD, Barceló D (1995) Anal Chim Acta 311:319–329
Jorgensen Cassella R, Garrigues S, Santelli RE, de la Guardia M (2000) Talanta 52:717–725
García Sánchez F, Cruces Blanco C (1990) Talanta 37:573–578
Del Olmo M, Laserna J, Romero D, Rohand J, Vilchez JL (1997) Talanta 44:443–449
García Sánchez F, Cruces Blanco C (1988) Quím Anal. 7:299–309
Hogendoorn EA, Van Zoonen P (1995) J Chromatogr A 703:149–166
Hagestam IH, Pinkerton TC (1985) Anal Chem 57:1757–1763
Unger KK (1991) Chromatographia 31:507–511
Desilets CP, Rounds MA, Regnier FE (1991) J Chromatogr 544:25–39
Kubalec P, Brandsteterová E (1999) J Chromatogr B 726:211–218
Keski-Hynnilä H, Raanaa K, Forsberg M, Männistö P, Taskinen J, Kistiainen R (2001) J Chromatogr B 759:227–236
Martínez Fernández J, Martínez Vidal JL, Parrilla Vázquez P, Garrido Frenich A (2001) Chromatographia 53:503–509
Parrilla Vázquez P, Martínez Fernández J, Gil García MD (2002) J Liq Chromatogr Related Technol 25:3045–3058
Parrilla Vázquez P, Martínez Vidal JL, Martínez Fernández J (2000) Analyst 125:1549–1553
Hogendoorn EA, Huls R, Dijkman E, Hoogenbrugge R (2001) J Chromatogr A 938:23–27
Vielhauer S, Rudolphi A, Boos KS, Seidel D (1995) J Chromatogr B 666:315–322
Boos KS, Rudolphi A (1997) LC-GC Int 15:602–611
Yu Z, Westerlund D, Boos KS (1997) J Chromatogr B 704:53–62
Parrilla P, Kaim P, Hogendoorn EA, Baumann RA (1999) Fresenius J Anal Chem 363:77–82
Pinkerton TC (1991) J Chromatogr A 544:13–23
Cruces Blanco C, García Sánchez F (1988) J Photochem Photobiol. A: Chemistry 42:357–373
Massart DL, Vandeginste BGM, Deming SN, Michotte Y, Kaufman L (1988) Chemometrics: a textbook, 2. Elsevier Science, Amsterdam, The Netherlands, pp. 108–110
EURACHEM Guidance Document No. 1. WELAC Guidance Document No. WGD 2. (1993) Accreditation for Chemical Laboratories: Guidance on the interpretation of the EN 45000 series of Standards and ISO/IEC Guide 25, pp.23–24. Available from the EURACHEM Secretariat, PO Box 46, Teddington, Middlesex, TW11 ONH, UK.
IUPAC, prepared by Currie LA IUPAC Commission on Analytical Nomenclature, (1995) Recommendations in Evaluation of Analytical Methods including Detection and Quantification Capabilities, Pure Appl Chem 67:1699–1723
Pablos-Espada MC, Arrebola-Liebanas FJ, Garrido-Frenich A, Martínez-Vidal JL (1999) Int J Environ Anal Chem 75:165–179
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Galera, M., Vázquez, P., Vidal, J. et al. Large-Volume Direct Injection for Determining Naphthalene Derivative Pesticides in Water Using a Restricted-Access Medium Column in RPLC-LC with Fluorescence Detection. Chromatographia 60, 517–522 (2004). https://doi.org/10.1365/s10337-004-0401-y
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1365/s10337-004-0401-y