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Reversible addition-fragmentation chain transfer (RAFT) (Co)polymerization of isobornyl acrylate

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Abstract

Controlled/living radical homopolymerization of isobornyl acrylate and its copolymerization with styrene with reversible chain transfer via the addition-fragmentation mechanism in the presence of benzyl dithiobenzoate have been studied. It has been shown that the (co)polymerization proceeds through living chains, a result that is confirmed by a linear increase in the number-average molecular weight with conversion and by low polydispersity indexes. With the use of polymer RAFT agents block copolymers have been synthesized. Amphiphilic copolymers have been obtained through acid hydrolysis of isobornyl acrylate units in copolymers of various microstructures.

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References

  1. Polymer Handbook, Ed. by J. Brandrup, E. H. Immergut, E. A. Grulke (Wiley, New York, 1999).

    Google Scholar 

  2. V. Coessens, T. Pintauer, and K. Matyjaszewski, Prog. Polym. Sci. 26(3), 337 (2001).

    Article  CAS  Google Scholar 

  3. C. Khoury, G. A. Mensing, and D. J. Beebe, Lab-on-a-Chip 2, 50 (2002).

    Article  CAS  Google Scholar 

  4. S. A. Bulgakova, M. M. Jons, A. E. Pestov, M. N. Toropov, N. I. Chkhalo, S. A. Gusev, E. V. Skorokhodov, N. N. Salashchenko, Russ. Microelectron. 42(3), 165 (2013).

    Article  CAS  Google Scholar 

  5. A. Ovabeek, J. Coat. Technol. Res. 7(1), 1 (2010).

    Article  Google Scholar 

  6. M. D. C. Lopez-Garcia, D. J. Beebe, and W. C. Crone, J. Appl. Polym. Sci. 105(4), 1894 (2007).

    Article  CAS  Google Scholar 

  7. P. Choi, P. F. Fu, and L. J. Guo, Adv. Funct. Mater. 17(5), 65 (2007).

    Article  CAS  Google Scholar 

  8. Controlled and Living Polymerization: From Mechanisms to Applications, Ed. by A. H. E. Muller and K. Matyjaszewski (Wiley-Interscience, New York, 2009).

    Google Scholar 

  9. R. E. Richard, M. Schwarz, S. Ranade, A. K. Chan, K. Matyjaszewski, B. Sumerlin, Biomacromolecules 6(6), 3410 (2005).

    Article  CAS  Google Scholar 

  10. W. M. Moreau, Semiconductor Lithography. Principles, Practices, and Materials (Plenum Press, New York, 1988).

    Book  Google Scholar 

  11. A. Weissberger, E. S. Proskauer, J. A. Riddick, and E. E. Toops, Technique of Organic Chemistry (Wiley-Interscience, New York, 1955).

    Google Scholar 

  12. E. V. Chernikova, A. V. Tarasenko, E. S. Garina, and V. B. Golubev, Polym. Sci., Ser. A 48(10), 1046 (2006).

    Article  Google Scholar 

  13. T. Kelen and F. J. Tudos, J. Macromol. Sci., Chem. 9(1), 1 (1975).

    Article  Google Scholar 

  14. M. Fineman and S. D. Ross, J. Polym. Sci., Part A: Polym. Chem. 9(2), 259 (1950).

    Google Scholar 

  15. Yu. E. Begantsova, F. S. Malyshev, S. D. Zaitsev, Yu. D. Semchikov, Polym. Sci., Ser. A 44(4), 329 (2002).

    Google Scholar 

  16. Handbook of RAFT Polymerization, Ed. by C. Barner, Kowollik Wiley-Interscience, New York, 2008).

    Google Scholar 

  17. Y. K. Chong, J. Krstina, T. P. T. Le, G. Moad, A. Postma, E. Rizzardo, S. H. Thang, Macromolecules 36(7), 2256 (2003).

    Article  CAS  Google Scholar 

  18. S. D. Zaitsev, Yu. D. Semchikov, E. V. Vasil’eva, and L. V. Kurushina, Polym. Sci., Ser. B 54(3–4), 205 (2012).

    Article  CAS  Google Scholar 

  19. C. Barner-Kowollik, M. L. Coote, T. P. Davis, L. Radom, P. Vana, J. Polym. Sci., Part A: Polym. Chem. 41(18), 2828 (2003).

    Article  CAS  Google Scholar 

  20. Y. Kwak, A. Goto, Y. Tsujii, Y. Murata, K. Komatsu, T. Fukuda, Macromolecules 35(8), 3026 (2002).

    Article  CAS  Google Scholar 

  21. S. A. Bulgakova, D. A. Gurova, M. M. Jons, S. D. Zaitsev, E. E. Kulikov, E. V. Skorokhodov, M. N. Toropov, D. A. Pryahin, A. E. Pestov, N. I. Chkhalo, N. N. Salashchenko, Russ. Microelectron. 43(6), 392 (2014).

    Article  CAS  Google Scholar 

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Correspondence to S. D. Zaitsev.

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Original Russian Text © E.E. Kulikov, S.D. Zaitsev, Yu.D. Semchikov, 2015, published in Vysokomolekulyarnye Soedineniya, Ser. C, 2015, Vol. 57, No. 1, pp. 134–142.

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Kulikov, E.E., Zaitsev, S.D. & Semchikov, Y.D. Reversible addition-fragmentation chain transfer (RAFT) (Co)polymerization of isobornyl acrylate. Polym. Sci. Ser. C 57, 120–127 (2015). https://doi.org/10.1134/S1811238215010051

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  • DOI: https://doi.org/10.1134/S1811238215010051

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