Structure and Thermodynamics of Free Clusters

The European Physical Journal D

, Volume 43, Issue 1, pp 91-95

First online:

The colours of nanometric gold

Optical response functions of selected gold-cluster thiolates
  • R. B. WyrwasAffiliated withSchool of Chemistry & Biochemistry, Georgia Institute of Technology
  • , M. M. AlvarezAffiliated withSchool of Chemistry & Biochemistry, Georgia Institute of Technology
  • , J. T. KhouryAffiliated withSchool of Chemistry & Biochemistry, Georgia Institute of Technology
  • , R. C. PriceAffiliated withSchool of Chemistry & Biochemistry, Georgia Institute of Technology
  • , T. G. SchaaffAffiliated withSchool of Chemistry & Biochemistry, Georgia Institute of Technology
  • , R. L. WhettenAffiliated withSchool of Chemistry & Biochemistry, Georgia Institute of Technology Email author 

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Abstract.

A set of broad-range NIR-vis-UV optical absorption spectra, measured for selected gold-cluster thiolate compounds (GCTs, containing ~20 to 300 Au atoms), is consistently displayed and then analyzed within the dielectric-functions approach. The size-evolution toward `bulk' (Au diameter >3-nm) optical response is thereby clearly demonstrated. The emergence of apparent energy gaps, Eon, for onset of optical absorption, as well as other fine-structure, is consistent with that of a well-quantized metallic electronic structure for the compounds' cores: the onset-band's location Eon and intensity are attributed semiclassically to a circulation-frequency resonance of the Fermi-level electrons. With decreasing cluster-size, an increasing fraction of the integrated (sum-rule) intensity is `missing' from the <4 eV region. This might be explained by the outermost layer consisting of Au(I)thiolate complexes.

PACS.

73.22.-f Electronic structure of nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals 73.22.Lp Collective excitations 36.40.Vz Optical properties of clusters 78.20.Ci Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity)