The European Physical Journal B

, Volume 69, Issue 2, pp 167–171

Organic superconductors revisited

STM imaging and DFT based simulations of the bc plane of κ-(BEDT-TTF)2Cu(NCS)2
  • C. Rohr
  • J. M. Büttner
  • F. A. Palitschka
  • N. D. Kushch
  • M. V. Kartsovnik
  • W. Biberacher
  • R. Gross
  • B. A. Hermann
Solid State and Materials

DOI: 10.1140/epjb/e2009-00135-2

Cite this article as:
Rohr, C., Büttner, J., Palitschka, F. et al. Eur. Phys. J. B (2009) 69: 167. doi:10.1140/epjb/e2009-00135-2

Abstract

The surfaces of a ten years aged crystal and a freshly prepared κ-(BEDT-TTF)2Cu(NCS)2 crystal were compared by scanning tunneling microscopy (STM). The molecularly-resolved STM images of the bc plane of the crystals agree with each other and with the electronic contrast obtained by new density functional theory (DFT) based simulations. Even after ten years STM images of the molecular stacking of BEDT-TTF display a variation in brightness at the positions of different molecules. We attribute this symmetry breaking concerning the brightness in the STM images of the otherwise equivalent BEDT-TTF dimers to the electronic states of a relaxed surface.

PACS

68.37.Ef Scanning tunneling microscopy74.70.Kn Organic superconductors71.15.Mb Density functional theory, local density approximation, gradient and other corrections

Copyright information

© EDP Sciences, SIF, Springer-Verlag Berlin Heidelberg 2009

Authors and Affiliations

  • C. Rohr
    • 1
  • J. M. Büttner
    • 1
  • F. A. Palitschka
    • 1
  • N. D. Kushch
    • 2
  • M. V. Kartsovnik
    • 3
  • W. Biberacher
    • 3
  • R. Gross
    • 4
    • 5
  • B. A. Hermann
    • 1
  1. 1.Walther-Meissner-Institute (WMI) of Low Temperature Research of the Bavarian Academy of Science and Faculty of Physics/Center for Nano Science (CeNS)Garching b. MünchenGermany
  2. 2.Institute of Problems of Chemical Physics, Russian Academy of ScienceMoscow-regionRussia
  3. 3.Walther-Meissner-InstitutGarchingGermany
  4. 4.Walther-Meissner-Institut, Bayerische Akademie der WissenschaftenGarchingGermany
  5. 5.Physik-DepartmentTechnische Universität MünchenGarchingGermany