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Change in the structure of a cathodic catalyst based on turbostratic carbon modified by CoTMPP in the course of corrosion interaction

  • Corrosion in Hydrogenous Energetics
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Abstract

The change in the structure of a cathodic catalyst based on turbostratic carbon (carbon black) modified by products of pyrolysis of cobalt tetra(p-methoxyphenyl)porphyrin in the course of corrosion tests in 0.5 M H2SO4 at a temperature of 60°C is studied. It is shown that corrosion treatment can result, in the case of multicomponent systems, both in changes in the support surface and in a decrease in the amount of active catalyst centers on the whole.

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References

  1. U.S. Department of Energy, Multi-Year Research, Development and Demonstration plan: Planned Program Activities for 2005–2015 (2007). http://www1.eere.energy.gov/hydrogenandfuelcells/mypp.

  2. Jaonen, F., Herranz, J., Lefevre, M., et al., Applied materials and interfaces, 2009, vol. 1, p. 1623.

    Article  Google Scholar 

  3. Li, X., Liu, G., Popov, B.N., et al., J. Power Sources, 2010, vol. 195, p. 6373.

    Article  CAS  Google Scholar 

  4. Iahnke, H., Schonborn, M., and Zimmermann, G., Top. Curr. Chem., 1976, vol. 61, p. 133.

    Article  Google Scholar 

  5. Bagotsky, V.S., Tarasevich, M.R., Radyshkina, K.A., et al., J. Power Sources, 1977, vol. 2, p. 233.

    Article  Google Scholar 

  6. Gupta, S.L., Tryk, D., Bae, I., et al., J. Appl. Electrochem., 1989, vol. 19, p. 19.

    Article  CAS  Google Scholar 

  7. Tarasevich, M.R., Radyushkina, K.A., and Bogdanovskaya, V.A., Elektrokhimiya porfirinov (Electrochemistry of Porphyrins), Moscow: Nauka, 1991.

    Google Scholar 

  8. Strelko, V.V., Kartel, N.T., Dukhno, I.N., et al., Surf. Sci., 2004, vol. 548, p. 281.

    Article  CAS  Google Scholar 

  9. Kuchinskii, E., Burshtein, R., and Frumkin, A., Zh. Fiz. Khim., 1940, vol. 14, no. 4, p. 441.

    CAS  Google Scholar 

  10. Tarasevich, M.R., Chalykh, A.E., Bogdanovskaya, V.A., et al., Electrochim. Acta, 2006, vol. 51, p. 4455.

    Article  CAS  Google Scholar 

  11. Tarasevich, M.R., Mazin, P.V., and Kapustina, N.A., Russ. J. Electrochem., 2011, vol. 47, p. 923.

    Article  CAS  Google Scholar 

  12. Tarasevich, T.R., Khrushcheva, E.A., and Filinovskii, V.Yu., Vrashchayushchiisya diskovyi elektrod s kol’tsom (Rotating Ring-Disk Electrode), Moscow: Nauka, 1987.

    Google Scholar 

  13. Damjanovic, A., Genshaw, M.A., and Bockris, J., O’M, J. Electrochem. Soc., 1967, vol. 114, p. 446.

    Google Scholar 

  14. Practical Surface Abalysis, Auger and X-Ray Photoelectron Spectroscopy, Briggs, D. and Seah, M.P., Eds., John Wiley and Sons, 1996.

  15. Tarasevich, M.R., Zagudaeva, N.M., and Maleeva, E.A.,Korroz.: Mater., Zashch., 2007, no. 10, p. 15.

  16. Gottfried, J.M., J. Am. Chem. Soc., 2007, vol. 129, p. 12110.

    Article  Google Scholar 

  17. Berner, S., Lidbaum, H., Ledung, G., et al., Appl. Surf. Sci., 2007, vol. 253, p. 7540.

    Article  CAS  Google Scholar 

  18. Gottfried, J.M., Flechtner, K., Kretschmann, A., et al., J. Am. Chem. Soc., 2006, vol. 128, p. 5644.

    Article  CAS  Google Scholar 

  19. Gupta, R.P. and Sen, S.K., Phys. Rev. B, 1974, vol. 10, p. 71.

    Article  CAS  Google Scholar 

  20. Gupta, R.P. and Sen, S.K., 20. Phys. Rev. B, 1975, vol. 12, p. 15.

    Article  CAS  Google Scholar 

  21. Naumkin, A.V., Ivanova, T.M., Shchukarev, A.V., et al., Dokl. Akad. Nauk SSSR, 2006, vol. 411, p. 779.

    Google Scholar 

  22. Karweik, D.H. and Winograd, N., Inorg. Chem., 1976, vol. 15, no. 10, p. 2336.

    Article  Google Scholar 

  23. McIntyre, N.S. and Cook, M.G., Anal. Chem., 1975, vol. 47, p. 2208.

    Article  CAS  Google Scholar 

  24. Frost, D.C., McDowell, C.F., and Woolsey, I.S., Mol. Phys., 1974, vol. 27, p. 1473.

    Article  CAS  Google Scholar 

  25. Liu, G., Li, X., Ganesan, P., and Popov, B.N., Electrochim. Acta, 2010, vol. 55, p. 2853.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    M. R. Tarasevich, V. A. Bogdanovskaya, L. P. Kazanskii, O. V. Lozovaya & P. V. Mazin

Authors
  1. M. R. Tarasevich
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  2. V. A. Bogdanovskaya
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  3. L. P. Kazanskii
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  4. O. V. Lozovaya
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  5. P. V. Mazin
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Corresponding author

Correspondence to V. A. Bogdanovskaya.

Additional information

Original Russian Text © M.R. Tarasevich, V.A. Bogdanovskaya, L.P. Kazanskii, O.V. Lozovaya, P.V. Mazin, published in Korroziya: Materialy, Zashchita, 2011, No. 6, pp. 39–48.

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Tarasevich, M.R., Bogdanovskaya, V.A., Kazanskii, L.P. et al. Change in the structure of a cathodic catalyst based on turbostratic carbon modified by CoTMPP in the course of corrosion interaction. Prot Met Phys Chem Surf 48, 755–763 (2012). https://doi.org/10.1134/S2070205112070131

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  • DOI: https://doi.org/10.1134/S2070205112070131

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