Abstract
A general approach to deriving formulas for calculating the diffusion attenuation of spin echo decay signal is developed and applied to obtaining data on random processes in linear and crosslinked polymers with different topological structures. The analysis explains the experimentally observed anomalous diffusion in polymer networks.
References
W. S. Price, Concepts Magn. Reson. 9, 299 (1997).
M. Adam and D. Lairez, in The physical properties of polymer gels, Ed. by Cohen-Addad (Wiley, New York, 1996), p. 87.
A. Pawlicka, M. Danczuk, W. Wieczorek, et al., J. Phys. Chem. A 112, 8888 (2008).
W. J. Liang and P.-L. Kuo, Macromolecules 37, 840 (2004).
T. Shiga and K. Fukumori, J. Polym. Sci. B 32, 85 (1994).
A. A. Marinin, K. G. Khatmullina, V. I. Volkov, and O. V. Yarmolenko, Russ. J. Electrochem. 46, 717 (2011).
A. A. Marinin, K. G. Khatmullina, V. I. Volkov, O. V. Yarmolenko, V. A. Zabrodin, Izv. Akad. Nauk, Ser. Khim. 60, 1071 (2011).
S. V. Dvinskikh and I. Furó, Russ. Chem. Rev. 75, 497 (2006).
P. T. Callaghan and E. T. Samulski, Macromolecules 30, 113 (1997).
A. I. Maklakov, V. D. Skirda, and N. F. Fatkullin, Selfdiffusion in solutions and alloys (Kaz. Gos. Univ., Kazan, 1987) [in Russian].
R. Kimmich, NMR: Tomography, diffusometry, relaxometry (Springer, Berlin, Heidelberg, 1997).
T. O. Stejskal and J. E. Tanner, J. Chem. Phys. 42, 288 (1965).
A. E. Chalykh, Water diffusion in polymer systems (Khimiya, Moscow, 1987) [in Russian].
J.-M. Petit, X. X. Zhu, and P. M. Macdonald, Macromolecules 29, 70 (1996).
Yu. Yamane, M. Matsui, H. Kimura, et al., Macromolecules 36, 5655 (2003).
M. J. Kim, K. Cardwell, and A. K. Khitrin, J. Chem. Phys. 120, 11327 (2004).
T. P. Kulagina, V. V. Marchenkov, and B. N. Provotorov, Vysokomol. Soedin., Ser. A 31, 381 (1989).
T. P. Kulagina, V. V. Marchenkov, and B. N. Provotorov, Vysokomol. Soedin., Ser. B 30, 23 (1988).
T. P. Kulagina, G. E. Karnaukh, and L. P. Smirnov, Dokl. Phys. Chem. 421, 216 (2008).
T. P. Kulagina, V. M. Litvinov, and I. I. Nazarova, in Proceedings of the 12th all-union school-symposium on magnetic resonance (Perm. Gos. Univ., Perm, 1991), p. 60.
T. P. Kulagina and P. S. Manikin, Strukt. Dinam. Mol. Syst. 4A, 232 (2008). http://www.ksu.ru/sdms/
Methods of computer simulation for study of polymers and biopolymers, Eds. by V. A. Ivanov, A. L. Rabinovich, and A. R. Khokhlov (LIBROKOM, Moscow, 2009) [in Russian].
M. Kehr, N. Fatkullin, and R. Kimmich, J. Chem. Phys. 126, 094903 (2007).
T. P. Kulagina, V. A. Varakina, and A. N. Kuzina, Strukt. Dinam. Mol. Syst. 10B, 80 (2011). http://www.ksu.ru/sdms/
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.P. Kulagina, G.E. Karnaukh, A.N. Kuzina, L.P. Smirnov, 2013, published in Khimicheskaya Fizika, 2013, Vol. 32, No. 3, pp. 62–68.
Rights and permissions
About this article
Cite this article
Kulagina, T.P., Karnaukh, G.E., Kuzina, A.N. et al. Relation of self-diffusion and the topological structure of flexible polymers as studied by NMR. Russ. J. Phys. Chem. B 7, 170–176 (2013). https://doi.org/10.1134/S1990793113020036
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1990793113020036