Abstract
Semi-empirical quantum mechanical calculations of the geometry change associated with negative ion formation for halomethanes were carried out. The relation between these changes and electron polarizabilities was found. Also, calculated adiabatic electron affinities are related to polarizabilities.
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REFERENCES
E. Schultes, A. A. Christodoulides and R. N. Schindler, Chem. Phys. 8, 354 (1975).
D. L. McCorkle, A. A. Christodoulides, L. G. Christophorou and I. Szamrej, J. Chem. Phys. 72, 4049 (1980).
J. A. Ayala, W. E. Wentworth and E. C. M. Chen, J. Phys. Chem. 85, 3989 (1981).
D. L. McCorkle, A. A. Christodoulides and L. G. Christophorou, in: Electron Molecule Interaction and their Applications, p. 547. Academic Press, New York (1984).
I. Szamrej and M. Fory´ s, Prog. React. Kinet. 23, 117 (1998).
M. Fory´s and I. Szamrej, J. Radioanal. Nucl. Chem. 232, 67 (1998).
I. Szamrej, L. G. Christophorou and J. K. Olthoff (Eds), in: Gaseous Dielectrics VIII, p. 63. Kluwer Academic/ Plenum Publishers, New York (1998).
A. Rosa, W. Barszczewska, M. Fory´s and I. Szamrej, Mass. Spectrom. Ion Phys. (in press).
S. J. Burns, J. M. Matthews and D. L. McFadden, J. Phys. Chem. 100, 19436 (1996).
G. L. Gutsev, J. Chem. Phys. 98, 7072 (1993).
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Pezler, B., Szamrej, I. Geometry and energy changes in halomethanes due to electron capture. Research on Chemical Intermediates 27, 787–794 (2001). https://doi.org/10.1163/15685670152622068
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DOI: https://doi.org/10.1163/15685670152622068