Abstract
The results of the regeneration of the deactivated palladium catalyst of acetylene hydrogenation using supercritical fluid extraction (T = 130°C, P = 250 bar) were reported. The activity of the catalyst regenerated in supercritical carbon dioxide is comparable to the activity of the catalyst regenerated by the conventional procedure.
Similar content being viewed by others
References
M. D. Navalikhina and O. V. Krylov, Russ. Chem. Rev. 67, 587 (1998).
S. A. Nikolaev, L. N. Zanaveskin, V. V. Smirnov, V. A. Averyanov, and K. L. Zanaveskin, Russ. Chem. Rev. 78, 231 (2009).
S. Asplund, J. Catal. 158, 267 (1996).
A. Sarkany, React. Kinet. Catal. Lett. 74, 299 (2001).
M. R. Rahimpour, O. Dehghani, M. R. Gholipour, M. S. Shokrollahi Yancheshmeh, S. Seifzadeh Haghighi, and A. Shariati, Chem. Eng. J. 198–199, 491 (2012).
A. Pachulski, R. Schödel, and P. Claus, Appl. Catal. Gen. 400, 14 (2011).
T.-B. Lin and T.-C. Chou, Ind. Eng. Chem. Res. 34, 128 (1995).
L. O. Almanza and O. I. Martinez, in Catalyst Deactivation, Ed. by J. J. Spivey, G. W. Roberts, and B. H. Davis, Vol. 139 of Studies in Surface Science and Catalysis (Elsevier, Amsterdam, 2001), p. 311.
R.-J. Liu, P. A. Crozier, C. M. Smith, D. A. Hucul, J. Blackson, and G. Salaita, Appl. Catal. Gen. 282, 111 (2005).
L. A. Tyurina, S. A. Nikolaev, S. A. Gurevich, V. M. Kozhevin, V. V. Smirnov, and K. L. Zanaveskin, Catal. Ind. 1, 179 (2009).
P. L. Dhepe, A. Fukuoka, and M. Ichikawa, Catal. Lett. 81, 69 (2002).
J. Kim, G. W. Roberts, and D. J. Kiserow, Chem. Mater. 18, 4710 (2006).
T. R. Bilalov, F. M. Gumerov, F. R. Gabitov, Kh. E. Kharlampidi, G. I. Fedorov, A. A. Sagdeev, R. S. Yarullin, and I. A. Yakushev, Russ. J. Phys. Chem. B 3, 1093 (2009).
G. I. Garrido, F. C. Patcas, G. Upper, M. Turk, S. Yilmaz, and B. Kraushaar-Czarnetzki, Appl. Catal. Gen. 338, 58 (2008).
S. Royuela, J. Morere, C. Pando, and J. A. R. Renuncio, in Proceedings of the 10th Conference on Supercritical Fluids and Their Applications, Naples, Italy, 2013, p. 307.
A. Zakharov, A. A. Jaddoa, T. R. Bilalov, and F. M. Gumerov, Int. J. Mass Spectrom. Chromatogr. 2 (4), 113 (2014).
L. Vradman, M. Herskowitz, E. Korin, and J. Wisniak, Ind. Eng. Chem. Res. 40, 1589 (2001).
V. I. Bogdan, A. E. Koklin, and V. B. Kazanskii, Sverkhkrit. Fluidy Teor. Prakt. 1 (2), 5 (2006).
R. F. Gallyamov, A. A. Sagdeev, F. M. Gumerov, and F. R. Gabitov, Russ. J. Phys. Chem. B 4, 1069 (2010).
R. R. Shiriyazdanov, Russ. J. Phys. Chem. B 5, 1080 (2011).
S. N. Gaydamaka, V. V. Timofeev, D. A. Lemenovskii, S. V. Kardashev, O. O. Parenago, V. N. Bagratashvili, S. A. Sergienko, G. P. Brusova, and V. V. Lunin, Catal. Ind. 5, 216 (2013).
A. T. Galimova, A. A. Sagdeev, V. Z. Kuzmin, and F. M. Gumerov, Russ. J. Phys. Chem. B 9, 1123 (2015).
F. M. Gumerov, A. A. Sagdeev, R. F. Gallyamov, A. T. Galimova, and K. A. Sagdeev, Int. J. Anal. Mass Spectrom. Chromatogr. 2 (1), 1 (2014).
F. M. Gumerov, A. A. Sagdeev, T. R. Bilalov, A. A. Jaddoa, Kh. E. Kharlampidi, B. T. Burganov, et al., Catasysts: Regeneration Using Supercritical Fluid CO 2 -Extraction Process (Brig, Kazan, 2015) [in Russian].
R. M. Masagutov, Yu. F. Morozov, and B. I. Kutepov, Regeneration of Catalysts in Oil Refining and Petrochemicals (Khimiya, Moscow, 1987) [in Russian].
B. T. Burganov, E. A. Karalin, V. A. Vasil’ev, and Kh. E. Kharlampidi, Vestn. Kazan. Tekhnol. Univ. 17 (23), 53 (2014).
I. Y. Ahn, J. H. Lee, S. S. Kum, and S. H. Moon, Catal. Today 123, 151 (2007).
I. Y. Ahn, J. H. Lee, S. K. Kim, and S. H. Moon, Appl. Catal. Gen. 360, 38 (2009).
C. H. Bartholomew, P. K. Agrawal, and J. R. Katzer, Adv. Catal. 31, 135 (1982).
E. B. Maxted, Advances in Catalysis (Academic Press, New York, 1951), Vol. 3, p. 129.
S. Machmudah, A. Shotipruk, M. Goto, M. Sasaki, and T. Hirose, Ind. Eng. Chem. Res. 45, 3652 (2006).
E. K. Asep, S. Jinap, M. H. A. Jahurul, I. S. M. Zaidul, and H. Singh, Innov. Food Sci. Emerg. Technol. 20, 152 (2013).
U. Salgın, N. Yıldız, and A. Çalımlı, Sep. Sci. Technol. 39, 2677 (2004).
A. V. Lekar’, S. N. Borisenko, O. V. Filonova, E. V. Vetrova, E. V. Maksimenko, N. I. Borisenko, and V. I. Minkin, Russ. J. Phys. Chem. B 7, 968 (2013).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © B.T. Burganov, Kh.E. Kharlampidi, F.M. Gumerov, V.F. Khairutdinov, 2015, published in Sverkhkriticheskie Flyuidy. Teoriya i Praktika, 2015, Vol. 10, No. 3, pp. 89–96.
Rights and permissions
About this article
Cite this article
Burganov, B.T., Kharlampidi, K.E., Gumerov, F.M. et al. Regeneration of the palladium catalyst of acetylene hydrogenation in modified supercritical CO2 . Russ. J. Phys. Chem. B 10, 1147–1152 (2016). https://doi.org/10.1134/S1990793116070046
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1990793116070046