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Relation of self-diffusion and the topological structure of flexible polymers as studied by NMR

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Abstract

A general approach to deriving formulas for calculating the diffusion attenuation of spin echo decay signal is developed and applied to obtaining data on random processes in linear and crosslinked polymers with different topological structures. The analysis explains the experimentally observed anomalous diffusion in polymer networks.

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Correspondence to T. P. Kulagina.

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Original Russian Text © T.P. Kulagina, G.E. Karnaukh, A.N. Kuzina, L.P. Smirnov, 2013, published in Khimicheskaya Fizika, 2013, Vol. 32, No. 3, pp. 62–68.

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Kulagina, T.P., Karnaukh, G.E., Kuzina, A.N. et al. Relation of self-diffusion and the topological structure of flexible polymers as studied by NMR. Russ. J. Phys. Chem. B 7, 170–176 (2013). https://doi.org/10.1134/S1990793113020036

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  • DOI: https://doi.org/10.1134/S1990793113020036

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