Abstract
In this paper, results of hydrogen production via methane pyrolysis in the atmospheric pressure microwave plasma with CH4 swirl are presented. A waveguide-based nozzleless cylinder-type microwave plasma source (MPS) was used to convert methane into hydrogen. The plasma generation was stabilized by a CH4 swirl having a flow rate of 87.5 L min-1. The absorbed microwave power was 1.5–5 kW. The hydrogen production rate and the corresponding energy efficiency were 866 g (H2) h-1 and 577 g (H2) kWh-1 of microwave energy absorbed by the plasma, respectively. These parameters are better than our previous results when nitrogen was used as a swirl gas and much better than those typical for other plasma methods of hydrogen production (electron beam, gliding arc, plasmatron).
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G. Petitpas, J.-D. Rollier, A. Darmon, J. Gonzalez-Aguilar, R. Metkemeijer, L. Fulcheri, Int. J. Hydrogen Energy 32, 2848 (2007)
L. Bromberg, D.R. Cohn, A. Rabinovich, N. Alexeev, A. Samokhin, R. Ramprasad, S. Tamhankar, Int. J. Hydrogen Energy 25, 1157 (2000)
L. Bromberg, D.R. Cohn, A. Rabinovich, N. Alexeev, Int. J. Hydrogen Energy 24, 1131 (1999)
J.M. Cormie, I. Rusu, J. Phys. D: Appl. Phys. 34, 2798 (2001)
N. Reveau, M. Nikravech, O. Martinie, P. Lefaucheux, J.M. Cormier, in Proc. HAKONE VII, Greifswald, Germany, 2000, pp. 252–256
A. Czernichowski, M. Czernichowski, P. Czernichowski, in Proc. 16th Int. Symp. on Plasma Chemistry, Taormina, Italy, 2003, p. 578
H. Sekiguchi, Y. Mori, Thin Solid Films 435, 44 (2003)
H. Sekiguchi, S. Nakanishi, K. Fukuda, H. Inagaki, in Proc. 16th Int. Symp. on Plasma Chemistry, Taormina, Italy, 2003, p. 598
T. Kappes, W. Schiene, T. Hammer, in Proc. 8th Int. Symp. on High Pressure Low Temperature Plasma Chemistry, Puhajarve, Estonia, 2002, pp. 196–200
H. Kabashima, H. Einaga, S. Futamura, IEEE Trans. Ind. Appl. 39, 340 (2003)
S. Futamura, H. Kabashima, L. Ma, in Proc. 4th Int. Symp. on Non-thermal Plasma Technology for Pollution Control and Sustainable Energy Development, Panama City Beach, Florida, USA, 2004, pp. 211–215
B. Pietruszka, K. Anklam, M. Heintze, Appl. Catal. A 261, 19 (2004)
M. Heintze, B. Pietruszka, Catal. Today 89, 21 (2004)
B. Pietruszka, K. Anklam, M. Heintze, in 16th Int. Symp. on Plasma Chemistry, Taormina, Italy, 2003, p. 582
O. Mutaf-Yardimci, A.V. Saveliev, A.A. Fridman, L.A. Kennedy, Int. J. Hydrogen Energy 23, 1109 (1998)
J.S. Chang, Y. Uchida, M. Ara, J.T. Kim, K. Urashima, J.F. Kelly, M. Stanciulescu, R. Burisch, J.P. Charland, in Proc. 4th Int. Symp. on Non-thermal Plasma Technology for Pollution Control and Sustainable Energy Development, Panama City Beach, Florida, USA, 2004, pp. 216–220
T. Kappes, T. Hammer, in Proc. 4th Int. Symp. on Non-thermal Plasma Technology for Pollution Control and Sustainable Energy Development, Panama City Beach, Florida, USA, 2004, pp. 206–210
M. Deminsky, V. Jivotov, B. Potapkin, V. Rusanov, Pure Appl. Chem. 74, 413 (2002)
M. Jasiński, M. Dors, J. Mizeraczyk, J. Power Sources 181, 41 (2008)
M. Moisan, G. Sauve, Z. Zakrzewski, J. Hubert, Plasma Sources Sci. Technol. 3, 584 (1994)
M. Moisan, Z. Zakrzewski, J.C. Rostaining, Plasma Sources Sci. Technol. 10, 387 (2001)
M. Jasiński, J. Mizeraczyk, Z. Zakrzewski, Czech. J. Phys. 52, 421 (2002)
M. Jasiński, J. Mizeraczyk, Z. Zakrzewski, T. Ohkubo, J.S. Chang, J. Phys. D: Appl. Phys. 35, 2274 (2002)
M. Jasiński, J. Mizeraczyk, Z. Zakrzewski, J. Adv. Oxid. Technol. 7, 51 (2004)
J. Mizeraczyk, M. Jasiński, Z. Zakrzewski, Plasma Phys. Contr. Fusion 47, 589 (2005)
K.M. Green, M.C. Borras, P.P. Woskow, G.J. Flores, K. Hadidi, P. Thomas, IEEE Trans. Plasma Sci. 29, 399 (2001)
H.S. Uhm, Y.C. Hong, D.H. Shin, Plasma Sources Sci. Technol. 15, S26 (2006)
P.L. Spath, M.K. Mann, National Renewable Energy Laboratory Technical, Report, 2001, NREL/TP-570-27637
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Jasiński, M., Dors, M. & Mizeraczyk, J. Application of atmospheric pressure microwave plasma source for production of hydrogen via methane reforming. Eur. Phys. J. D 54, 179–183 (2009). https://doi.org/10.1140/epjd/e2008-00221-1
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DOI: https://doi.org/10.1140/epjd/e2008-00221-1